Citation: XIAO Zhu-qian, ZHANG Qiang, WANG Xiao-lei, GE Qing, GAI Xi-kun, MAO Jian-wei, JI Jian-bing. Organic nitrogen promotes stability of metallic catalysts in conversion of bamboo pulp to low carbon polyols[J]. Journal of Fuel Chemistry and Technology, ;2019, 47(6): 675-687. shu

Organic nitrogen promotes stability of metallic catalysts in conversion of bamboo pulp to low carbon polyols

XIAO Zhu-qian ^1,2,3 ,
ZHANG Qiang ^1,2 ,
WANG Xiao-lei ^1,2 ,
GE Qing ^1,2 ,
GAI Xi-kun ^1,2 ,
MAO Jian-wei ^1,2,, ,
JI Jian-bing ³

1.
Zhejiang Provincial Collaborative Innovation Center of Agricultural Biological Resources Biochemical Manufacturing, Zhejiang University of Science and Technology, Hangzhou 310023, China
2.
Zhejiang Provincial Key Laboratory of Chemical and Biological Processing Technology of Farm Products, Zhejiang University of Science and Technology, Hangzhou 310023, China
3.
College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China

Corresponding author: MAO Jian-wei, shaw1314@126.com; zjhzmjw@163.com
Received Date: 19 February 2019
Revised Date: 3 April 2019

Fund Project: and Technology Project of Zhejiang Province 2017C37049The project was supported by Science and Technology Project of Zhejiang Province (2017C37049)

Figures(12)

Herein, the synthesis and performance of a novel and stable catalyst capable of facile hydrolysis of bamboo pulp were reported. Based on adopting complex agent to have a complex reaction with Ni²⁺ cations, the graphitic g-C₃N₄ phase and nitride phases were formed eventually. The interaction among metals and C, N atoms was analyzed by XRD and XPS. Some Ni-W alloys (mainly NiWO₄ was included) were formed besides metallic Ni⁰ and tungsten species characterized. Particles on the surface of 15%Ni-20%W/MBC@M-0.25 catalyst exhibited homogeneous distribution and surrounded by disordered C₃N₄ layer characterized by TEM. Besides, the organic N sources were decomposed and the C₃N₄ phase with high hydrothermal property was formed simultaneously. For catalytic efficiency, 15%Ni-20%W/MBC@M-0.25 catalyst acquired the highest EG yield of 55.8% compared to 36.9% via 15%Ni-20%W/MBC catalysts. The carbon supports and organic nitrogen sources demonstrated great influence on catalytic efficiency. Catalyst recycle experiments implied that Ni-W/MBC@M-0.25 could remain relative stable under this catalytic reaction condition. The Ni-W alloys and the C₃N₄ phase were deduced as the main contributors to maintain the catalyst stability.
- bamboo pulp,
- organic nitrogen,
- metallic catalysts,
- hydrogenolysis,
- polyols
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