Citation: MA Bao-li, XU Tie-gang, HAN Zhi-bo, ZHANG Wen-cheng, GUO Jin-tao. Application of plant fiber filament in NiMo diesel hydrodesulfurization catalyst[J]. Journal of Fuel Chemistry and Technology, ;2019, 47(7): 863-869. shu

Application of plant fiber filament in NiMo diesel hydrodesulfurization catalyst

Petro China Daqing Chemical Research Centre of Petrochemical Research Institute, Daqing 163714, China

Corresponding author: MA Bao-li, mbl459@petrochina.com.cn
Received Date: 15 March 2019
Revised Date: 6 May 2019

Fund Project: The project was supported by National Key R&D Program of China (2017YFB0306600)National Key R&D Program of China 2017YFB0306600

Figures(8)

The micron-sized plant fiber filaments were used as templates to obtain cylindrical macropores during the gamma alumina support preparation. The support was then used to prepare the NiMo/alunima diesel hydrodesulfurization catalyst. The prepared catalyst and alumina support were characterized by BET, XRD, SEM, Ruman and TEM. The characterization results showed that the plant fiber filaments in the catalyst constructed some straight holes, the NiMo active components on the catalyst support were highly dispersed and the active phase MoS₂ stacked layers were mainly concentrated in 3-5 layers and the average length of MoS₂ bars was 4.49 nm. The influence of plant fiber filament content on the performance of diesel hydrodesulfurization catalyst was studied and compared with conventional catalysts. The high-pressure micro-reverse evaluation results show that the developed NiMo diesel hydrotreating catalyst containing 3% (mass ratio) plant fiber filament has 5%-15% higher activity than the conventional NiMo catalyst.
- hydrotreating,
- catalyst,
- plant solid fiber filament,
- diesel
1. [1]
  ZENG Yan. National energy administration:The Ⅵ standard of oil product countries is expected to be implemented in 2019[J]. Nat Gas Oil, 2016,34(2)17.
2. [2]
  WANG Jian, ZHANG Yang, CHU Yu, LU Xue-bin. Discussion on the quality upgrading scheme of diesel products[J]. Contemp Chem Ind, 2018,47(3):635-638. doi: 10.3969/j.issn.1671-0460.2018.03.052
3. [3]
  ZHANG Le, LI Ming-feng, NIE Hong, LI Hui-feng, WANG Zhe, HU Zhi-hai, LIU Xue-fen, DING Shi. Development and application of higly avtive ultra deep diesel HDS catalyst RS-2100 and RS-2200[J]. Pet Process Petrochem, 2017,48(6):1-6. doi: 10.3969/j.issn.1005-2399.2017.06.001
4. [4]
  LI Shi-cai, ZHANG Bin, JIANG Xue-zhang. Commercial application results of diesel(Ⅴ) production unit using FH-UDS catalyst[J]. Modern Chem Ind, 2017,46(11):2313-2315. doi: 10.3969/j.issn.1671-0460.2017.11.037
5. [5]
  WANG Dan, SONG Jin-he, HAN Zhi-bo, WEN Guang-ming, ZHANG Wen-cheng. Development and commercial application of diesel hydrotreating catalyst[J]. Petro Chem Ind, 2017,46(2):241-247. doi: 10.3969/j.issn.1000-8144.2017.02.017
6. [6]
  LIU Li, GUO Rong, SUN Jin, DING Li, YANG Cheng-min, DUAN Wwei-yu, YAO Yun-hai. The research development of diesel hydrodesulfurization catalysts[J]. Chem Ind Eng Prog, 2016,35(11):3503-3510.
7. [7]
  YANG Wei-ya, LING Feng-xiang, ZHANG Hui-cheng, WANG Shao-jun, SHEN Zhi-qi. Synthe sis and characte rization of hie rarchically porous alumina with thre e-dime nsional inte rconne cte d pore structure[J]. J Fuel Chem Technol, 2018,46(5):558-563. doi: 10.3969/j.issn.0253-2409.2018.05.007
8. [8]
  LI Hong, CHEN Sheng-li, DONG Peng, ZHOU Qian. Preparation, characterization and catalytic performance of novel macroporous catalysts for heavy oil hydrogenation[J]. J Fuel Chem Technol, 2009,37(4):444-447. doi: 10.3969/j.issn.0253-2409.2009.04.011
9. [9]
  WANG Huai-yuan, ZHU You-zhuang, ZHAO Jing-yan, CHENG Xiao-shuang, ZHANG Zhi-hua. Effect of charateristics of TiO2 carrier on performance of dibenzothiopene hydrodesulfurization[J]. J Chem Ind Eng, 2013,64(7):2462-2467. doi: 10.3969/j.issn.0438-1157.2013.07.021
10. [10]
  ZHANG Mei-yun, SU Zhi-ping, LU Zhao-qing, ZHANG Mei-juan. Effect of the fibrillation of plant fibers on the structure and properties of its porous composite material[J]. J Shanxi Univ Sci Technol, 2017,35(1):1-5. doi: 10.3969/j.issn.1000-5811.2017.01.001
11. [11]
  ZHU Chong-ye, NIU Guo-xing, CHEN Hai-ying, LI Quan-zhi, LU Qiu-yun, WANG Jia-huan, FANG Wei-ping. Surface species structure of nickel-molybdenum hydrotreating catalyst[J]. J Fudan Univ (Sci Technol), 1995,34(5):490-500.
12. [12]
  ZHANG Cheng, WANG Yong-lin, YANG Chun-yan, SUI Bao-kuan, YANG Gang, ZHAO Guo-li. Characterization of active phase of Ni Mo/TiO₂-Al₂O₃ catalyst and its performance in hydrodesulphurization reaction[J]. Ind Catal, 2012, 20(5):31-35.
13. [13]
  YUAN Hui, XU Guang-tong, QI He-rima, LI Hui-feng, LU Li-jun, YANG Xing-yuan, TA Na. Laser Raman spectra study on Co-Mo/Al₂O₃ hydrodesulphurization catalysts[J]. Spectrosc Spectral Anal, 2014,34(2):435-438. doi: 10.3964/j.issn.1000-0593(2014)02-0435-04
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沈阳化工大学材料科学与工程学院沈阳 110142