Citation: Jie Ying WU, Yu Peng TIAN, Fu Xin XIE, Shi Sheng NI. A Novel Biferrocene Trinuclear Complex with Cis-Configuration[J]. Chinese Chemical Letters, ;1999, 10(3): 251-254. shu

A Novel Biferrocene Trinuclear Complex with Cis-Configuration

Department of Chemistry, Anhui University, Hefei 230039

Received Date: 6 October 1998

Fund Project: This work is supported by the National Natural Science Foundation of Chian.Natural Science Foundation of Anhui Province and Open Foundation of State Key Laboratory of Coordination Chemistry.Nanjing University.

A novel biferocene trinuclear complex for Schiff base ligand S-methyt-N-(ferrocenyll-methyl -methylidene) dithiocarbazate (hereafter abbreviated as HL) is described.X-ray diffraction studies established the structure of the palladium complex, PdL₂.The geometry of Pd (Ⅱ) in the complex is close to square planar and in novel cis-configuration with two ferrocene moieties on the same side.Degenerate four-wave mixing (DFWM) measurements show that the complex exhibit obvious nonlinear optical response.
- Palladium complex,
- cis-configuration biferrocene,
- third-order nonlinear opticalproperty
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