Citation: Jin Dan, Zhao Zhigang, Meng Han, Huang Congying, Fang Mougui. Synthesis, Structure and Optical Property of a New Pyridinium Salt[J]. Chemistry, ;2019, 82(8): 758-761. shu

Synthesis, Structure and Optical Property of a New Pyridinium Salt

School of Pharmacy, Wannan Medical College, Wuhu 241002

Corresponding author: Jin Dan, jindande@126.com
Received Date: 22 February 2019
Accepted Date: 12 April 2019

Figures(5)

A new compound, 4-[2-(3, 4-dimethoxyphenyl)ethenyl]-N-methylpyridinium perchlorate, was synthesized by the reaction of pyridinium salt with 3, 4-dimethoxybenzaldehyde in methanol. The structure of the compound was determined by IR, elemental analysis, ¹H NMR and ESI-MS. The crystal structure of the compound was further determined by X-ray single crystal diffraction. The crystal belongs to orthorhombic system with space group P_bca, a=13.5897(11)nm, b=13.9126(11)nm, c=17.3485(14)nm, α=90°, β=90°, γ=90°, M_r=355.76, V=3280.0(5)nm³, Z=8, F(000)=1488, D_c=1.181 g/cm³, μ=0.265mm^-1. Meanwhile, the optical property of the titled compound was also studied.
- Pyridinium salt,
- Synthesis,
- Crystal structure,
- Optical property
1. [1]
  G S He, L X Yuan, Y P Cui et al. J. Appl. Phys., 1997, 81(6):2529~2537.
2. [2]
  M Albota, D Belionne. Science, 1998, 281:1653~1656.
3. [3]
  Y Ren, Q Fang, W T Yu et al. J. Mater. Chem., 2000, 10:2025~2030.
4. [4]
  B H Cumpston, S P Ananthavel, S R Marder et al. Nature, 1999, 398:51~57.
5. [5]
6. [6]
7. [7]
8. [8]
  D H Choi, W M K P Wijekoon, H M Kim et al. Chem. Mater., 1994, 6:234~238.
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
  D Jin, D C Zhang. Acta Cryst., 2005, C61:o657~o659.
15. [15]
  D Jin, F Zhang, Y Zhang et al. Acta Cryst., 2005, E61:o3618~o3620.
16. [16]
  D Jin, Z F Dai, D C Zhang. Acta Cryst., 2008, C64:o50~o52.
17. [17]
  G M Sheldrick. SHELXS-2014, University of Göttingen, Germany.
18. [18]
  G M Sheldrick. SHELXL-2014, University of Göttingen, Germany.
19. [19]
20. [20]
  G S He, L X Yuan, P N Prasad et al. Opt. Commun., 1997, 140:49~52.
1. [1]
  Ke-Ai Zhou , Lian Huang , Xing-Ping Fu , Li-Ling Zhang , Yu-Ling Wang , Qing-Yan Liu . Fluorinated metal-organic framework for methane purification from a ternary CH4/C2H6/C3H8 mixture. Chinese Journal of Structural Chemistry, 2023, 42(11): 100172-100172. doi: 10.1016/j.cjsc.2023.100172
2. [2]
  Muhammad Riaz , Rakesh Kumar Gupta , Di Sun , Mohammad Azam , Ping Cui . Selective adsorption of organic dyes and iodine by a two-dimensional cobalt(II) metal-organic framework. Chinese Journal of Structural Chemistry, 2024, 43(12): 100427-100427. doi: 10.1016/j.cjsc.2024.100427
3. [3]
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5. [5]
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17. [17]
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18. [18]
  Zhiwei Chen , Heyun Sheng , Xue Li , Menghan Chen , Xin Li , Qiuling Song . Efficient capture of difluorocarbene by pyridinium 1,4-zwitterionic thiolates: A concise synthesis of difluoromethylene-containing 1,4-thiazine derivatives. Chinese Chemical Letters, 2024, 35(4): 108937-. doi: 10.1016/j.cclet.2023.108937
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20. [20]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084

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沈阳化工大学材料科学与工程学院沈阳 110142