Citation: Wang Haina, Zhang Hui, Yu Tianzhi, Zhao Yuling. Synthesis and Evaluation of Dicoumarin Acylhydrazone Derivatives as Fluorescent Probes for Cu²⁺[J]. Chemistry, ;2020, 83(3): 240-245, 252. shu

Synthesis and Evaluation of Dicoumarin Acylhydrazone Derivatives as Fluorescent Probes for Cu²⁺

1.
Key Laboratory of Opto-Electronic Technology and Intelligent Control(Ministry of Education), Lanzhou Jiaotong University, Lanzhou, 730070
2.
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou, 730070

Corresponding author: Yu Tianzhi, yutianzhi@hotmail.com
Received Date: 22 September 2019
Accepted Date: 30 November 2019

Figures(10)

Two fluorescent probes, (N¹'E, N³'E)-N¹', N³'-bis((7-N, N-diethylaminocoumarin-3-yl)methylene) malonohydrazide and (N¹'E, N⁴'E)-N¹', N⁴'-bis((7-N, N-diethylaminocoumarin-3-yl)methylene) succinohydrazide, bearing acylhydrazone group as binding site and coumarin group as the fluorescence signal group were synthesized and characterized by conventional techniques. These probes showed notable fluorescence turn-off response for Cu²⁺ over other metals ions. The probes and Cu²⁺ formed 1:2 coordination complexes according to spectroscopy data and Job's plots. Further study demonstrated that the detection limit of Cu²⁺ for the probes was as low as 10^-9 mol/L.
- Cu²⁺,
- Dicoumarin,
- Acylhydrazone,
- Fluorescent probe
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis and Evaluation of Dicoumarin Acylhydrazone Derivatives as Fluorescent Probes for Cu2+

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通讯作者: 陈斌, bchen63@163.com

Synthesis and Evaluation of Dicoumarin Acylhydrazone Derivatives as Fluorescent Probes for Cu²⁺