Citation:
Huang Kelong, Pan Chunyue, Tan Yougan, Liu Jian'an. Synthesis and Flame Retardancy for Polyvinyl Chloride of Organoantimony Compounds[J]. Chinese Journal of Applied Chemistry,
;1995, 12(5): 76-78.
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Organoantimony compounds of the formula ph3SbX2,where X=Cl,Br and pen-tachlorophenoxy,have been prepared from the reaction of triphenylantimony with CuCl2,bromine and pentachlorophenol respectively. The compounds were characterized by elemen-tal analysis,melting point determination, infrared spectra and thermal behavior. The ther-mal decomposition mechanism was studied in air by differential scanning calorimetry. The flame retardancy of the compounds in polyvinyl chloride(PVC) was determined,which indi-cated that these compounds had high flame resisting activities for PVC at low additive levels.
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