Citation: Haixi Tian, Lin Mao, Guoqiang Xu, Xiaoyue Luo, Hui Li. Synthesis and Adsorption Performance of Pinoresinol Diglucoside Imprint-Modified Metal Organic Frame Composites[J]. Chemistry, ;2021, 84(6): 571-577. shu

Synthesis and Adsorption Performance of Pinoresinol Diglucoside Imprint-Modified Metal Organic Frame Composites

Haixi Tian ¹ ,
Lin Mao ¹ ,
Guoqiang Xu ¹ ,
Xiaoyue Luo ¹ ,
Hui Li ^{1, 2,,}

1.
College of Chemistry and Chemical Engineering, Jishou University, Jishou, 416000
2.
National and Local United Engineering Laboratory of Integrative Utilization of Eucommia ulmoides, Jishou University, Jishou, 416000

Corresponding author: Hui Li, lihuijsdx@163.com
Received Date: 16 November 2020
Accepted Date: 26 December 2020

Figures(9)

A molecular imprinted polymer (MIP)-modified MIL-101 metal-organic frame composites (MIPs@ED-MIL-101) was fabricated for selective analysis of pinoresinol diglucosides (PDG). This PDG-imprinted MIPs@ED-MIL-101 composite was characterized in crystal structure, surface chemical group and particle morphology by XRD, FT-IR and SEM. The adsorption kinetics, selectivity and solid phase extraction performance of MIPs@ED-MIL-101 composite for template molecules were tested. Results showed that the MIPs@ED-MIL-101 composite has greatly improved adsorption performance for PDG, and can be used to selectively adsorb PDG from the simulated mixture. When this MIPs@ED-MIL-101 composite was used as adsorbent for the extraction and separation of PDG from crude extract of Eucommia ulmoides, the purity of obtained product was 85.3%. Also, this novel material can also be reused for many times with a slight loss in adsorption capacity.
- Metal organic frameworks MIL-101,
- Post-synthetic modification,
- Imprint modification,
- Pinoresinol diglucoside,
- Adsorption
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沈阳化工大学材料科学与工程学院沈阳 110142