Citation: HAN Lei, HUANG Chuan-feng, LIU Shu-wei, CHENG Qiu-xiang, CHANG Fang-yuan. Investigation of performance of Ni/W-USY/Al₂O₃ catalyst with full mesoporous in Fischer Tropsch wax hydrocracking[J]. Journal of Fuel Chemistry and Technology, ;2019, 47(3): 329-337. shu

Investigation of performance of Ni/W-USY/Al₂O₃ catalyst with full mesoporous in Fischer Tropsch wax hydrocracking

Hydrocarbon High-efficiency Utilization Technology Research Center, Shaanxi Yanchang Petroleum(Group) Corp. Ltd., Xi'an 710075, China

Corresponding author: HUANG Chuan-feng, huangcf1130@163.com
Received Date: 29 October 2018
Revised Date: 14 January 2019

Fund Project: The project was supported by National Science and Technology Major Project 2018YFB0604600The project was supported by National Science and Technology Major Project (2018YFB0604600)

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Ni/W-USY/Al₂O₃ with full mesoporous structure was prepared and used for hydrocracking of Fischer Fropsch wax. The catalyst was evaluated for its reaction performance, product characteristics and catalyst properties change. In a 312 h experiment, the result showed that the catalyst possessed high initial activity, and maintained stable after 120 h, and did not show obvious deactivation afterward. When the heavy wax conversion reached 73.95% at the stable stage, the fuel oil selectivity reached to 98.46% and C_{3, 4} constituted the most cracked gas. Gasoline, kerosene and diesel, as the products, were transparent and composed of paraffins and iso-paraffins substituted by methyl-groups. The iso-paraffin contents in the three products were 63.98%, 52.26% and 48.90% respectively. The fresh catalyst contained two main active states of WS₂ and NiWS, had good metal dispersion and rich mesoporous structure. With transition from high activity to stable state of the catalyst property, part of W migrated and formed more Ni-S-W bonds with Ni, and some W-S bonds broke to form W-W bonds after releasing S, resulting in the increase of active states of NiWS and the decrease of WS₂, and forming more Brönsted acid sites and less Lewis acid sites.
- Fischer Tropsch wax,
- hydrocracking,
- catalyst,
- fuel oil,
- iso-paraffin
1. [1]
  GREGOR H, ERIK R, MATTHIAS J. Design and evaluation of a Fischer-Tropsch process for the production of waxes from biogas[J]. Energy, 2017,132(1):370-381.
2. [2]
  YANG Chao, JIANG Jian, LU Dan. Advances in Fischer-Tropsch wax hydrocracking process[J]. Chem Ind Eng Prog, 2013,32(12):2882-2890.
3. [3]
  DIETER L. Hydrocracking of iron-catalyzed fischer-tropsch waxes[J]. Energy Fuels, 2005,19(5):1795-1803. doi: 10.1021/ef050085v
4. [4]
  JIANG J, YANG C, LU Z J, DING J, LI T, LU Y, CAO F H. Characterization and application of a Pt/ZSM-5/SSMF catalyst for hydrocracking of paraffin wax[J]. Catal Commun, 2015,60(5):1-4.
5. [5]
  YAN P H, TAO Z C, HAO K, WANG Y D, YANG Y, LI Y W. Effect of impregnation methods on nickel-tungsten catalysts and its performance on hydrocracking Fischer-Tropsch wax[J]. J Fuel Chem Technol, 2013,41(6):691-697. doi: 10.1016/S1872-5813(13)60032-8
6. [6]
  HAAN-DE R, JOORST G, MOKOENA E, NICOLAIDES C P. Non-sulfided nickel supported on silicated alumina as catalyst for the hydrocracking of n-hexadecane and of iron-based Fischer-Tropsch wax[J]. Appl Catal A:Gen, 2007,327(2):247-254. doi: 10.1016/j.apcata.2007.05.022
7. [7]
  KAZAKOW M O, NADEINA K A, DANILOVA I G, DIK P P, KLIMOV O V, PEREYMA V Y. Hydrocracking of vacuum gas oil over NiMo/Y-Al₂O₃:Effect of mesoporosity introduced by zeolite Y recrystallization[J]. Catal Today, 2018,305(1):117-125.
8. [8]
  LI Yu-hui, FENG Li-juan, WANG Jing-gang, XU Kang-wen, LI Chun-hu. Oxidative desulfurization of diesel oil by mesoporous catalyst MoO₃/Al₂O₃[J]. Acta Pet Sin (Pet Process Sect), 2011,27(6):878-883. doi: 10.3969/j.issn.1001-8719.2011.06.007
9. [9]
  ATAUSHI I, DAISUKE K, THANITA S, HIROYUKI N, TADANON H. Preparation and characterization of zeolite-containing silica-aluminas with three layered micro-meso-meso-structure and their reactivity for catalytic cracking of soybean oil using Curie point pyrolyzer[J]. Fuel Process Technol, 2017,161(15):8-16.
10. [10]
  LI Tao, CHE Xiao-li, YUN Yi-feng, TAO Zhi-chao, ZHAO Chun-li, YANG Yong, LI Yong-wang. Study of the relationship between the acidity of amorphous silica-alumina supports and diesel selectivity in Fischer-Tropsch wax hydrocracking[J]. J Fuel Chem Technol, 2017,45(5):589-595. doi: 10.3969/j.issn.0253-2409.2017.05.010
11. [11]
  SIMONE G, LAURA A P, VINCENZO C, CHIARA G. Liquid fuels from Fischer-Tropsch wax hydrocracking:Isomer distribution[J]. Catal Today, 2010,156(1/2):58-64.
12. [12]
  VINCENZO C, CHIARA G, WALLACE O P, ROSA C, ROBERTO G, PIETRO S. Middle distillates from hydrocracking of FT waxes:Composition, characteristics and emission properties[J]. Catal Today, 2010,149(1/2):40-46.
13. [13]
  YANG Ping, XIN Jing, LI Ming-feng. Effects of Molybdenum/Tungsten Oxides Loading on Structure and Acidity of Y Zeolites[J]. Acta Pet Sin (Pet Proces Sect), 2011,25(5):668-673. doi: 10.3969/j.issn.1001-8719.2011.05.002
14. [14]
  TAN Zheng-xing, SHEN Bao-jian. Dealumination, silicon reinsertion, and secondary pore formation in steaming of zeolite Y[J]. J Chem Ind Eng, 2016,67(8):3160-3167.
15. [15]
  JOHN W. Hydrocracking processes and catalysts[J]. Fuel Process Technol, 1993,35(2):55-85.
16. [16]
  GOLUBINA E V, LOKTEVA E S, EROKHIN A V, VELIGZHANIN A A, ZUBAVICHUS Y V, LIKHOLOBOV V A, LUNIN V V. The role of metal-support interaction in catalytic activity of nanodiamond-supported nickel in selective phenylacetylene hydrogenation[J]. J Catal, 2016,344:90-99. doi: 10.1016/j.jcat.2016.08.017
17. [17]
  ZUO Dong-hua, NIE Hong, MICHEL Vrinat, SHI Ya-hua, MICHEL Lacroix, LI Da-dong. Study on the hydrodesulfurization active phase insulfided NiW/Al₂O₃catalyst I.XPS and HREM characterizations[J]. Chin J Catal, 2004,25(4):309-314. doi: 10.3321/j.issn:0253-9837.2004.04.014
18. [18]
  SANTOLALLA-VARGAS C E, SUAREZ T V A, REYES J A, CROMWELL D K, PAWELEC B, FIERRO J L G. Effects of pH and chelating agent on the NiWS phase formation in NiW/γ-Al₂O₃ HDS catalysts[J]. Mater Chem Phys, 2015,166:105-115. doi: 10.1016/j.matchemphys.2015.09.033
19. [19]
  DIAZ-DE-LEON J N, PICQUART M, MASSIN L, VRINAT M, REYES-LOS-DE J A. Hydrodesulfurization of sulfur refractory compounds:Effect of gallium as an additive in NiWS/γ-Al₂O₃catalysts[J]. J Mol Catal A:Chem, 2012,363-364:311-321. doi: 10.1016/j.molcata.2012.07.006
20. [20]
  PARTHASARATHI B, SEENIVASAN H, RAJAM K S, WILLIAM G. XRD, FESEM and XPS studies on heat treated Co-W electrodeposits[J]. Mater Lett, 2012,76:103-105. doi: 10.1016/j.matlet.2012.02.046
21. [21]
  LU S S, XIAO S, ZHANG L M, DONG B, GAO W K, DAI F N, LIU B, CHAI Y M, LIU C G. Heterostructured binary Ni-W sulfides nanosheets as pH-universal electrocatalyst for hydrogen evolution[J]. Appl Surf Sci, 2018,455:455-435. doi: 10.1016/j.apsusc.2018.05.155
22. [22]
  SZILAGYI I M, SAJIO I, KIRALY P, TARKANYI G, TOTH A L. Phase transformations of ammonium tungsten bronzes[J]. J Therm Anal Calorim, 2009,98(3):707-716. doi: 10.1007/s10973-009-0287-x
23. [23]
  ZHANG Jun. Design of zeolites and hydrocracking catalyst for maximizing middle distillates[D]. Qingdao: China University of Petroleum, 2008: 91-95.
24. [24]
  YAN Peng-hui. Fundermantal research of hydrocracking perfomance over Ni/W-HY/Al₂O₃ catalyst on fischer-tropsch wax[D]. Beijing: University of Chinese Academy of Sciences, 2013: 37-42.
25. [25]
  ZHANG Jian, LU Hai-long, SUN Jian-wei, YAO Jian-dong, LI Quan-zhi. EXSFS study of Ni/W/zeolite/Al₂O₃hydrocracking catalyst sulfurized with different modified zeolites[J]. Chem J Chin Univ, 2000,21(10):1459-1463. doi: 10.3321/j.issn:0251-0790.2000.10.003
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Investigation of performance of Ni/W-USY/Al2O3 catalyst with full mesoporous in Fischer Tropsch wax hydrocracking

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Investigation of performance of Ni/W-USY/Al₂O₃ catalyst with full mesoporous in Fischer Tropsch wax hydrocracking