Citation: YI Sha, YANG Bin, ZHAO Zhi-jing. Effect of Ce on the structure and properties of PtCu composite membrane electrodes[J]. Journal of Fuel Chemistry and Technology, ;2016, 44(10): 1266-1271. shu

Effect of Ce on the structure and properties of PtCu composite membrane electrodes

School of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093, China

Corresponding author: YANG Bin, yangbin@kmust.edu.cn
Received Date: 13 June 2016
Revised Date: 24 July 2016

Figures(4)

All the membrane electrodes were prepared by ion beam sputtering (IBS) apparatus. Vacuum annealing in combination with acid etching was used as post-processing. The high resolution transmission electron microscopy and X-ray diffraction were employed to investigate the surface morphology and alloying degree of samples. The electrochemical performance was used to detect hydrogen evolution property. The result confirmed that, with the same condition of post-processing, the membrane electrode doped Ce had cross-bridged structure and higher alloying degree, and the electrochemical performance was enhanced by 92.25% compared to pure Pt.
- Ce,
- membrane electrodes,
- cross-bridged structure,
- hydrogen evolution property
1. [1]
  LI W Z, XIN Q, YAN Y S. Nanostructured Pt-Fe/C cathode catalysts for direct methanol fuel cell:The effect of catalyst composition[J]. Int J Hydrogen Energy, 2010,35(6):2530-2538. doi: 10.1016/j.ijhydene.2010.01.013
2. [2]
  JIA Yu-jie, JIANG Jian-chun, SUN Kang, LU Tian-hong. Effect of Pt/Au atomic ratio in active-carbon-supported Au-Pt catalyst on its cathodic performance in direct formic acid fuel cells[J]. J Fuel Chem Technol, 2011,39(10):792-795. doi: 10.1016/S1872-5813(11)60046-7
3. [3]
  JOO J, KIM P, KIM W, YI J. Effect of the preparation conditions of carbon-supported Pt catalyst on PEMFC performance[J]. J Appl Electrochem, 2009,39(1):135-140. doi: 10.1007/s10800-008-9645-9
4. [4]
  ZHANG Xi-gui, WANG Tao, XIA Bao-jia, QIN Pei, XU Nai-xin. Study on oxygen electrode of PEMFC-effect of Ni, Co on properties of Pt/C electro-catalyst[J]. J Fuel Chem Technol, 2003,31(5):411-414.
5. [5]
  LIU M Y, HE Y Q, MAO Z Q, XIE X F. CO-poisoning mechanism of anodic electrocatalyst in proton-exchange membrane fuel cell[J]. Chin J Power Sources, 2002,26(zl):247-249.
6. [6]
  HU Tao, YANG Jian, ZHAO Jun, WANG Dan-jun, SONG Huan-ling, CHOU Ling-jun. Preparation of a Cu-Ce-O catalyst by urea combustion for removing CO from hydrogen[J]. Chin J Catal, 2007,28(10):844-846. doi: 10.1016/S1872-2067(07)60069-2
7. [7]
  XU Yun-fei.Stduy of Pt-Ru/C catalyst of proton-exchange membrane fuel cell[D].Tianjin:Tianjin University, 2007.
8. [8]
  MA Bo-yuan, ZHAO Xing. Theoretical study on CO poisoning of Pt-Ru catalysts[J]. J Liaoning Univ Technol, 2008,28(4):274-277.
9. [9]
  LI L, WANG H X, XU BQ, LI J L, LU T H, MAO Z Q. Study of PEMFC electro-catalysts:Characteristics of a homemade CO-tolerant Pt-Ru/C catalyst[J]. Acta Chim Sin, 2003,61(6):818-823.
10. [10]
  HAN Xing-wang.Aerobic alcohol oxidation catalyzed by copper catalyst[D].Zhejiang:Zhejiang University of Technology, 2014.
11. [11]
  ZHANG Xiao-wei.Interface control and functional assembly of copper-based composite catalysts[D].Beijing:University of Science and Technology Beijing, 2015.
12. [12]
  WANG Li-min, ZHANG Jin-guo, WANG Lin-shan. The copper and copper alloy powders application and research status[J]. Powder Metall Ind, 2013,23(1):52-57.
13. [13]
  LINDNEY N, KAZACHKIN A D V, LUEBKE D R, JULIE L D. Effect of catalyst pre-reduction temperature on the reaction of 1, 2-dichloroethane and H₂ catalyzed by SiO₂-supported PtCu bimetallics[J]. Appl Catal A:Gen, 2012,415:59-69.
14. [14]
  KANG Qiu-zhen, ZHANG Shang-hu. Research, application and market prospects of cerium series products[J]. Gansu Metall, 2013,35(3):44-46.
15. [15]
  TROVARELLI A, FORNASIERO P.Catalysis by Ceria and Related Materials (Volume 2)[M].London:Imperial College Press, 2013.
16. [16]
  ZHAN Wang-cheng, GUO Yun, GONG Xue-qing, GUO Yang-long, WANG Yan-qin, LU Guan-zhong. Current status and perspectives of rare earth catalytic materials and catalysis[J]. Chin J Catal, 2014,35(8):1238-1250. doi: 10.1016/S1872-2067(14)60189-3
17. [17]
  LIU S, WU X D, WENG D D, RAN R. Ceria-based catalysts for soot oxidation:A review[J]. J Rare Earths, 2015,33(6):567-590. doi: 10.1016/S1002-0721(14)60457-9
18. [18]
  WEI Y H, ZHAO Z, JIAO J Q, LIU J, DUAN A J, JIANG G Y. Preparation of ultrafine Ce-based oxide nanoparticles and their catalytic performances for diesel soot combustion[J]. J Rare Earths, 2014,32(2):124-130. doi: 10.1016/S1002-0721(14)60041-7
19. [19]
  LEADRO F N, RENATA F M, RODRIGO F S, OSVALDO A S. Catalytic combustion of soot over ceria-zinc mixed oxides catalysts supported onto cordierite[J]. J Environ Sci, 2014,26(3):694-701. doi: 10.1016/S1001-0742(13)60442-8
20. [20]
  WU W W, FAN Y J, WU X H, LIAO S, HUANG X F, LI X H. Preparation of nano-sized cerium and titanium pyrophosphates via solid-state reaction at room temperature[J]. Rare Metals, 2009,28(1):33-38. doi: 10.1007/s12598-009-0007-5
21. [21]
  DING Meng-lin, ZHANG Si-cai, LV Ning-ning, ZUO Shu-feng. Influence of Pt-Ce on structure and performance of Cu/Al₂O₃ and its application in catalytic oxidation of benzene[J]. J Chin Rare Earths Soc, 2013,31(3):289-295. doi: 10.1016/S1002-0721(12)60274-9
22. [22]
  LI X C, LUO L T, LI F Y. Study on the surface behavior of Pt-Ce/γ-Al₂O₃[J]. J Rare Earths, 1992,10(3):199-203.
23. [23]
  ZHI K D, LIU Q S, ZHAO R Q, HE R X, ZHANG L F. Preparation and characterization of Cu-Ce-La mixed oxide as water-gas shift catalyst for fuel cells application[J]. J Rare Earths, 2008,26(4):538-543. doi: 10.1016/S1002-0721(08)60133-7
24. [24]
  ZHOU Gui-lin, WEI Meng-ying, FEI Li-sha, WU Mao, CAO Yuan-yuan, ZHOU Xin-xing, XIE Hong-mei. Removal of ρ-nitrophenol from aqueous solutions by catalytic oxidation over Cu-Ce catalyst[J]. Water Treat Technol, 2012,38(2):52-55.
25. [25]
  YANG Y, YANG B, PENG J C ZHAO Z J, ZHAO Y M. Enhanced hydrogen evolution properties obtained by electrochemical modification of carbon-supported platinum-copper bimetallic nanocatalysts and structural characterization[J]. RSC Adv, 2015,5:20981-20986. doi: 10.1039/C4RA16060F
26. [26]
  LI Hua-ling, LIAO Shi-jun, SONG Hui-yu. Preparation of special morphologic nano-platinum and its application in fuel cell[J]. Mod Chem Ind, 2013,33(5):26-30.
27. [27]
  CHEN Ji-min, ZHANG Jie-fei. Study on annealing process and microstructure of Al-Cu-Ce alloy[J]. Hot Working Technol, 2013,42(20):214-216.
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