Citation: ZHOU Xu-hui, WU Shi-yong, YOU Quan, HUANG Sheng, WU You-qing, GAO Jin-sheng, ZHENG Huan-an, MIN Xiao-jian, SHANG Jian-xuan. Effects of carbonization temperature on the products from integrated mild-liquefaction and carbonization process of Hongliulin coal[J]. Journal of Fuel Chemistry and Technology, ;2017, 45(11): 1289-1295. shu

Effects of carbonization temperature on the products from integrated mild-liquefaction and carbonization process of Hongliulin coal

  • Corresponding author: WU You-qing, wyq@ecust.edu.cn
  • Received Date: 24 July 2017
    Revised Date: 25 August 2017

    Fund Project: The project was supported by the National Natural Science Foundation of China (21476079, 21476080) and the Fundamental Research Funds for the Central Universities (WB1414014)the Fundamental Research Funds for the Central Universities WB1414014the National Natural Science Foundation of China 21476080the National Natural Science Foundation of China 21476079

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  • The integrated mild-liquefaction and carbonization experiments of Hongliulin coal were conducted at 430-600 ℃, and distributions and physico-chemical properties of the obtained products were investigated. The results show that the yields of semi-cokes, organic liquid products and n-hexane soluble organic products were up to 40.64%-53.02%, 30.89%-36.98% and 29.74%-33.28%, respectively. The increasing carbonization temperature in the relatively low temperature range was favorable for the elevated yield of n-hexane soluble organic products, while at relatively high temperature presenting an opposite one. The semi-cokes obtained at 430 ℃ presented a strong caking property, while those at 550 ℃ showed no caking property, and the content of their volatile matters decreased to about 10%. It is suggested that the produced semi-coke could be directionally utilized as blending coal in coking or smokeless fuel by adjusting carbonization temperature.
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    1. [1]

      BAI Xiao-yan. Influence of pyrolysis temperature on volatile phenolic compounds in low rank coal pyrolysis water[J]. Clean Coal Technol, 2014,20(2):87-89.  

    2. [2]

      LI X, PRIYANTO D E, ASHIDA R, MIURA K. Two-stage conversion of low-rank coal or biomass into liquid fuel under mild conditions[J]. Energy Fuels, 2015,29(5):3127-3133. doi: 10.1021/ef502574b

    3. [3]

      MILAN S, DEJAN C, PREDRAG S, VUK S. An initial study on feasible treatment of Serbian lignite through utilization of low-rank coal upgrading technologies[J]. Chem Eng Res Des, 2014,11(92):2383-2395.  

    4. [4]

      KLAUS J. HUTTINGER, ALEXANDER W M. Molecular structure of a brown coal[J]. Fuel, 1987,66(8):1164-1165. doi: 10.1016/0016-2361(87)90319-X

    5. [5]

      WU You-qing, WU Shi-yong, GAO Jin-sheng, LI Liang. A mild coal liquefaction process:CN, 201310539685.2[P]. 2014-02-05.

    6. [6]

      ZHUANG De-wang, WU Shi-yong, YOU Quan, HUANG Sheng, SHANG Jian-xuan, MIN Xiao-jian, DENG Hua-an, WU You-qing. Low rank coal mild liquefaction coupled with carbonization and its products[J]. J Fuel Chem Technol, 2016,44(5):528-533.  

    7. [7]

      YOU Q, WU S, WU Y, HUANG S, GAO J, SHANG J, MIN X, ZHENG H. Product distributions and characterizations for integrated mild-liquefaction and carbonization of low rank coals[J]. Fuel Process Technol, 2017,156:54-61. doi: 10.1016/j.fuproc.2016.09.022

    8. [8]

      ZHUANG De-wang. The research of mild liquefaction coupled with carbonization process of Hongliulin coal[D]. Shanghai:East China University of Science and Technology, 2016.

    9. [9]

      LUQUE M D, PRIEGO F. Soxhlet extraction:Past and present panacea[J]. J Chromatogra A, 2010,1217(16):2383-2389. doi: 10.1016/j.chroma.2009.11.027

    10. [10]

      ZHU Xiao-su, WANG Yu, DU Shu-feng, ZHENG Jian-guo, ZHANG Fan. Research on the relayed coke of heavy coal-liquids[J]. Coal Convers, 1998,21(2):68-74.  

    11. [11]

      SONG Yong-hui, MA Qiao-na, HE Wen-jin, LAN Xin-zhe. Regularity of gaseous product release during direct coal liquefaction residue pyrolysis process[J]. Spectrosc Spect Anal, 2016,36(7):2017-2021.  

    12. [12]

      FAN Yun-zhu. Exploratory study on properties and application of coal direct liquefaction residue[D]. Shanghai:East China University of Science and Technology, 2011.

    13. [13]

      CALKINS W H, TYLER R J. Coal flash pyrolysis:2. Polymethylene compounds in low temperature flash pyrolysis tars[J]. Fuel, 1984,63(8):1119-1124. doi: 10.1016/0016-2361(84)90198-4

    14. [14]

      SIMELL P A, LEPPALAHTI J K, BREDENBERG J B. Catalytic purification of tarry fuel gas withcarbonate rocks and ferrous materials[J]. Fuel, 1992,71(2):211-218. doi: 10.1016/0016-2361(92)90011-C

    15. [15]

      SOLOMON P R, HAMBLEN D G, CARANGELO R M, SERIO M A, DESHPANDE G V. Models of tar formation during coal devolatilization[J]. Combust Flame, 1988,71(2):137-146. doi: 10.1016/0010-2180(88)90003-X

    16. [16]

      CHANG Song, CHU Mo, CAO Wen-han, WANG Bo. Precipitated rule of gas from direct liquefaction residue pyrolysis[J]. Clean Coal Technol, 2014,20(2):84-86.  

    17. [17]

      WANG Peng, BU Xue-peng, XIN Shi-he, DENG Yi-ying. Study on the pyrolysis characteristics of coal liquefaction residues[J]. Coal Chem Ind, 2005,33(2):20-23.  

    18. [18]

      LI Jian-guang, FANG Yi-tian, ZHANG Yong-qi, LI Chun-yu, WANG Yang. Property of char from fast pyrolysis of direct coal liquefaction residue[J]. J Fuel Chem Technol, 2008,36(3):273-278.  

    19. [19]

      XU L, TANG M, DUAN E, LIU B, MA X, ZHANG Y, ARGYLE M D, FAN M. Pyrolysicharacteristics and kinetics of residue from China Shenhua industrial direct coal liquefaction plant[J]. Thermochim Acta, 2014,589:1-10. doi: 10.1016/j.tca.2014.05.005

    20. [20]

      CHEN Ming-bo, WANG Bin, ZHAO Qi, QU Si-jian. Study on the coking character of coalliquefaction residue[J]. Clean Coal Technol, 2005,11(1):29-33.  

    21. [21]

      LI Xiao-hong, MA Jiang-shan, XUE Yan-li, LI Wen-ying. Properties of semi-coke from co-pyrolysis of lignite and direct liquefaction residue of Shendong coal[J]. J Fuel Chem Technol, 2015,43(11):1281-1286. doi: 10.3969/j.issn.0253-2409.2015.11.001 

    22. [22]

      QIAN W, XIE Q, HUANG Y, DANG J, SUN K, YANG Q, WANG J. Combustion characteristics of semicokes derived from pyrolysis of low rank bituminous coal[J]. Int J Min Sci Technol, 2012,22(5):645-650. doi: 10.1016/j.ijmst.2012.08.009

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