Citation: Bing DENG, Ekkehard WINTERFELDT. Synthesis of Bicyclooctane Derivatives for Kinetic Resolution[J]. Chinese Chemical Letters, ;1997, 8(5): 389-392. shu

Synthesis of Bicyclooctane Derivatives for Kinetic Resolution

Bing DENG ^a ,
Ekkehard WINTERFELDT ^b

a Department of Chemisny, Shanxi University, Taiyuan 030006;
b Institute of Organic Chemistry, University Hannover, Schneiderberg IB, 30167 Hannover, Germany

Received Date: 17 December 1996

Fund Project: This work was supported by the Shanxi Provincial Foundation for Scientists Studying Abroad.

Synthesis of five 7-membered compounds containing silane,sulfur and phosphorus groups was achieved by using endo,endo-bicyclo[3.3.0]octanediol 2.These tricyclic molecules are considered as ideal substrates for kinetic resolution of the diol.A discussion of the spectral data about these compounds was given and four of them would be substrate molecules containing an sp³ hybridized prochiral center and could be used for molecules for a kinetic resolution combining configurational diastereotopos-differentiating and diastereoisomer-differentiating reactions.
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