Citation: GUO Hai-jun, LI Qing-lin, ZHANG Hai-rong, XIONG Lian, PENG Fen, YAO Shi-miao, CHEN Xin-de. Attapulgite supported Cu-Fe-Co based catalyst combination system for CO hydrogenation to lower alcohols[J]. Journal of Fuel Chemistry and Technology, ;2019, 47(11): 1346-1356. shu

Attapulgite supported Cu-Fe-Co based catalyst combination system for CO hydrogenation to lower alcohols

GUO Hai-jun ^1,2,3,4 ,
LI Qing-lin ^1,5 ,
ZHANG Hai-rong ^1,2,3,4 ,
XIONG Lian ^1,2,3,4 ,
PENG Fen ^1,2,3,4 ,
YAO Shi-miao ^1,2,3,4 ,
CHEN Xin-de ^1,2,3,4,,

1.
Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China
2.
Key Laboratory of Renewable Energy, Chinese Academy of Sciences, Guangzhou 510640, China
3.
Guangdong Key Laboratory of New and Renewable Energy Research and Development, Guangzhou 510640, China
4.
R & D Center of Xuyi Attapulgite Applied Technology, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Xuyi 211700, China
5.
Nano Science and Technology Institute, University of Science and Technology of China, Suzhou 215123, China

Corresponding author: CHEN Xin-de, cxd_cxd@hotmail.com
Received Date: 12 August 2019
Revised Date: 28 September 2019

Fund Project: the Project of Jiangsu Province Science and Technology BE2018342the Science and Technology Program of Guangzhou 201707010240the Project of Guangdong Provincial Natural Science Foundation 2018A030313150The project was supported by the Science and Technology Program of Guangzhou (201707010240), the Project of Guangdong Provincial Natural Science Foundation (2018A030310126, 2018A030313150), the Project of Jiangsu Province Science and Technology (BE2018342) and the Project of Key Laboratory Foundation of Renewable Energy, Chinese Academy of Sciences (CAS) (Y807jc1001)the Project of Guangdong Provincial Natural Science Foundation 2018A030310126the Project of Key Laboratory Foundation of Renewable Energy, Chinese Academy of Sciences (CAS) Y807jc1001

Figures(7)

Attapulgite (ATP) and ATP mixed with SiO₂ microspheres (ATPS) supported Cu-Fe-Co modified Fischer-Tropsch (F-T) catalysts were prepared by impregnation method (IM) and impregnation-solution combustion method (IMSC). The catalysts were characterized by N₂ adsorption-desorption, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), transmission electron microscopy (TEM), hydrogen temperature-programmed reduction (H₂-TPR) and CO₂-temperature programmed desorption (CO₂-TPD). The catalysts were also applied to lower alcohols synthesis from CO hydrogenation. Results show that the IMSC method is much beneficial for the loading, dispersion and reduction of CuO on the prepared catalyst than IM method, which promots the touch of H₂ and CO with Cu active site. The optimum reaction temperature for lower alcohols synthesis is 280℃ for the catalysts prepared by both methods. Through the optimization of catalyst combination system between ATP and ATPS supported Cu-Fe-Co based catalysts (CFCK/ATP, CFCK/ATPS) and Cu/ZnO/Al₂O₃ catalyst (CZA) for methanol synthesis, the ideal catalyst combination system, CZA‖CFCK/ATPS-IMSC, is obtained for lower alcohols synthesis. For the dual-bed configuration, a lower alcohols selectivity of 39.6% with the fraction of C₂₊ alcohols of 22.7% in oxygenates is achieved at CO conversion of 46.3% via the product conversion coupling effect.
- attapulgite,
- CO hydrogenation,
- lower alcohols,
- catalyst combination system,
- product conversion coupling effect
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