Citation: Xiaoya Gao, Xubing Li, Chenho Tung, Lizhu Wu. Recent Advances in Quantum Dots Based Artificial Photosynthesis[J]. Chemistry, ;2021, 84(1): 10-15. shu

Recent Advances in Quantum Dots Based Artificial Photosynthesis

Xiaoya Gao ^{1, 2} ,
Xubing Li ^{1, 2,,} ,
Chenho Tung ^{1, 2, #} ,
Lizhu Wu ^{1, 2, #,,}

1.
Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, 100190
2.
School of Future Technology, University of Chinese Academy of Sciences, Beijing, 100049

Corresponding author: Xubing Li, lixubing@mail.ipc.ac.cn Lizhu Wu, lzwu@mail.ipc.ac.cn
Received Date: 6 August 2020
Accepted Date: 3 September 2020

Figures(3)

The facile conversion of H₂O or CO₂ into chemical fuels (such as H₂, CO) via semiconductor quantum dots (QDs) artificial photosynthesis is considered as an effective way to solve the energy and environmental crisis. Due to the unique photophysical and photochemical properties (e.g., excellent light absorption capacity, adjustable energy band structure, multi-exciton generation, abundant surface active sites, etc.), QDs have received much attention in the field of artificial photosynthesis in recent years. Here, we summarize our recent advances in chemical conversions via artificial photosynthesis using semiconductor QDs, and also provide prospects of future studies.
- Quantum dots,
- Artificial photosynthesis,
- Photocatalytic H₂ evolution,
- Photocatalytic CO₂ reduction,
- Organic transformation
1. [1]
  Armaroli N, Balzani V. Angew. Chem. Int. Ed., 2007, 46(1/2): 52~66.
2. [2]
  Gong J, Li C, Wasielewski M R. Chem. Soc. Rev., 2019, 48(7): 1862~1864.
3. [3]
  Antal T K, Krendeleva T E, Rubin A B. Appl. Microbiol. Biotechnol., 2011, 89(1): 3~15.
4. [4]
  Whang D R, Apaydin D H. ChemPhotoChem, 2018, 2(3): 148~160.
5. [5]
  Liu W, Cao L, Cheng W, et al. Angew. Chem. Int. Ed., 2017, 56(32): 9312~9317.
6. [6]
  Roger I, Shipman M A, Symes M D. Nat. Rev. Chem., 2017, 1(1): 0003.
7. [7]
8. [8]
  Yan Y, Crisp R W, Gu J, et al. Nat. Energy, 2017, 2(5): 17052.
9. [9]
  Robel I, Kuno M, Kamat P V. J. Am. Chem. Soc., 2007, 129(14): 4136~4137.
10. [10]
  Kundu S, Patra A. Chem. Rev., 2017, 117(2): 712~757.
11. [11]
  Li X B, Tung C H, Wu L Z. Nat. Rev. Chem., 2018, 2(8): 160~173.
12. [12]
13. [13]
  Li X B, Tung C H, Wu L Z. Angew. Chem. Int. Ed., 2019, 58(32): 10804~10811.
14. [14]
  Wu H L, Li X B, Tung C H, et al. Adv. Mater., 2019, 31(36): 1900709.
15. [15]
  Wang F, Wang W G, Wang X J, et al. Angew. Chem. Int. Ed., 2011, 50(14): 3193~3197.
16. [16]
  Jian J X, Liu Q, Li Z J, et al. Nat. Commun., 2013, 4: 2695.
17. [17]
  Li C B, Li Z J, Yu S, et al. Energy Environ. Sci., 2013, 6(9): 2597~2602.
18. [18]
  Wang F, Liang W J, Jian J X, et al. Angew. Chem. Int. Ed., 2013, 52(31): 8134~8138.
19. [19]
  Liang W J, Wang F, Wen M, et al. Chem. Eur. J., 2015, 21(8): 3187~3192.
20. [20]
  Jian J X, Ye C, Wang X Z, et al. Energy Environ. Sci., 2016, 9(6): 2083~2089.
21. [21]
  Wen M, Li X B, Jian J X, et al. Sci. Rep., 2016, 6: 29851.
22. [22]
  Li Z J, Li X B, Wang J J, et al. Energy Environ. Sci., 2013, 6(2): 465~469.
23. [23]
  Li Z J, Wang J J, Li X B, et al. Adv. Mater., 2013, 25(45): 6613~6618.
24. [24]
  Li Z J, Fan X B, Li X B, et al. J. Am. Chem. Soc., 2014, 136(23): 8261~8268.
25. [25]
  Wang J J, Li Z J, Li X B, et al. ChemSusChem, 2014, 7(5): 1468~1475.
26. [26]
  Fan X B, Yu S, Zhan F, et al. ChemSusChem, 2017, 10(24): 4833~4838.
27. [27]
  Fan X B, Yu S, Wu H L, et al. J. Mater. Chem. A, 2018, 6(34): 16328~16332.
28. [28]
  Huang M Y, Li X B, Gao Y J, et al. J. Mater. Chem. A, 2018, 6(14): 6015~6021.
29. [29]
  Yu S, Fan X B, Wang X, et al. Nat. Commun., 2018, 9: 4009.
30. [30]
  Wang J J, Wang J, Feng K, et al. J. Mater. Chem. A, 2017, 5(20): 9537~9543.
31. [31]
  Yu S, Li Z J, Fan X B, et al. ChemSusChem, 2015, 8(4): 642~649.
32. [32]
  Li Z J, Fan X B, Li X B, et al. J. Mater. Chem. A, 2017, 5(21): 10365~10373.
33. [33]
  Fan X B, Yu S, Wang X, et al. Adv. Mater., 2019, 31(7): 1804872.
34. [34]
  Wang Y, Ma Y, Li X B, et al. J. Am. Chem. Soc., 2020, 142(10): 4680~4689.
35. [35]
  Gao Y J, Li X B, Wang X Z, et al. Matter, 2020, 3(2): 571~585.
36. [36]
  Li X B, Gao Y J, Wang Y, et al. J. Am. Chem. Soc., 2017, 139(13): 4789~4796.
37. [37]
  Wang Y, Li X B, Wu H L, et al. ACS Sustain. Chem. Eng., 2019, 7(7): 7286~7293.
38. [38]
  Li X B, Gao Y J, Wu H L, et al. Chem. Commun., 2017, 53(41): 5606~5609.
39. [39]
  Guo Q, Liang F, Gao X Y, et al. ACS Catal., 2018, 8(7): 5890~5895.
40. [40]
  Gao Y J, Li X B, Wu H L, et al. Adv. Funct. Mater., 2018, 28(33): 1801769.
41. [41]
  Gao Y J, Yang Y C, Li X B, et al. Chem. Commun., 2018, 54(38): 4858~4861.
42. [42]
  Bowker M. Green Chem., 2011, 13(9): 2235~2246.
43. [43]
  Wolff C M, Frischmann P D, Schulze M, et al. Nat. Energy, 2018, 3(10): 862~869.
44. [44]
  Wang W, Chen J, Li C, et al. Nat. Commun., 2014, 5(1): 4647.
45. [45]
  Wu H L, Li X B, Tung C H, et al. Adv. Sci., 2018, 5(4): 1700684.
46. [46]
  Liu B, Li X B, Gao Y J, et al. Energy Environ. Sci., 2015, 8(5): 1443~1449.
47. [47]
  Wen M, Wu H L, Li X B, et al. Part. Part. Syst. Charact., 2018, 35(1): 1700278~1700282.
48. [48]
  Li X B, Liu B, Wen M, et al. Adv. Sci., 2016, 3(4): 1500282.
49. [49]
  Li J, Gao X, Liu B, et al. J. Am. Chem. Soc., 2016, 138(12): 3954~3957.
50. [50]
  Wu H L, Li X B, Wang Y, et al. J. Mater. Chem. A, 2019, 7(45): 26098~26104.
51. [51]
  Li X B, Li Z J, Gao Y J, et al. Angew. Chem. Int. Ed., 2014, 53(8): 2085~2089.
52. [52]
  Zhao L M, Meng Q Y, Fan X B, et al. Angew. Chem. Int. Ed., 2017, 56(11): 3020~3024.
53. [53]
  Jiang Y, Wang C, Rogers C R, et al. Nat. Chem., 2019, 11(11): 1034~1040.
54. [54]
  Zhang Z, Edme K, Lian S, et al. J. Am. Chem. Soc., 2017, 139(12): 4246~4249.
55. [55]
  Pal A, Ghosh I, Sapra S, et al. Chem. Mater., 2017, 29(12): 5225~5231.
56. [56]
  Caputo J A, Frenette L C, Zhao N, et al. J. Am. Chem. Soc., 2017, 139(12): 4250~4253.
57. [57]
  Guo Q, Liang F, Li X B, et al. Chem, 2019, 5(10): 2605~2616.
58. [58]
  Hao H, Lang X. ChemCatChem, 2019, 11(5): 1378~1393.
59. [59]
  Lu H, Huang Z, Martinez M S, et al. Energy Environ. Sci., 2020, 13(5): 1347~1376.
60. [60]
  Huang C, Li X B, Tung C H, et al. Chem. Eur. J., 2018, 24(45): 11530~11534.
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沈阳化工大学材料科学与工程学院沈阳 110142