Citation: Ge Fang, Zhu Yanyun, Xian Mo, Wang Xiaowu. Iron-Based Complexes: Applications in 1, 3-Diene Monomers Homogeneous Coordination-Insertion Polymerization Catalysis[J]. Chemistry, ;2020, 83(5): 404-417. shu

Iron-Based Complexes: Applications in 1, 3-Diene Monomers Homogeneous Coordination-Insertion Polymerization Catalysis

Ge Fang ² ,
Zhu Yanyun ² ,
Xian Mo ¹ ,
Wang Xiaowu ^1,,

1.
Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, 266101
2.
College of Chemistry and Chemical Engineering, Qingdao University, Qingdao, 266071

Corresponding author: Wang Xiaowu, wangxw@qibebt.ac.cn
Received Date: 30 December 2019
Accepted Date: 15 January 2020

Figures(6)

There is an urgent need to develop catalysts in line with environmental concerns. The abundant and non-toxic dual character of the iron element is fully consistent with this trend. In the past decades, catalysis based on well-defined iron complexes has experienced a very rapid growth. After the pioneering work of Gibson and Brookhart related to the polymerization of ethylene, it appeared in the literature an increasing number of studies on the coordination-insertion polymerization of 1, 3-dienes using iron-based catalytic systems. The purpose of this review is to provide an update in this field by examining the catalytic systems developed in recent years. Particular emphasis is placed on those involving discrete complexes through their structure and catalytic performance, in terms of both activity and selectivity (when relevant) as well as their limitations.
- Iron,
- Well-defined complexes,
- Coordination-insertion polymerization,
- 1,
- 3-Dienes
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Iron-Based Complexes: Applications in 1, 3-Diene Monomers Homogeneous Coordination-Insertion Polymerization Catalysis

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com