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Citation: Yan Cuiwei, Li Yantuan, Liao Daizheng, Jiang Zonghui, Wang Genglin. Synthesis,Magnetism and Antibacterial Activity of Cu(Ⅱ)-Ln(Ⅲ) Binuclear Complexes[J]. Chinese Journal of Applied Chemistry, ;1995, 12(5): 37-41. shu

Synthesis,Magnetism and Antibacterial Activity of Cu(Ⅱ)-Ln(Ⅲ) Binuclear Complexes

1.
Department of Chemistry, Qufu Normal University, Qufu 273165;
2.
Department of Chemistry, Nankai University, Tianjin

Received Date: 12 December 1994
Revised Date: 13 April 1995

Six μ-oxamido heterobinuclear complexes,namely Cu(oxen)Ln(phen)₂(ClO₄)₃, (oxen:N,N'-bis(2-aminoethyl) oxamido dianion;phen:1,10-phenanthroline and Ln:Y,La,Ce,Nd,Gd,Yb) have been synthesized and characterized. The variable-temperature mag-netic susceptibility of Cu(oxen)Gd(phen)₂(ClO₄)₃·H₂O was measured over 4~300K and the susceptibility data were least-squares fit to the susceptibility equation derived from the spin Hamiltonian operator Ĥ=-2JŜ₁·Ŝ₂. The exchange integral J was found to be 2.3cm^-1,indicating that a very weak ferromagnetic spin-exchange interaction operates be-tween Cu(Ⅱ) and Gd(Ⅲ) ions. The antibacterial activity of the complexes were also exam-ined.
- copper-rare earth binuclear complex,
- synthesis,
- magnetism,
- antibacterial activity
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