Citation: Wen PEI, Chen SHEN. Heck Arylation of Cyclohexene Promoted by Ultrasonic and Micro wave in Ionic Liquid: a Novel Method of the Synthesis of 3-Naphthylcyclohexene[J]. Chinese Chemical Letters, ;2006, 17(12): 1534-1536. shu

Heck Arylation of Cyclohexene Promoted by Ultrasonic and Micro wave in Ionic Liquid: a Novel Method of the Synthesis of 3-Naphthylcyclohexene

Wen PEI ,
Chen SHEN

College of Chemical Engineering and Materials, Zhejiang University of Technology, Hangzhou 310014

Received Date: 31 August 2006

Synthesis of 3-naphthylcyclohexene by the Heck reactions of bromonaphthalene and naphthyl triflates with cyclohexene catalyzed by palladiun and nickel complex (promoted by ultrasonic and microwave in ionic liquid of [bmim][BF₄]) were performed with high yield and good regioselectivity. This method has advantages of environmentally benign, generality, simplicity and potential for recycling of ionic liquid and catalyat.
- Naphthylcyclohexene,
- palladium and nickel complex,
- ionic liquid,
- Heck reaction,
- synthesis
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