Citation: Xue Yuan HUANG, Rui Xiang LI, Hua CHEN, Xian Jun LI. The Performance of Rhodium Complex-diphosphine Systems in the Hydroformylation of 1-Dodecene[J]. Chinese Chemical Letters, ;2003, 14(6): 623-626. shu

The Performance of Rhodium Complex-diphosphine Systems in the Hydroformylation of 1-Dodecene

Department of Chemistry, Sichuan University, Chengdu 610064

Received Date: 4 November 2002

The catalytic performances of four HRh(CO)(PPh₃)₃-diphosphine (BISBI, BDPX,BDNA and BINAP) systems in 1-dodecene hydroformylation were investigated and comparedwith HRh(CO)(PPh₃)₃-PPh₃system. The catalyst system HRh(CO)(PPh₃)₃- BISBI exhibited veryhigh regioselectivity for the formation of linear aldehyde.
- Hydroformylation,
- 1-dodecene,
- diphosphine,
- rhodium complex
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