Citation: CHENG Jun-jie, LI Zhen-rong, ZHAO Liang-fu. Catalytic performance of Ni-W supported on micro-mesoporous Hβ/Al-SBA-15 composite molecular sieves in the hydrocracking of naphthalene to BTX[J]. Journal of Fuel Chemistry and Technology, ;2017, 45(1): 93-99. shu

Catalytic performance of Ni-W supported on micro-mesoporous Hβ/Al-SBA-15 composite molecular sieves in the hydrocracking of naphthalene to BTX

1.
Laboratory of Applied Catalysis and Green Chemical Engineering, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: ZHAO Liang-fu, lfzhao@sxicc.ac.cn
Received Date: 30 September 2016
Revised Date: 25 November 2016

Fund Project: Strategic Leading Science and Technology of Chinese Academy of Sciences XDA07020200and Leading Science and Technology of Chinese Academy of Sciences XDA07020400

Figures(11)

Micro-mesoporous Hβ/Al-SBA-15 composite molecular sieves was prepared by post-synthesis method and characterized by XRD, N₂ sorption, Py-FTIR, NH₃-TPD, SEM and TEM. With the Hβ/Al-SBA-15 composite as support, Ni-W/Hβ/Al-SBA-15 catalyst was prepared through impregnation and its catalytic performance in the hydrocracking of naphthalene to BTX was investigated. The results verified that the Hβ/Al-SBA-15 composite are provided with both micropores and mesopores. Both Bronsted acid and Lewis acid sites are present on the surface of Hβ/Al-SBA-15 and its acidity is stronger than that of SBA-15. After loading Ni and W, the Ni-W/Hβ/Al-SBA-15 catalyst with moderate acidity and micro-mesoporous structure exhibits high activity in the hydrocracking of naphthalene to BTX; the conversion of naphthalene reaches 96%, with the selectivity of 61.1% to BTX.
- micro-mesopore material,
- naphthalene,
- hydrocraking catalyst,
- BTX,
- Hβ/Al-SBA-15 composite,
- Ni-W
1. [1]
  DONG W L, JAE Y J, TAE W K, SANG E S, SUNG H B. Selective hydrodealkylation of C₉⁺ aromatics to benzene, toluene and xylenes (BTX) over a Pt/H-ZSM-5 catalyst[J]. J Mol Catal A:Chem, 2015,407:147-151. doi: 10.1016/j.molcata.2015.06.035
2. [2]
  ELFADLY A, ZEID I, YEHIA F, RABIE A, ABOUALALA M, PARK S. Highly selective BTX from catalytic fast pyrolysis of lignin over supported mesoporous silica[J]. Int J Biol Macromol, 2016,91:278-93. doi: 10.1016/j.ijbiomac.2016.05.053
3. [3]
  SULTANA A, FUJITANI T. Conversion of levulinic acid to BTX over different zeolite catalysts[J]. Catal Commun, 2017,88:26-29. doi: 10.1016/j.catcom.2016.09.023
4. [4]
  ZHU Rong, CHEN Hang-rong, SHI Jian-lin, YAN Dong-sheng. Synthesis and characterization of SBA-15 and SBA-16 templated by block copolymers[J]. J Inorg Mater, 2003,18(4):855-860.
5. [5]
  XU Feng, GU Jian-feng, GUAN Nai-jia, YUAN Zhong-yong. Magnesium modified ZSM-5/AlPO₄-5 composite zeolite for side-chain alkylation of toluene with methanol[J]. Acta Pet Sin (Pet Process Sect), 2008,346(4):346-349.
6. [6]
  XU Xin-long, SHEN Jian. Synthesis and characterization of composite molecular sieves Beta/SBA-15[J]. Fine Chem, 2014,31(5):591-596.
7. [7]
  LI Meng, FU Ji-quan. Synthesis of SBA-15 by using the dissolution of ZSM-5 zeolite[J]. J Beijing Univ Chem Technol (Nat Sci Ed), 2010,37(4):88-93.
8. [8]
  CORMA A. From microporous to mesoporous molecular sieve materials and their use in catalysis[J]. Chem Rev, 1997,97(6):2373-2419. doi: 10.1021/cr960406n
9. [9]
  WANG Hong-ping, ZHANG Ze-kai, CHEN Yin-fei. In situ synthesis of high-silica β zeolite over cordierite support and its application in catalytic combustion of toluene[J]. Petrkchem Technol, 2011,40(11):1158-1164.
10. [10]
  VU X H, URSULA B, MICHAEL H. Direct synthesis of nanosized-ZSM-5/SBA-15 analog composites from preformed ZSM-5 precursors for improved catalytic performance as cracking catalyst[J]. J Mater Sci, 2014,49(16):5676-5689. doi: 10.1007/s10853-014-8287-z
11. [11]
  XU Xin-long, SHEN Jian. Preparation of β/SBA-15 composite molecular sieves and their catalytic performances of the synthesis of tert-butyl phenol[J]. Petrkchem Technol, 2014,43(7):767-773.
12. [12]
  KRESGE C T, LEONOWICZ M E, ROTH W J, VARTULI J C, BECK J S. Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism[J]. Nature, 1992,359(22):710-712.
13. [13]
  CUI Q Y, ZHOU Y S, WEI Q, YU G L, ZHU L. Performance of Zr^- and P^-modified USY-based catalyst in hydrocracking of vacuum gas oil[J]. Fuel Process Technol, 2013,106:439-446. doi: 10.1016/j.fuproc.2012.09.010
14. [14]
  GANJALA V S P, NEELI C K P, PRAMOD C V. Eco-friendly nitration of benzenes over zeolite-β-SBA-15 composite catalyst[J]. Catal Commun, 2014,49:82-86. doi: 10.1016/j.catcom.2014.02.006
15. [15]
  LIU Bing-si, QIU Jian-guo, YUAN Xing-dong. Study of lumping kinetic model for hydrocracking[J]. Acta Pet Sin (Pet Process Sect), 1994,10(3):10-18.
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沈阳化工大学材料科学与工程学院沈阳 110142