Citation: Tian Bac HUANG, Ling Fei LIU, Xuang Long XU, Wen Fang HUANG, Ke WANG. Aliphatic Phosphenium Canon Featuring A P-S Bond[J]. Chinese Chemical Letters, ;1999, 10(3): 205-206. shu

Aliphatic Phosphenium Canon Featuring A P-S Bond

Institute of Pesticides and Pharmaceuticals, East China University of Science and Technology, shanghai 200237, Institute of Organic Synthesis, Central China Normal University, Wuhan 430079

Received Date: 24 August 1998

Fund Project: Supported by the National Natural Science Foundation of China (29602001).

The first aliphatic phosphenium cation featuring a P-S bond (dimethylamino) (methylthio) phosphenium cation 1.has been prepared by treatument of the (dimethylamino) (methylthio) chlorophosphines 2 wih the stoichiometri quantity of AlCl₃ in CH₂Cl₂ solution, and characterized by ¹H ¹³C ²⁷Al and ³¹P NMR spectroscopy.
- Phosphenium cation,
- chlorophosphine,
- ³¹p nmr spectroseopy
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