Citation: LI Ming-jie, GAO Xiu-juan, YANG Qi, FENG Ru, ZHANG Jun-feng, SONG Fa-en, ZHANG Qing-de, HAN Yi-zhuo, TAN Yi-sheng. Effect of Ce doping on the performance of MoSn catalyst in the selective oxidation of dimethyl ether to methyl formate[J]. Journal of Fuel Chemistry and Technology, ;2020, 48(10): 1248-1255. shu

Effect of Ce doping on the performance of MoSn catalyst in the selective oxidation of dimethyl ether to methyl formate

LI Ming-jie ^1,2 ,
GAO Xiu-juan ^1,2 ,
YANG Qi ^1,2 ,
FENG Ru ^1,2 ,
ZHANG Jun-feng ¹ ,
SONG Fa-en ¹ ,
ZHANG Qing-de ^1,3,, ,
HAN Yi-zhuo ¹ ,
TAN Yi-sheng ¹

1.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China
3.
Dalian National Laboratory for Clean Energy, Dalian 116023, China

Corresponding author: ZHANG Qing-de, qdzhang@sxicc.ac.cn
Received Date: 30 July 2020
Revised Date: 8 September 2020

Fund Project: The project was supported by the National Natural Science Foundation of China (21773283, 21373253), CAS Interdisciplinary Innovation Team (BK2018001), the Dalian National Laboratory For Clean Energy (DNL) Cooperation Fund, CAS (DNL 201903), the Youth Innovation Promotion Association CAS (2014155) and the Open Project Program of State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University (201624)The Dalian National Laboratory For Clean Energy (DNL) Cooperation Fund, CAS DNL 201903The National Natural Science Foundation of China 21373253The National Natural Science Foundation of China 21773283The Open Project Program of State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University 201624The Youth Innovation Promotion Association CAS 2014155CAS Interdisciplinary Innovation Team BK2018001

Figures(6)

A series of MoSn catalysts doped with different Ce loadings were prepared by hydrothermal method and their catalytic performance in the selective oxidation of dimethyl ether (DME) to methyl formate (MF) was investigated. The results indicate that the introduction of 0.5% Ce can significantly improve the activity of the MoSn catalyst over the 0.5%Ce-MoSn catalyst, the conversion of DME reaches 11.8% at 130 ℃, with a selectivity of 92.2% for MF. The MoSn catalysts were characterized by nitrogen sorption, XRD, NH₃-TPD, CO₂-TPD, H₂-TPR, XPS and in situ-IR; the results illustrate that a small amount of Ce in the MoSn catalyst can obviously increase the quantity of Mo⁵⁺, though it has little effect on the structure of the MoSn catalyst.
- MoSn catalyst,
- dimethyl ether,
- selective oxidation,
- methyl formate,
- hydrothermal method
1. [1]
  WANG D S, HAN Y Z, TAN Y S, TSUBAKI N. Effect of H₂O on Cu-based catalyst in one-step slurry phase dimethyl ether synthesis[J]. Fuel Process Technol, 2009,90(3):446-451. doi: 10.1016/j.fuproc.2008.11.007
2. [2]
  SUN Ming, YU Lin, SUN Chang-yong, SONG Yi-bing, SUN Jian. Application of dimethyl ether and development of its downstream products[J]. Fine Chem, 2003,20(11):695-699.
3. [3]
  HUANG Xiu-min, XU yi-de, SHEN Wen-jie. Selective oxidation of dimethyl ether to formaldehyde over supported MoOx and VOx catalysts[J]. Chin J Catal, 2004,25(4):267-271.
4. [4]
  HUANG X M, LIU J L, CHEN J L, XU Y D, SHEN W J. Mechanistic study of selective oxidation of dimethyl ether to formaldehyde over Alumina-supported molybdenum oxide catalyst[J]. Catal Lett, 2006,108(1/2):79-86.
5. [5]
  LIU H C, CHEUNG P, IGLESIA E. Structure and support effects on the selective oxidation of dimethyl ether to formaldehyde catalyzed by MoO_x domains[J]. J Catal, 2003,217(1):222-232.
6. [6]
  LIU H C, IGLESIA E. Selective oxidation of dimethyl ether to formaldehyde on small molybdenum oxide domains[J]. J Catal, 2002,208(1):1-5.
7. [7]
  WANG Duo-ren. Production development and application prospects of methyl formate[J]. Chem Eng Oil Gas, 1998,27(3):149-151.
8. [8]
  ZHOU Shou-zu. Production technology and application foreground of methyl formate[J]. Chem Technol Market, 2003,26(2):13-18.
9. [9]
  LI Zhen-xiang. Brief discussion on methanol carbonylation to synthesize methyl formate[J]. Small Nitrogen Fert Des Technol, 2003,24(1):60-62.
10. [10]
  WANG Qing-song, LI Guo-ru, LI Gong. Catalytic activity of methanol dehydrogenation to MF over Cu/SBA-15 and Cu-ZnO/SBA-15 prepared by grinding and impregnation[J]. J Changzhou Univ, 2014,26(1):23-26.
11. [11]
  TONNER S P, TRIMM D L, WAINWEIGHT M S, CANT N W. Dehydrogenation of methanol to methyl formate over copper-catalysts[J]. Ind Eng Chem Prod Res Dev, 1984,23(3):384-388. doi: 10.1021/i300015a012
12. [12]
  AI M. The production of methyl formate by the vapor-phase oxidation of methanol[J]. Chem Technol Market, 2003,26(2):13-18.
13. [13]
  AI M. The reaction of formaldehyde on various metal-oxide catalysts[J]. J Catal, 1982,77(1):279-288.
14. [14]
  LIU Guang-bo, ZHANG Qing-de, HAN Yi-zhuo, TSUBAKI Noritatsu, TAN Yi-sheng. Low-temperature oxidation of dimethyl ether to methyl formate with high selectivity over MoSn catalysts[J]. J Fuel Chem Technol, 2013,41(2):223-227.
15. [15]
  LIU G B, ZHANG Q D, HAN Y Z, TSUBAKI N, TAN Y S. Selective oxidation of dimethyl ether to methyl formate over trifunctional MoSn catalyst under mild conditions[J]. Green Chem, 2013,15(6):1501-1504. doi: 10.1039/c3gc40279g
16. [16]
  LIU G B, ZHANG Q D, HAN Y Z, TSUBAKI N, TAN Y S. Effects of the MoO₃ structure of Mo-Sn catalysts on dimethyl ether oxidation to methyl formate under mild conditions[J]. Green Chem, 2015,17(2):1057-1064. doi: 10.1039/C4GC01591F
17. [17]
  ZHANG Z Z, ZHANG Q D, HAN Y Z, TSUBAKI N, TAN Y S. The effects of the Mo-Sn contact interface on the oxidation reaction of dimethyl ether to methyl formate at a low reaction temperature[J]. Catal Sci Technol, 2016,6(15):6109-6117. doi: 10.1039/C6CY00460A
18. [18]
  ZHANG Z Z, ZHANG Q D, HAN Y Z, TSUBAKI N, TAN Y S. Effect of MoO₃ crystalline structure of MoSn catalysts on selective oxidation of glycol dimethyl ether to 1, 2-propandiol[J]. , 2016,6(6):1842-1849.
19. [19]
  ZHANG Z Z, ZHANG Q D, HAN Y Z, TSUBAKI N, TAN Y S. Effect of tetrahedral molybdenum oxide species and MoOx domains on the selective oxidation of dimethyl ether under mild condition[J]. Catal Sci Technol, 2016,6(9):2975-2983. doi: 10.1039/C5CY01569C
20. [20]
  YANG Qi, GAO Xiu-juan, FENG Ru, LI Ming-jie, ZHANG Jun-feng, ZHANG Qing-de, HAN Yi-zhuo, TAN Yi-sheng. MoSn catalyst prepared by hydrothermal synthesis method for dimethyl ether catalytic oxidation[J]. J Fuel Chem Technol, 2019,47(8):934-941.
21. [21]
  STAMPF S, CHEN Y, DUMESIC J A, HILL C G. Interactions of molybdenum oxide with various oxide supports:Calcination of mechanical mixtures[J]. J Catal, 1987,105(2):445-454.
22. [22]
  MENG Y L, WANG T, CHEN S, GONE J L. Selective oxidation of methanol to dimethoxymethane on V₂O₅-MoO₃/γ-Al₂O₃ catalysts[J]. Appl Catal B:Environ, 2014,160-161(1):161-172.
23. [23]
  WHITING G T, KONDRAT S A, HAMMOND C, DIMITRATOS N, HUTCHINGS G J. Methyl formate formation from methanol oxidation using supported Gold-Palladium nanoparticles[J]. ACS Catal, 2015,5(2):637-644.
24. [24]
  GONCALVES F, MEDEIROS P R S, EON J G, APPEL L G. Active sites for ethanol oxidation over SnO₂-supported molybdenum oxides[J]. Appl Catal A:Gen, 2000,193(1/2):195-202.
25. [25]
  HABER J, LALIK E. Catalytic properties of MoO₃ revisited[J]. Catal Today, 1997,33(1/3):119-137.
1. [1]
  Liuyun Chen , Wenju Wang , Tairong Lu , Xuan Luo , Xinling Xie , Kelin Huang , Shanli Qin , Tongming Su , Zuzeng Qin , Hongbing Ji . Soft template-induced deep pore structure of Cu/Al₂O₃ for promoting plasma-catalyzed CO₂ hydrogenation to DME. Acta Physico-Chimica Sinica, 2025, 41(6): 100054-. doi: 10.1016/j.actphy.2025.100054
2. [2]
  Zhuoyan Lv , Yangming Ding , Leilei Kang , Lin Li , Xiao Yan Liu , Aiqin Wang , Tao Zhang . Light-Enhanced Direct Epoxidation of Propylene by Molecular Oxygen over CuO_x/TiO₂ Catalyst. Acta Physico-Chimica Sinica, 2025, 41(4): 100038-. doi: 10.3866/PKU.WHXB202408015
3. [3]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
4. [4]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
5. [5]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
6. [6]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
7. [7]
  Haoying ZHAI , Lanzong WEN , Wenjie LIAO , Qin LI , Wenjun ZHOU , Kun CAO . Metal-organic framework-derived sulfur-doped iron-cobalt tannate nanorods for efficient oxygen evolution reaction performance. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 1037-1048. doi: 10.11862/CJIC.20240320
8. [8]
  Juntao Yan , Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-. doi: 10.3866/PKU.WHXB202312024
9. [9]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
10. [10]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
11. [11]
  Jianding LI , Junyang FENG , Huimin REN , Gang LI . Proton conductive properties of a Hf(Ⅳ)-based metal-organic framework built by 2,5-dibromophenyl-4,6-dicarboxylic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1094-1100. doi: 10.11862/CJIC.20240464
12. [12]
  Xi YANG , Chunxiang CHANG , Yingpeng XIE , Yang LI , Yuhui CHEN , Borao WANG , Ludong YI , Zhonghao HAN . Co-catalyst Ni₃N supported Al-doped SrTiO₃: Synthesis and application to hydrogen evolution from photocatalytic water splitting. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 440-452. doi: 10.11862/CJIC.20240371
13. [13]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
14. [14]
  Jingzhao Cheng , Shiyu Gao , Bei Cheng , Kai Yang , Wang Wang , Shaowen Cao . 4-氨基-1H-咪唑-5-甲腈修饰供体-受体型氮化碳光催化剂的构建及其高效光催化产氢研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406026-. doi: 10.3866/PKU.WHXB202406026
15. [15]
  Lewang Yuan , Yaoyao Peng , Zong-Jie Guan , Yu Fang . 二维共价有机框架作为光催化剂在有机合成中的研究进展. Acta Physico-Chimica Sinica, 2025, 41(8): 100086-. doi: 10.1016/j.actphy.2025.100086
16. [16]
  Yu Wang , Haiyang Shi , Zihan Chen , Feng Chen , Ping Wang , Xuefei Wang . 具有富电子Pt^δ^-壳层的空心AgPt@Pt核壳催化剂：提升光催化H₂O₂生成选择性与活性. Acta Physico-Chimica Sinica, 2025, 41(7): 100081-. doi: 10.1016/j.actphy.2025.100081
17. [17]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
18. [18]
  .
  CCS Chemistry | 超分子活化底物为自由基促进高效选择性光催化氧化
  . CCS Chemistry, 2025, 7(10.31635/ccschem.025.202405229): -.
19. [19]
  Fangxuan Liu , Ziyan Liu , Guowei Zhou , Tingting Gao , Wenyu Liu , Bin Sun . Hollow structured photocatalysts. Acta Physico-Chimica Sinica, 2025, 41(7): 100071-. doi: 10.1016/j.actphy.2025.100071
20. [20]
  Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Fei Liu . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 100036-. doi: 10.3866/PKU.WHXB202408004

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(1040)
HTML views(266)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142