Citation: LI Ying, ZHAO Lu, LIU Xiao-zhan, ZENG Chun-xin, FANG Ke-gong. Preparation of KNiMo-based catalysts by using non-thermal plasma and their catalytic performance in the synthesis of higher alcohols from syngas[J]. Journal of Fuel Chemistry and Technology, ;2019, 47(5): 513-522. shu

Preparation of KNiMo-based catalysts by using non-thermal plasma and their catalytic performance in the synthesis of higher alcohols from syngas

LI Ying ^1,2 ,
ZHAO Lu ^1,, ,
LIU Xiao-zhan ¹ ,
ZENG Chun-xin ¹ ,
FANG Ke-gong ^1,,

1.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, ChineseAcademy of Sciences, Taiyuan 030001, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: ZHAO Lu, zhaolu@sxicc.ac.cn FANG Ke-gong, kgfang@sxicc.ac.cn
Received Date: 8 January 2019
Revised Date: 20 February 2019

Fund Project: National Natural Science Foundation of China 21473230National Natural Science Foundation of China 21603255Natural Science Foundation of Shanxi 201701D221054Natural Science Foundation of Shanxi 201601D021052the National Key R&D Program of China 2018YFB0604700The project was supported by the National Key R&D Program of China (2018YFB0604700), National Natural Science Foundation of China (21603255, 21473230) and Natural Science Foundation of Shanxi (201601D021052, 201701D221054)

Figures(9)

A series of KNiMo-based catalysts were prepared by using non-thermal plasma and characterized by XRD, nitrogen sorption, TEM, H₂-TPD, CO-TPD, and in-situ CO adsorption DRIFTS; their catalytic performance in the higher alcohol synthesis (HAS) from syngas was investigated. The results indicate that in comparison with those prepared by the conventional thermal method, the KNiMo-based catalysts prepared by using non-thermal plasma display thinner and shorter MoS₂ slabs and more highly dispersed and coordinatively unsaturated sites, which endow the KNiMo-based catalysts excellent performance in HAS. In particular, for the HAS over the KNiMo-DPS catalyst under 350 ℃, 5 MPa, and a gas hourly space velocity (GHSV) of 5000 h^-1, the conversion of CO reaches 32.3%, with a selectivity of 75.1% to total alcohol and a C₂₊ alcohol selectivity of 65.2% in the total alcohols.
- higher alcohol synthesis,
- syngas conversion,
- KNiMo-based catalyst,
- non-thermal plasma
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