Citation: QIE Zhi-qiang, ZHANG Zi-yi, JING Jie-ying, YANG Zhi-fen, FENG Jie, LI Wen-ying. Effect of Ni₂P loading on the structure and naphthalene hydrogenation performance of Ni₂P/Ce-Al₂O₃ catalyst[J]. Journal of Fuel Chemistry and Technology, ;2019, 47(6): 718-724. shu

Effect of Ni₂P loading on the structure and naphthalene hydrogenation performance of Ni₂P/Ce-Al₂O₃ catalyst

Training Base of State Key Laboratory of Coal Science and Technology, Taiyuan University of Technology, Taiyuan 030024, China

Corresponding author: JING Jie-ying, LI Wen-ying,
Received Date: 30 January 2019
Revised Date: 16 April 2019

Fund Project: the National Natural Science Foundation of China U1610221Program for the Top Young Academic Leaders of Higher Learning Institutions of Shanxi 164010121-SThe project was supported by the National Natural Science Foundation of China (U1610221), Natural Science Foundation of Shanxi Province (201701D221237) and Program for the Top Young Academic Leaders of Higher Learning Institutions of Shanxi (164010121-S)Natural Science Foundation of Shanxi Province 201701D221237

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A series of Ni₂P/Ce-Al₂O₃ catalysts were prepared by temperature-programmed reduction method, and the influence of Ni₂P loading on the catalyst structure and naphthalene hydrogenation saturation performance was investigated. The results show that the specific surface area, the Ni₂P particle size and the active site number of the as-synthesized catalysts are greatly affected by Ni₂P loading, which is derived from the variable interaction between active component Ni₂P and the support Ce-Al₂O₃. When the Ni₂P loading is 17% (mass ratio), the catalyst possesses a large specific surface area (40 m²/g), a small Ni₂P particle size (26.3 nm), and the maximum number of active sites (26.7 μmol/g). Meanwhile, the conversion rate of naphthalene and the selectivity of decalin reach to 95% and 76%, respectively, and the activity stability of the catalyst is good, which is mainly attributed to the large specific surface area and high number of active sites of the catalyst providing more sites for the reaction.
- naphthalene hydrogenation,
- Ni₂P/Ce-Al₂O₃,
- Ni₂P loading,
- temperature-programmed reduction method
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Effect of Ni2P loading on the structure and naphthalene hydrogenation performance of Ni2P/Ce-Al2O3 catalyst

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Effect of Ni₂P loading on the structure and naphthalene hydrogenation performance of Ni₂P/Ce-Al₂O₃ catalyst