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Citation: Liu Dehai, Cai Chaozhong. Catalytic Ring-Opening Polymerization of Cycloalkenes by Mo(CO)₆ System[J]. Chinese Journal of Applied Chemistry, ;1995, 12(5): 107-108. shu

Catalytic Ring-Opening Polymerization of Cycloalkenes by Mo(CO)₆ System

Liu Dehai ,
Cai Chaozhong

Department of Chemistry, Zhanjiang Training College, Zhanjiang 524048

Received Date: 18 October 1994
Revised Date: 6 March 1995

The ring-opening polymerization of cyclopentene,cyclohexene,α-pinene and ter-pene catalyzed by Mo(CO)₆ with CH_nX_4-n(n=0,1;X=Cl,Br) under UV irradiation has been studied. It was found that addition of small amount of anhydrous AlCl₃ promoted the polymerization. The optimum conditions of polymerization were reported.
- cyclopentene,
- cyclohexene,
- poly(α-pinene),
- polyterpene,
- ring-opening polymeriza-tion,
- hexacarbonylmolybdenum,
- aluminium trichloride
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Catalytic Ring-Opening Polymerization of Cycloalkenes by Mo(CO)₆ System