Citation: Wang Hongmei, Bai Jin, Yang Lina, Li Jian. Research Progress in Catalytic Hydrodesulfurization Mechanism of Transition Metal Phosphides[J]. Chemistry, ;2017, 80(4): 349-355. shu

Research Progress in Catalytic Hydrodesulfurization Mechanism of Transition Metal Phosphides

College of Chemistry, Chemical Engineering, and Environmental Engineering, Liaoning Shihua University, Fushun 113001

Corresponding author: Bai Jin, baijin_fy@163.com
Received Date: 8 August 2016
Accepted Date: 15 November 2016

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In this paper the mechanism of the hydrodesulfurization (HDS) reaction of sulfur-containing compounds over bulk transition metal phosphide catalysts, supported transition metal phosphide catalysts, and modified transition metal phosphide catalysts were reviewed. The structure-activity relationships of catalysts, the influence of different types of catalysts on the reaction paths of sulfur-containing compounds over catalysts were also discussed in detail. The calculation of rate constant of different HDS steps over phosphide catalyst led to a better understanding of HDS reaction steps. These results can also help us to understand the reaction kinetics and reaction network of sulfur-containing compounds over phosphide catalysts, which offers an important academic value and general guiding significance for the development and application of new-style deep HDS catalyst.
- Hydrodesulfurization,
- Transition metal phosphides,
- Reaction network,
- Dibenzothiophene,
- Mechanism
1. [1]
  E Muthuswamy, G H L Savithra, S L Brock. Acs. Nano, 2011, 5(3): 2402~2411.
2. [2]
  R Prins, M E Bussell. Catal. Lett., 2012, 142(12): 1413~1436.
3. [3]
  F Bataille, J L Lemberton, P Michaud et al. J. Catal., 2000, 191: 409~422.
4. [4]
  T Weber, J A R van Veen. Catal. Today, 2008, 130: 170~177.
5. [5]
  G H Singhal, R L Espino, J E Sobel. J. Catal., 1981, 67: 446~456.
6. [6]
  T Todorova, R Prins, T Weber. J. Catal., 2007, 246: 109~117.
7. [7]
  R R Chianelli. Catal. Rev. Sci. Eng., 1984, 26: 361~393.
8. [8]
  T Kawai, K K Bando, Y K Lee et al. J. Catal., 2006, 241(1): 20~24.
9. [9]
  T Wada, K K Bando, S T Oyama et al. Chem. Lett., 2012, 41: 1238~1240.
10. [10]
  W R A M Robinson, J N M van Gestel, T I Korányi et al. J. Catal., 1996, 161: 539~550.
11. [11]
  W Li, B Dhandapani, S T Oyama. Chem. Lett., 1998, 1998(3):207~208.
12. [12]
  Y K Lee, S T Oyama. J. Catal., 2006, 239(2): 376~389.
13. [13]
  S T Oyama, Y K Lee. J. Catal., 2008, 258(2): 393~400.
14. [14]
  S T Oyama, H Y Zhao, H J Freund et al. J. Catal., 2012, 285: 1~5.
15. [15]
  H Y Zhao, S T Oyama, H-J Freund et al. Appl. Catal. B, 2015, 164: 204~216.
16. [16]
  A E Nelson, M Sun, A S M Junaid. J. Catal., 2006, 241(1): 180~188.
17. [17]
  T Kabe, W Qian, A Ishihara. J. Phys. Chem., 1994, 98: 912~916.
18. [18]
  M Jian, R Prins. Catal. Lett., 1998, 50: 9~13.
19. [19]
  J Bai, X Li, A J Wang et al. J. Catal., 2012, 287:161~169.
20. [20]
  J Bai, X Li, A J Wang et al. J.Catal., 2013, 300: 197~200.
21. [21]
22. [22]
  L Yang, X Li, A J Wang et al. J. Catal., 2014, 317: 144~152.
23. [23]
24. [24]
  M Hussain, S K Song, S K Ihm. Fuel, 2013, 106: 787~792.
25. [25]
26. [26]
27. [27]
28. [28]
  Q Wei, Y Li, T Zhang et al. Energy Fuels, 2014, 28(12): 7343~7351.
29. [29]
  H L Yin, X L Liu, Y Y Yao et al. J. Porous. Mater., 2015, 22: 29~36.
30. [30]
  C O Castillo-Araiza, G Chávez, A Dutta et al. Fuel Proc. Technol., 2015, 132: 164~172.
31. [31]
  S Zhang, L Song, X Wu et al. Vacuum, 2014, 108(10): 45~48.
32. [32]
  J N Wang, Y C Fu, H Chen et al. Chem. Eng. J., 2015, 275: 89~101.
33. [33]
  H Song, M Dai, Y T Guo et al. Fuel. Proc. Technol., 2012, 96: 228~236.
34. [34]
35. [35]
36. [36]
37. [37]
  F Richard, T Boita, G Pérot. Appl. Catal. A, 2007, 320: 69~79.
38. [38]
39. [39]
  F X Sun, W C Wu, Z L Wu et al. J. Catal., 2004, 228(2): 298~310.
40. [40]
  J A Rodriguez, J Y Kim, J C Hanson et al. J. Phys. Chem. B, 2003, 107(26): 6276~6285.
41. [41]
  C Stinner, R Prins, T Weber. Appl. Catal. A, 2007, 328(1): 58~67.
42. [42]
  I I Abu, K J Smith. Appl. Catal. A, 2007, 328(1): 58~67.
43. [43]
  I I Abu, K J Smith. J. Catal., 2006, 241(2): 356~366.
44. [44]
  I I Abu, K J Smith. Catal. Today, 2007, 125(3~4): 248~255.
45. [45]
  J Ramirez, G Macias, L Cedeno et al. Catal. Today, 2004, 98(1~2): 19~30.
46. [46]
  P F Zhao, S F Ji, N Wei et al. Chin. J. Inorg. Chem., 2010, 26(12):2273~2279.
47. [47]
  C Q Li, M L Deng, H Wang et al. J. Fuel. Chem. Technol., 2012, 40(4): 501~506.
48. [48]
  P F Zhao, S F Ji, N Wei et al. Acta Phys-Chim. Sin., 2011, 27(7): 1737~1742.
49. [49]
  P Y Wu, Q Y Li, L Lan et al. Chin. J. Chem. Eng., 2014, 22: 903~908.
50. [50]
  Q Y Li, P Y Wu, L Lan et al. Catal. Today, 2013, 216:38~43.
51. [51]
  X Li, Z C Sun, A J Wang et al. Appl. Catal. A, 2012, 417~418: 19~25.
52. [52]
53. [53]
  Z Sun, X Li, A Wang et al. Top. Catal., 2012, 55(14~15):1010~1021.
54. [54]
  H Song, J Wang, Z D Wang et al. J. Catal., 2014, 311:257~265.
55. [55]
56. [56]
57. [57]
  Q Y Li, P Y Wu, L Lan et al. Appl. Petrochem. Res., 2013, 4(2): 209~216.
58. [58]
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