Citation: YANG Gai-xiu, WANG Ke-xin, ZHANG Ze-zhen, ZHEN Feng, SUN Yong-ming. Preparation of MnO₂ catalyst by electrochemical deposition and its application in the microbial fuel cells[J]. Journal of Fuel Chemistry and Technology, ;2020, 48(7): 889-896. shu

Preparation of MnO₂ catalyst by electrochemical deposition and its application in the microbial fuel cells

Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, CAS Key Laboratory of Renewable Energy, Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development, Guangzhou 510640, China

Corresponding author: SUN Yong-ming, sunym@ms.giec.ac.cn
Received Date: 31 March 2020
Revised Date: 3 June 2020

Fund Project: the Natural Science Foundation of Guangdong Province 2017A030310280the Strategic Priority Research Program of Chinese Academy of Sciences XDA 21050400National Natural Science Foundation of China 51806224the Natural Science Foundation of Guangdong Province 2019A1515011971The project was supported by the Natural Science Foundation of Guangdong Province (2017A030310280, 2019A1515011971), National Natural Science Foundation of China (51806224) and the Strategic Priority Research Program of Chinese Academy of Sciences (XDA 21050400)

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As a green and clean renewable energy technology, microbial fuel cells (MFCs) have attracted extensive attention. The electrocatalysts with high activity and low-cost towards oxygen reduction reaction (ORR) are of great importance for the large-scale commercial applications of MFCs. Among multifarious cathode catalysts, manganese-based oxides showed high catalytic activity close to that of the precious metals. In this work, a sponge-like manganese dioxide (MnO₂) electro-catalyst was successfully prepared by the electrodeposition method. The surface morphology and composition of as-prepared MnO₂ catalyst were characterized by means of scanning electron microscopy (SEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and so on; the electrocatalytic activity of the obtained MnO₂ material towards ORR were evaluated by the linear sweep voltammetry (LSV) in a neutral phosphate buffer solution. The results demonstrate that the as-prepared MnO₂ catalyst appears as crystalline γ-MnO₂ and has a high Mn³⁺/Mn⁴⁺ ratio, which is beneficial to improving the catalytic activity in ORR. The as prepared γ-MnO₂ catalyst exhibits superior activity for the ORR under neutral conditions to the commercial MnO₂ catalyst. An MFC coupled with as-prepared catalyst generates an open circuit voltage of 0.52 V, with a maximum power density of 975.6 mW/m², about 1.7 times of that achieved with the MFC using commercial MnO₂ as cathode catalyst, which suggests that the MnO₂ catalyst prepared by the electrodeposition could be an economical alternative for Pt free catalysts in practical application of MFC.
- electrodeposition,
- MnO₂,
- cathode catalyst,
- oxygen reduction reaction,
- microbial fuel cell
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Preparation of MnO2 catalyst by electrochemical deposition and its application in the microbial fuel cells

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Preparation of MnO₂ catalyst by electrochemical deposition and its application in the microbial fuel cells