Citation: WANG Rui-yi, LIU Huan, ZHENG Zhan-feng. Low temperature light-assisted hydrogen production from aqueous reforming ethylene glycol over Pt/Al₂O₃ and Pd/Al₂O₃ catalysts[J]. Journal of Fuel Chemistry and Technology, ;2019, 47(12): 1486-1494. shu

Low temperature light-assisted hydrogen production from aqueous reforming ethylene glycol over Pt/Al₂O₃ and Pd/Al₂O₃ catalysts

1.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: ZHENG Zhan-feng, zfzheng@sxicc.ac.cn
Received Date: 16 October 2019
Revised Date: 7 November 2019

Fund Project: the the Shanxi Science and Technology Department 2015081044The project was supported by the the Shanxi Science and Technology Department (2015081044)

Figures(8)

Al₂O₃ supported Pt and Pd nanoparticle catalysts were prepared by impregnation-reduction method, and employed in the photocatalytic aqueous-phase reforming of ethylene glycol. Light illumination can decrease the reaction activation energy remarkably. Pt/Al₂O₃ exhibits much higher H₂ turnover frequency (TOF) and lower CO selectivity than Pd/Al₂O₃ catalyst. Their morphology and structure were characterized by XRD, TEM, UV-vis techniques. In situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) indicates light can promote the cleavage of O-H bonds of ethylene glycol molecule. DFT calculation suggests the lower CO selectivity over Pt/Al₂O₃ catalyst can be attributed to the low energy barriers of reaction in the step of CO+O→CO₂.
- hydrogen production,
- ethylene glycol,
- photocatalysis,
- aqueous-phase reforming,
- metal catalyst
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Low temperature light-assisted hydrogen production from aqueous reforming ethylene glycol over Pt/Al2O3 and Pd/Al2O3 catalysts

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通讯作者: 陈斌, bchen63@163.com

Low temperature light-assisted hydrogen production from aqueous reforming ethylene glycol over Pt/Al₂O₃ and Pd/Al₂O₃ catalysts