Citation: WEI Guo-qiang, HE Fang, ZHAO Zeng-li, ZHAO Wei-na, HUANG Zhen, ZHENG An-qing, ZHAO Kun, FENG Yi-peng, LI Hai-bin. Chemical looping gasification of biomass based on the oxygen carrier derived from the layered double hydroxide (LDH) precursor[J]. Journal of Fuel Chemistry and Technology, ;2016, 44(3): 349-356. shu

Chemical looping gasification of biomass based on the oxygen carrier derived from the layered double hydroxide (LDH) precursor

1.
CAS Key Laboratory of Renewable Energy, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences (CAS), Guangzhou 510640, China
2.
Guangdong Mechanical & Electrical College, Guangzhou 510515, China

Corresponding author: HE Fang, hefang@ms.giec.ac.cn
Received Date: 23 August 2015
Revised Date: 30 November 2015

Fund Project: National Natural Science Foundation of China 51406214and the Science and Technology Planning Project of Guangdong Province 2015A020215023

Figures(5)

Layered double hydroxide (LDH) precursors with different metal elements were prepared by co-precipitation method at constant pH value; highly dispersed Cu/Al/Zn, Cu/Al/Ni and Cu/Al/Ni/Zn mixed metal oxygen carriers were obtained by calculation of the corresponding precursors. These oxygen carriers were characterized by XRD, XRF, H₂-TPR, SEM and nitrogen adsorption and their activity in the chemical looping gasification (CLG) of biomass was investigated in a fixed bed reactor. The results indicated that typical hydrotalcite structure appears in the three precursors with stable layer board. The interlayer spacing of Cu/Al/Zn precursor is 0.2642nm, larger than that of the Cu/Al/Ni precursor. The oxygen carriers derived from the corresponding precursors display similar elements contents as the preparation reagents. Due to the synergy among various metals, the Cu/Al/Ni/Zn oxygen carrier shows the highest reaction activity and anti-sintering ability. The addition of Ni and Zn has a positive effect on the activity of CuO and reduce its reduction temperature; Zn shows a better synergistic effect than Ni with Cu. The carbon conversion reaches 82.03% for the CLG of biomass with Cu/Al/Ni/Zn as oxygen carrier; the surface area of Cu/Al/Ni/Zn remanis 5.995m²/g after the CLG reaction, suggesting that it could be an ideal candidate for the CLG of biomass.
- layered double hydroxide,
- hydrotalcite,
- chemical looping gasification,
- oxygen carrier,
- biomass
1. [1]
  RICHTER H, KNOCHE K, RICHTER H, KNOCHE K. Reversibility of combustion processes[J]. ACS Symp Ser, 1983,235(3):71-86.
2. [2]
  UDOMSIRICHAKORN J, BASU P, ABDUL SALAM P, ACHARYA B. CaO-based chemical looping gasification of biomass for hydrogen-enriched gas production with in situ CO₂ capture and tar reduction[J]. Fuel Process Technol, 2014,127:7-12. doi: 10.1016/j.fuproc.2014.06.007
3. [3]
  HUANG Z, HE F, FENG Y, ZHAO K, ZHENG A, CHANG S, LI H. Synthesis gas production through biomass direct chemical looping conversion with natural hematite as an oxygen carrier[J]. Bioresour Technol, 2013,140:138-145. doi: 10.1016/j.biortech.2013.04.055
4. [4]
  TIAN H, FISHER J C. Isotopic steam investigations of hematite (Fe₂O₃) for chemical looping combustion of methane[J]. Catal Commun, 2015,67:83-86. doi: 10.1016/j.catcom.2015.04.015
5. [5]
  MEI D, ABAD A, ZHAO H, ADÁNEZ J. Characterization of a sol-gel derived CuO/CuAl₂O₄ oxygen carrier for chemical looping combustion (CLC) of gaseous fuels: Relevance of gas-solid and oxygen uncoupling reactions[J]. Fuel Process Technol, 2015,133:210-219. doi: 10.1016/j.fuproc.2015.02.007
6. [6]
  SHEN L H, WU J H, XIAO J. Experiments on chemical looping combustion of coal with a NiO based oxygen carrier[J]. Combust Flame, 2009,156(3):721-728. doi: 10.1016/j.combustflame.2008.08.004
7. [7]
  FORUTAN H R, KARIMI E, HAFIZI A, RAHIMPOUR M R, KESHAVARZ P. Expert representation chemical looping reforming: A comparative study of Fe, Mn, Co and Cu as oxygen carriers supported on Al₂O₃[J]. J Ind Eng Chem, 2015,21:900-911. doi: 10.1016/j.jiec.2014.04.031
8. [8]
  ADáNEZ-RUBIO I, GAYÁN P, ABAD A, DE DIEGO L F, GARCÍA-LABIANO F, ADÁNEZ J. Evaluation of a spray-dried CuO/MgAl₂O₄ oxygen carrier for the chemical looping with oxygen uncoupling process[J]. Energy Fuels, 2012,26(5):3069-3081. doi: 10.1021/ef3002229
9. [9]
  SIRIWARDANE R, TIAN H, MILLER D, RICHARDS G. Fluidized bed testing of commercially prepared MgO-promoted hematite and CuO-Fe₂O₃ mixed metal oxide oxygen carriers for methane and coal chemical looping combustion[J]. Appl Energy, 2015,157:348-357. doi: 10.1016/j.apenergy.2015.04.042
10. [10]
  LI K Z, WANG H, WEI Y G, YAN D X. Direct conversion of methane to synthesis gas using lattice oxygen of CeO₂-Fe₂O₃ complex oxides[J]. Chem Eng J, 2010,156(3):512-518. doi: 10.1016/j.cej.2009.04.038
11. [11]
  LIU Jie-xiang, ZHANG Xiang-guang. Theoretical investigation on the structure of anions intercalated MgAl-layered double hydroxides and the interaction between anions and host layer[J]. J Fuel Chem Technol, 2013,41(6):761-768.
12. [12]
  WANG L, DALIN L, WATANABE H, TAMURA M, NAKAGAWA Y, TOMISHIGE K. Catalytic performance and characterization of Co/Mg/Al catalysts prepared from hydrotalcite-like precursors for the steam gasification of biomass[J]. Appl Catal B: Environ, 2014,150:82-92.
13. [13]
  SONG Q L, LIU W, CHRISTOPHER D B, RYAN N H, EASAN S, STUART A S, JOHN S D. A high performance oxygen storage material for chemical looping processes with CO₂ capture[J]. Energy Environ Sci, 2013,6(1):288-298. doi: 10.1039/C2EE22801G
14. [14]
  LONG H, XU Y, ZHANG X Q, HU S J, SHANG S Y, YIN Y X, DAI X Y. Ni-Co/Mg-Al catalyst derived from hydrotalcite-like compound prepared by plasma for dry reforming of methane[J]. J Energy Chem, 2013,22(5):733-739. doi: 10.1016/S2095-4956(13)60097-2
15. [15]
  LI B S, YUAN S L. Synthesis, characterization, and evaluation of TiMgAlCu mixed oxides as novel SO_x removal catalysts[J]. Ceram Int, 2014,40(8):11559-11566. doi: 10.1016/j.ceramint.2014.03.112
16. [16]
  GALINDO R, LÓPEZ-DELGADO A, PADILLA I, YATES M. Hydrotalcite-like compounds: A way to recover a hazardous waste in the aluminium tertiary industry[J]. Appl Clay, 2014,95:41-49. doi: 10.1016/j.clay.2014.03.022
17. [17]
  BHUIYAN M R, LIN S D, HSIAO T C. Effect of calcination on Cu-Zn-loaded hydrotalcite catalysts for C-C bond formation derived from methanol[J]. Catal Today, 2014,226:150-159. doi: 10.1016/j.cattod.2013.10.053
18. [18]
  DALIN L, KOIKE M, CHEN J H, NAKAGAWA Y, TOMISHIGE K. Preparation of Ni-Cu/Mg/Al catalysts from hydrotalcite-like compounds for hydrogen production by steam reforming of biomass tar[J]. Int J Hydrogen Energy, 2014,39(21):10959-10970. doi: 10.1016/j.ijhydene.2014.05.062
19. [19]
  SIRIWARDANE R, TIAN H J, SIMONYI T, POSTON J. Synergetic effects of mixed copper-iron oxides oxygen carriers in chemical looping combustion[J]. Fuel, 2013,108:319-333. doi: 10.1016/j.fuel.2013.01.023
20. [20]
  HUANG Z, HE F, FENG Y P, ZHAO K, ZHENG A Q, CHANG S, WEI G Q, ZHAO Z L, LI H B. Biomass char direct chemical looping gasification using NiO-modified iron ore as an oxygen carrier[J]. Energy Fuels, 2014,28(1):183-191. doi: 10.1021/ef401528k
21. [21]
  ZHU Xi-feng. Biomass Pyrolysis Principle and Technology[M]. Hefei: University of Science and Technology of China Press, 2006.
22. [22]
  LUCRÉDIO A F, ASSAF J M, ASSAF E M. Reforming of a model sulfur-free biogas on Ni catalysts supported on Mg (Al) O derived from hydrotalcite precursors: Effect of La and Rh addition[J]. Biomass Bioenergy, 2014,60:8-17. doi: 10.1016/j.biombioe.2013.11.006
23. [23]
  GAO P, LI F, XIAO F K, ZHAO N, WEI W, ZHONG L S, SUN Y H. Effect of hydrotalcite-containing precursors on the performance of Cu/Zn/Al/Zr catalysts for CO₂ hydrogenation: Introduction of Cu²⁺ at different formation stages of precursors[J]. Catal Today, 2012,194(1):9-15. doi: 10.1016/j.cattod.2012.06.012
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