Citation: MENG Jun-guang, WANG Xiao-bo, ZHAO Zeng-li, ZHENG An-qing, LI Hai-bin. Effects of modified olivine on the CO₂ reforming of toluene[J]. Journal of Fuel Chemistry and Technology, ;2017, 45(3): 295-302. shu

Effects of modified olivine on the CO₂ reforming of toluene

1.
The Key Laboratory of Renewable Energy of Chinese Academy of Sciences, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: WANG Xiao-bo, wangxb@ms.giec.ac.cn
Received Date: 14 November 2016
Revised Date: 6 January 2017

Fund Project: the National Natural Science Foundation of China 51506208the Projects of International Cooperation and Exchanges NSFC 51661145011

Figures(9)

An olivine catalyst was tested in a fixed bed reactor in CO₂ reforming of the toluene as a tar model molecule produced during biomass gasification. The olivine catalyst was characterized by XRD, SEM, BET, H₂-TPR; and the effects of the operating parameters (reforming reaction temperature and CO₂ concentration) and catalyst preparation parameters (calcination temperature and nickel content) on the activity and selectivity for toluene conversion were examined. The results show that the olivine catalyst can increase the toluene conversion and lower the carbon formation. The toluene conversion also increases with the reforming temperature rise. The calcined olivine reaches the highest activity when the calcination temperature is 900℃. The CO₂ addition can reduce the carbon formation obviously by 17.0% when the CO₂/C₇H₈ molar ratio is 4. Moreover, the Ni/olivine catalyst has a better performance and the toluene conversation is up to 99.4%, while the carbon formation increases a little bit.
- modified olivine,
- toluene,
- CO₂,
- catalytic reforming
1. [1]
  ABDOULMOUMINE N, ADHIKARI S, KULKARMI A, CHATTANATHAN S. A review on biomass gasification syngas cleanup[J]. Appl Energy, 2015,155:294-307. doi: 10.1016/j.apenergy.2015.05.095
2. [2]
  ZHANG Shu, CHEN Zong-ding, XU Min, XU De-ping, WANG Yong-gang. Review on technology development for tar removal/catalytical reforming during coal gasification[J]. Coal Sci Technol, 2014,42(1):106-111.
3. [3]
  YUNG M M, JABLONSKI W S, MAGRINI-BAIR K A. Review of catalytic conditioning of biomass-derived syngas[J]. Energy Fuels, 2009,23(4):1874-1887. doi: 10.1021/ef800830n
4. [4]
  WU You, ZHAO Li-xin, MENG Hai-bo, CONG Hong-bin, YAO Zong-lu, HOU Shu-lin. Research progresses on removal of tar in biomass pyrolysis[J]. Environ Prot Chem Ind, 2016,36(1):17-21.
5. [5]
  DEVI L, CRAJE M, THÜNE P, PTASINSKI K J, JANSSEN F J J G. Olivine as tar removal catalyst for biomass gasifiers:Catalyst characterization[J]. Appl Catal A:Gen, 2005,294:68-79. doi: 10.1016/j.apcata.2005.07.044
6. [6]
  VIRGINIE M, ADANEZ J, COURSON C, DIEGO L F, LABIANO F G, NIZNANSKY D, KIENNEMANN A, GAYAN P, ABAD A. Effect of Fe-olivine on the tar content during biomass gasification in a dual fluidized bed[J]. Appl Catal B:Environ, 2012,121:214-222.
7. [7]
  YUE Bao-hua, BU Xian-ni, WANG Xue-guang, DING Wei-zhong. Effect of calcination temperature on catalytic performance of olivine for toluene cracking[J]. CIESC J, 2009,60(2):378-383.
8. [8]
  WEI Li-gang, XU Shao-ping, LIU Chang-hou, LIU Shu-qin. Effects of precalcination on catalytic activity of olivine in biomass gasification[J]. J Fuel Chem Technol, 2008,36(4):426-430.
9. [9]
  VIRGINIE M, COURSON C, KIENNEMANN A. Toluene steam reforming as tar model molecule produced during biomass gasification with an iron/olivine catalyst[J]. Comptes Rendus Chimie, 2010,13(10):1319-1325. doi: 10.1016/j.crci.2010.03.022
10. [10]
  CHEAH S, GAGTON K R, PARENT Y O, JARVIS M W, VINZANT T B, SMITH K M, THORNBURG N E, NIMLOS M R, MAGRINI-BAIR K A. Nickel cerium olivine catalyst for catalytic gasification of biomass[J]. Appl Catal B:Environ, 2013,134:34-45.
11. [11]
  YANG Xiao-qin, XU Shao-ping, HU Guan, LIU Chang-hou. Effects of olivines from different quarries on the steam reforming of benzene[J]. Chin J Catal, 2009,30(6):497-502.
12. [12]
  RAUCH R, BOSCH K, SWIERCZYNSKI D, COURSON C, KIENNEMANN A. Comparison of different olivines for biomass steam gasification[M]. na, 2004.
13. [13]
  SWIERCZYNSKI D, COURSON C, BEDEL L, KIENNEMANN A, VILMINOT S. Oxidation reduction behavior of iron-bearing olivines (Fe_x Mg_1-x) 2SiO₄ used as catalysts for biomass gasification[J]. Chem Mater, 2006,18(4):897-905. doi: 10.1021/cm051433+
14. [14]
  CHRISTODOULOU C, GRIMEKIS D, PANOPOULOS K D, PACHATOURIDOU E P, ILIOPOULOU E F, KAKARAS E. Comparing calcined and un-treated olivine as bed materials for tar reduction in fluidized bed gasification[J]. Fuel Process Technol, 2014,124:275-285. doi: 10.1016/j.fuproc.2014.03.012
15. [15]
  WANG Hui, YANG Hai-feng, RAN Xin-quan, WEN Zhen-yi, SHI Qi-zhen. AM1 thermodynamic research of the pyrolysis mechanism of toluene (Ⅰ)[J]. Chin J Inorg Chem, 2001,17(4):538-544.
16. [16]
  KONG Meng. Carbon dioxide reforming of tolueneas a model compound of tar from biomass-derived syngas over Ni catalyst[D]. Hangzhou:Zhejiang Univisity, 2012.
17. [17]
  KONG M, YANG Q, FEI J H, ZHENG X M. Experimental study of Ni/MgO catalyst in carbon dioxide reforming of toluene, a model compound of tar from biomass gasification[J]. Int J Hydrogen Energy, 2012,37(18):13355-13364. doi: 10.1016/j.ijhydene.2012.06.108
18. [18]
  LI Lan-lan, ZHENG An-qing, FENG Yi-peng, MENG Jun-guang, ZHAO Zeng-li, LI Hai-bin. Effects of olivine on the catalytic reforming of toluene[J]. J Fuel Chem Technol, 2015,43(7):806-815.
19. [19]
  YANG X X, XU S P, XU H L, LIU X D, LIU C H. Nickel supported on modified olivine catalysts for steam reforming of biomass gasification tar[J]. Catal Commun, 2010,11(5):383-386. doi: 10.1016/j.catcom.2009.11.006
20. [20]
  SHI Pei-chao, CHEN Tian-hu, ZHANG Xian-long, CHEN Dong, SONG Lei, LI Zong-hu. CO₂ reforming of toluene from biomass tar over Ni/palygorskite catalast[J]. Chin J Catal, 2010,31(10):1281-1285.
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沈阳化工大学材料科学与工程学院沈阳 110142

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Effects of modified olivine on the CO₂ reforming of toluene