Citation: Xue Ran LU, Xing Hua TANG, Shu Ling GONG, Yuan Yin CHEN. A Novel Calix [4] arene Having Long-Chain Monoalkenyl at The Upper Rim[J]. Chinese Chemical Letters, ;1997, 8(7): 579-582. shu

A Novel Calix [4] arene Having Long-Chain Monoalkenyl at The Upper Rim

Department of Chemistry, Wuhan University, Wuhan, 430072

Received Date: 29 January 1997

Fund Project: This work was supported by The National Natural Science Foundation of China.

5-1',1'-dimethylundecenyloxyphenylmethyl-11,17,23-tris-1",1"-dimethylethyl-25,26,27,28-tetrahydroxycalix [4] arene was synthesized from 1,1-dimethylundecenyoxylphenyl-methylphenol (3) and bishydroxymethylated p-tert-butylphenol-formaldehyde trimer (7) (3-[3-[3-(Hydroxymethyl)-5-tert-butylsalicyl-5]-tert-butylsalicy]-5-tert-butyl-2-hydroxybenzyl Alcohol) by ‘1+3’ fragment condensation in dioxane with TiCl₄ as condensation agent in 28% yield.It is the first long-chain monoalkenyl substituted calix [4] arene in which the alkenyl was attached to the upper rim of calix [4] arene.
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