Citation: Wang Jun, Jing Xuewei, Jiang Yan, Chen Liduo. Synthesis and Catalytic Performance of Dendritic Pyridineimine Chromium Catalyst[J]. Chemistry, ;2019, 82(2): 138-143. shu

Synthesis and Catalytic Performance of Dendritic Pyridineimine Chromium Catalyst

1.
Provincial Key Laboratory of Oil & Gas Chemical Technology, College of Chemistry & Chemical Engineering, Northeast Petroleum University, Daqing 163318
2.
Daqing Chemical Research Center of Petro China Petrochemical Research Institute, Daqing 163714

Received Date: 2 August 2018
Accepted Date: 20 September 2018

Figures(8)

A novel dendritic pyridineimine ligand DPI was synthesized using 1.0G dendritic polyamide-amine and pyridine dialdehyde as the raw materials, and the dendritic pyridineimine chromium (DPI-Cr) catalyst was synthesized with chromium chloride hexahydrate complex as reagent. The structure of the DPI-Cr catalyst was fully characterized by FT-IR, UV-Vis, MS and element analysis. The effect of solvent type, co-catalyst type, reaction temperature, reaction pressure and Al/Cr molar ratio on the catalytic performance in ethylene oligomerization was detected in detail. The results showed that the DPI-Cr catalyst displays better catalytic activity and olefine selectivity. Under the optimal reaction conditions, the catalytic activity could reach up to 4.91×10⁴ g/(molCr·h), and the selectivity of C₆ and C₈ was 73.90%.
- Dendrimers,
- Pyridineimine ligand,
- Chromium catalyst,
- Ethylene oligomerization
1. [1]
  D A Tomalia, J M J Fréchet. J. Poly. Sci. A, 2010, 40(16): 2019~2728.
2. [2]
  P A Chase, R J M K Gebbink, G V Koten. J. Org. Chem., 2004, 689(24): 4016~4054.
3. [3]
  M Prabaharan, J J Grailer, S Pilla et al. Biomaterials, 2009, 30(16): 3009~3019.
4. [4]
  Y H Kim, O Webster. J. Macromol. Sci. Polym. Rev., 2002, C42(1): 55~89.
5. [5]
  Y Bai, N Song, J P Gao et al. J. Am. Chem. Soc., 2005, 127(7): 2060~2061.
6. [6]
  Y Shen, M Kuang, Z Shen et al. Angew. Chem. Int.Ed., 2008, 47(12): 2227~2230.
7. [7]
  R Malgas, S F Mapolie, S O Ojwach et al. Catal. Commun., 2008, 9(7): 1612~1617.
8. [8]
  T V Laine, U Piironen, K Lappalainen et al. J. Organomet. Chem., 2000, 606(2): 112~124.
9. [9]
  R Malgas, S F Mapolie, S O Ojwach et al. Catal. Commun., 2008, 9(7): 1612~1617.
10. [10]
11. [11]
  A Bollmann, K Blann, J T Dixon et al. J. Am. Chem. Soc., 2004, 126(45): 14712~3.
12. [12]
  K Blann, A Bollmann, J T Dixon et al. Chem. Commun., 2005, 5(5): 620~621.
13. [13]
14. [14]
  J Wang, P Zang, S Chen et al. J. Macromol. Sci. A, 2013, 50(2): 163~167.
15. [15]
  A Aid, R D Andrei, S Amokrane et al. Appl. Clay Sci., 2017, 146: 432~438.
16. [16]
  W H Sun, S Song, B Li et al. Dalton Transac., 2012, 41(39): 11999~2010.
17. [17]
  S D McGuinness, J A Rucklidge, R P Tooze et al. Organometallics, 2007, 26(10): 2561~2569.
18. [18]
  S Kuhlmann, J T Dixon, M Haumann et al. Adv. Synth. Catal., 2006, 348(10/11): 1200~1206.
19. [19]
  J M Benito, E de Jesús, F J de la Mata et al. Chem. Commun., 2005, 41(41): 5217~5219.
20. [20]
  R Malgas-Enus, S F Mapolie. Inorg. Chim. Acta, 2015, 428(2): 212~212.
21. [21]
22. [22]
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沈阳化工大学材料科学与工程学院沈阳 110142