Citation: Ma Mingming, Du Ru, Chu Chu. Electrochemical Synthesis of 4, 4'-Oxydianiline Molecular Imprinted Polymer/Poly 4, 4'-Oxydianiline and Its Absorbing Properties[J]. Chemistry, ;2020, 83(1): 80-87. shu

Electrochemical Synthesis of 4, 4'-Oxydianiline Molecular Imprinted Polymer/Poly 4, 4'-Oxydianiline and Its Absorbing Properties

College of Environmental and Chemical Engineering, Xi'an Polytechnic University, Xi'an, 710048

Received Date: 20 June 2019
Revised Date: 13 October 2019
Accepted Date: 1 November 2019

Figures(11)

A novel electromagnetic material 4, 4'-oxydianiline molecular imprinted polymer composite poly 4, 4'-oxydianiline (4, 4'-ODL-MIP/P-4, 4'-ODL) was prepared on the surface of graphene modified pencil electrode (G-PEC) by means of the secondary electrochemical polymerization. The effects of the effective conductive length, the concentration of graphene, pH of buffer, the concentration ratio of 4, 4'-oxydianiline to functional monomer acrylamide, the range of scanning potential, the number of scanning cycles, scanning rate and elution time on the charge of composite materials were investigated. The testing results of the vector network analyzers showed that as-synthesized composite material exhibited a reflection loss of -10.57dB at 12.56MHz, and the effective electromagnetic wave absorption rate reached 90%. However, the reflection loss of a single 4, 4'-ODL-MIP and graphene were both higher than -10 dB, the effective electromagnetic wave absorption rates were only about 68% and 60%, respectively. Therefore, the composite material exhibited good wave absorbing properties.
- 4, 4'-Oxydianiline,
- Molecular imprinted polymer,
- Secondary electrochemical polymerization,
- Charge,
- Electromagnetic wave absorbing
1. [1]
2. [2]
  Chen J C, Rajendran K, Huang S W, et al. J. Polym. Res., 2011, 18(6):1693~1703.
3. [3]
  Yao Y, Zhang G C, Li J W, et al. J. Appl. Polym. Sci., 2017, 135(12):46029.
4. [4]
  Yang W, Chen Y, Wang J, et al. Nanoscale Res. Lett., 2018, 13(1):181.
5. [5]
  Li K, Liu A, Wei D, et al. Nanoscale Res. Lett., 2018, 13(1):124.
6. [6]
  Raccichini R, Varzi A, Passerini S, et al. Nat. Mater., 2014, 14(3):271~279.
7. [7]
  Liu H R, Yang F, Jin L H, et al. J. Mater. Sci., 2018, 29(9):7763~7769.
8. [8]
9. [9]
10. [10]
  Pell W G, Conway B E, Marincic N. J. Electroanal. Chem., 2000, 491(1-2):9~21.
11. [11]
  Wu X, Du J, Li M, et al. RSC Adv., 2018, 8(1):311~327.
12. [12]
  Eersels K, Diliën H, Lowdon J W, et al. Nutrients, 2018, 10(6):1~12.
13. [13]
  Gui R, Jin H, Guo H, et al. Biosens. Bioelectron., 2018, 100:56~70.
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
22. [22]
23. [23]
  Zhang K, Wu F, Li J, et al. Mater. Chem. Phys., 2018, 208:198~206.
24. [24]
25. [25]
  Manjon F J, Mari B, Serrano J, et al. J. Appl. Phys., 2005, 97(5):190~193.
26. [26]
27. [27]
28. [28]
1. [1]
  Yuxia Luo , Xiaoyu Xie , Fangfang Chen . 药物递送魔法师——分子印迹聚合物. University Chemistry, 2025, 40(8): 202-210. doi: 10.12461/PKU.DXHX202409129
2. [2]
  Junjie Zhang , Yue Wang , Qiuhan Wu , Ruquan Shen , Han Liu , Xinhua Duan . Preparation and Selective Separation of Lightweight Magnetic Molecularly Imprinted Polymers for Trace Tetracycline Detection in Milk. University Chemistry, 2024, 39(5): 251-257. doi: 10.3866/PKU.DXHX202311084
3. [3]
  Min LI , Xianfeng MENG . Preparation and microwave absorption properties of ZIF-67 derived Co@C/MoS₂ nanocomposites. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1932-1942. doi: 10.11862/CJIC.20240065
4. [4]
  Yanglin Jiang , Mingqing Chen , Min Liang , Yige Yao , Yan Zhang , Peng Wang , Jianping Zhang . Experimental and Theoretical Investigations of Solvent Polarity Effect on ESIPT Mechanism in 4′-N,N-diethylamino-3-hydroxybenzoflavone. Acta Physico-Chimica Sinica, 2025, 41(2): 2309027-0. doi: 10.3866/PKU.WHXB202309027
5. [5]
  Ruiying WANG , Hui WANG , Fenglan CHAI , Zhinan ZUO , Benlai WU . Three-dimensional homochiral Eu(Ⅲ) coordination polymer and its amino acid configuration recognition. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 877-884. doi: 10.11862/CJIC.20250052
6. [6]
  .
  南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积
  . CCS Chemistry, 2025, 7(0): -.
7. [7]
  Nan Xiao , Fang Sun . 二芳基硫醚化合物的构建及应用. University Chemistry, 2025, 40(6): 360-363. doi: 10.12461/PKU.DXHX202407099
8. [8]
  Zhongxin YU , Wei SONG , Yang LIU , Yuxue DING , Fanhao MENG , Shuju WANG , Lixin YOU . Fluorescence sensing on chlortetracycline of a Zn-coordination polymer based on mixed ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2415-2421. doi: 10.11862/CJIC.20240304
9. [9]
  Bao Jia , Yunzhe Ke , Shiyue Sun , Dongxue Yu , Ying Liu , Shuaishuai Ding . Innovative Experimental Teaching for the Preparation and Modification of Conductive Organic Polymer Thin Films in Undergraduate Courses. University Chemistry, 2024, 39(10): 271-282. doi: 10.12461/PKU.DXHX202404121
10. [10]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
11. [11]
  Xuefei Leng , Yanshai Wang , Hai Wang , Shengyang Tao . The In-Depth integration of “Industry-University-Research” in the Exploration and Practice of “Comprehensive Training in Polymer Engineering”. University Chemistry, 2025, 40(4): 66-71. doi: 10.12461/PKU.DXHX202405105
12. [12]
  Ke Qiu , Fengmei Wang , Mochou Liao , Kerun Zhu , Jiawei Chen , Wei Zhang , Yongyao Xia , Xiaoli Dong , Fei Wang . A Fumed SiO₂-based Composite Hydrogel Polymer Electrolyte for Near-Neutral Zinc-Air Batteries. Acta Physico-Chimica Sinica, 2024, 40(3): 2304036-0. doi: 10.3866/PKU.WHXB202304036
13. [13]
  Minghui Wu , Markus Mühlinghaus , Xuechao Li , Chaojie Xu , Qiang Chen , Haiming Zhang , Klaus Müllen , Lifeng Chi . On-Surface Synthesis of Chevron-Shaped Conjugated Ladder Polymers Consisting of Benzo[a]azulene Units. Acta Physico-Chimica Sinica, 2024, 40(8): 2307024-0. doi: 10.3866/PKU.WHXB202307024
14. [14]
  Linjie ZHU , Xufeng LIU . Synthesis, characterization and electrocatalytic hydrogen evolution of two di-iron complexes containing a phosphine ligand with a pendant amine. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 939-947. doi: 10.11862/CJIC.20240416
15. [15]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005
16. [16]
  Fanpeng Meng , Fei Zhao , Jingkai Lin , Jinsheng Zhao , Huayang Zhang , Shaobin Wang . Optimizing interfacial electric fields in carbon nitride nanosheet/spherical conjugated polymer S-scheme heterojunction for hydrogen evolution. Acta Physico-Chimica Sinica, 2025, 41(8): 100095-0. doi: 10.1016/j.actphy.2025.100095
17. [17]
  Xingchao Zhao , Xiaoming Li , Ming Liu , Zijin Zhao , Kaixuan Yang , Pengtian Liu , Haolan Zhang , Jintai Li , Xiaoling Ma , Qi Yao , Yanming Sun , Fujun Zhang . Photomultiplication-Type All-Polymer Photodetectors and Their Applications in Photoplethysmography Sensor. Acta Physico-Chimica Sinica, 2025, 41(1): 100007-0. doi: 10.3866/PKU.WHXB202311021
18. [18]
  Hanmei Lü , Xin Chen , Qifu Sun , Ning Zhao , Xiangxin Guo . Uniform Garnet Nanoparticle Dispersion in Composite Polymer Electrolytes. Acta Physico-Chimica Sinica, 2024, 40(3): 2305016-0. doi: 10.3866/PKU.WHXB202305016
19. [19]
  Cuicui Yang , Bo Shang , Xiaohua Chen , Weiquan Tian . Understanding the Wave-Particle Duality and Quantization of Confined Particles Starting from Classic Mechanics. University Chemistry, 2025, 40(3): 408-414. doi: 10.12461/PKU.DXHX202407066
20. [20]
  Dongdong Yao , JunweiGu , Yi Yan , Junliang Zhang , Yaping Zheng . Teaching Phase Separation Mechanism in Polymer Blends Using Process Representation Teaching Method: A Teaching Design for Challenging Theoretical Concepts in “Polymer Structure and Properties” Course. University Chemistry, 2025, 40(4): 131-137. doi: 10.12461/PKU.DXHX202408125

Get Citation

PDF

XML

Metrics

PDF Downloads(6)
Abstract views(453)
HTML views(51)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Electrochemical Synthesis of 4, 4'-Oxydianiline Molecular Imprinted Polymer/Poly 4, 4'-Oxydianiline and Its Absorbing Properties

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

Metrics

通讯作者: 陈斌, bchen63@163.com