Citation: WANG Hong-hao, LIU Su-yao, ZHANG Huai-ke, GUO Da-guang, MA Jun, REN Jie, WANG Hai-yan. Synthesis and characterization of ZSM-22 zeolites and their catalytic performance in alkylation reaction[J]. Journal of Fuel Chemistry and Technology, ;2016, 44(8): 1010-1016. shu

Synthesis and characterization of ZSM-22 zeolites and their catalytic performance in alkylation reaction

WANG Hong-hao ¹ ,
LIU Su-yao ^2,3 ,
ZHANG Huai-ke ^2,4 ,
GUO Da-guang ¹ ,
MA Jun ¹ ,
REN Jie ^2,4,*,, ,
WANG Hai-yan ^1,*,,

1.
Chemical Engineering and Environmental Science, Liaoning Shihua University, Fushun 113001, China
2.
State Engineering Laboratory for Indirect Coal Liquefaction, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
3.
University of Chinese Academy of Sciences, Beijing 100049, China
4.
Synfuels China Co. Ltd, Beijing 101407, China

Corresponding author: REN Jie, renjie@sxicc.ac.cn WANG Hai-yan, fswhy@126.com
Received Date: 30 March 2016
Revised Date: 6 May 2016

Figures(8)

The ZSM-22 molecular sieves with various morphologies were synthesized by different methods. XRD, SEM, BET, MAS NMR, NH₃-TPD and Py-FTIR were used to study the structure, morphology, surface area, Si-Al coordination and acidity of the samples. Furthermore, the toluene-methanol alkylation as probe reaction was used to investigate the effect of ZSM-22 zeolites morphology on catalytic performance. The lattice parameters, surface areas, Si-Al coordination and acidity of all samples are obviously different. As a result, the interaction of each bundle of the bundle-like ZSM-22 zeolites leads to the structure change of Si (4Si) coordination, the increase of T3 and T4 with decrease of T2 location, and thus displays more L acid sites. At 380℃ reaction temperature, the bundle-like ZSM-22 zeolite catalyst shows high selectivity to p-xylene (76.1%) at about 16.7% conversion in the toluene-methanol alkylation.
- ZSM-22 molecular sieve,
- morphology,
- toluene-methanol alkylation
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