Citation: Di Guanglan, Zhu Zhiliang. Research Progress in LDH-based Photocatalysts[J]. Chemistry, ;2017, 80(3): 228-235. shu

Research Progress in LDH-based Photocatalysts

Di Guanglan ,
Zhu Zhiliang ^*,,

State Key Laboratory of Pollution Control and Resources Reuse, Tongji University, Shanghai 200092

Corresponding author: Zhu Zhiliang, zzl@tongji.edu.cn
Received Date: 27 September 2016
Accepted Date: 12 November 2016

Figures(3)

Layered double hydroxides (LDHs) possess various unique properties such as flexible tenability, uniform distribution of different metal cations in the metal layer, facile exchangeability of intercalated anions and topological transformation characteristics, which makes them to be used as ideal photocatalysts, catalyst supports and precursors. As one kind of novel multifunctional materials, LDH-based photocatalysts have been widely investigated in environmental remediation, energy reservation, industrial catalysis, biomedicine synthesis. However, choosing the feasible path to further optimize the performance of LDH-based photocatalysts to achieve efficient use of solar energy, high conversion efficiency and selectivity of photocatalytic reaction still remains a great challenge. In this paper, the preparation methods of LDH-based photocatalysts are classified into four types including brucite-like sheet construction, guest-intercalation sensitization, de-lamination-assembly and nanocomposite hybrid according to the structure characteristics and the mode of introducing active components. The influence of the preparation methods on photocatalytic performance of LDH-based photocatalysts are introduced and discussed in details. The latest research progress and possible photocatalytic mechanism over LDH-based photocatalysts are reviewed. Finally, the prospects for the development and application of LDH-based photocatalysts are also discussed.
- Layered double hydroxide,
- Photocatalysis,
- Preperation method,
- Catalytic mechanism
1. [1]
  M R Hoffmann, J A Moss, M M Baum. Dalton Transac., 2011, 40:5151-5158.
2. [2]
  H Pan. Renew. Sust. Energ. Rev., 2016, 57:584-601.
3. [3]
  H F Cheng, B B Huang, Y Y Liu et al. Chem. Commun., 2012, 48:9729-31.
4. [4]
  Y Deng, J Liu, J Wang. Adv. Mater., 2014, 26(3):471-476.
5. [5]
6. [6]
  N Shaham-Waldmann, Y Paz. Mat. Sci. Semicon. Proc., 2016, 42:72-80.
7. [7]
  P Zhang, T Wang, X X Chang et al. Acc. Chem. Res., 2016, 49:911-927.
8. [8]
  C X Feng, G G Li, P H Ren et al. Appl. Catal. B, Environ., 2014, 158-159:224-232.
9. [9]
  H L Wang, L S Zhang, Z G Chen et al. Chem. Soc. Rev., 2014, 43:5234-5244.
10. [10]
  Y J Yao, J C Qin, H Chen et al. J. Hazard. Mater., 2015, 291:28-37.
11. [11]
  P J Sideris, U G Nielsen, Z Gan et al. Science, 2008, 321:113-117.
12. [12]
  M F Shao, F Y Ning, J W Zhao et al. J. Am. Chem. Soc., 2012, 134:1071-1077.
13. [13]
  S He, M Wei, D G Evans et al. Chem. Commun., 2013, 49:5912-5920.
14. [14]
  B Sels, D D Vos, M Buntinx et al. Nature, 1999, 400:855-857.
15. [15]
  W Gao, Y Zhao, H Chen et al. Green Chem., 2015, 17:1525-1534.
16. [16]
17. [17]
  S Y Guan, R Z Liang, C Y Li et al. J. Mater. Chem. B, 2016, 4:1331-1336.
18. [18]
  S M Xu, T Pan, Y B Dou et al. J. Phys. Chem. C, 2015, 119:18823-18834.
19. [19]
  K Teramura, S Iguchi, Y Mizuno et al. Angew. Chem. Int. Ed., 2012, 51:8008-8011.
20. [20]
  J Ju, J Bai, X Bo et al. Electrochim. Acta, 2012, 78:569-575.
21. [21]
  C M Li, M Wei, D G Evans et al. Small, 2014, 10:4469-4486.
22. [22]
  C M Li, M Wei, D G Evans et al. Catal. Today, 2015, 247:163-169.
23. [23]
  J T Feng, Y F He, Y N Liu et al. Chem. Soc. Rev., 2015, 44:5291-5319.
24. [24]
  Q Wang, D O'Hare. Chem. Rev., 2012, 112:4124-4155.
25. [25]
  Y F Zhao, X D Jia, G I Waterhouse et al. Adv. Energy Mater., 2015, 150:1974-1994.
26. [26]
  Y Lee, J H Choi, H J Jeon et al. Energy Environ. Sci., 2011, 4:914-920.
27. [27]
28. [28]
  A W Xu, Y Gao, H Q Liu. J. Catal., 2002, 207:151-157.
29. [29]
  N Kannadasan, N Shanmugam, S Cholan et al. Mater. Charact., 2014, 97:37-46.
30. [30]
  M Faisal, A A Ismail, A A Ibrahim et al. Chem. Eng. J., 2013, 229:225-233.
31. [31]
  G Morales-Mendoza, F Tzompantzi, C Garcia-Mendoza et al. Appl. Clay Sci., 2015, 118:38-47.
32. [32]
  C G Silva, Y Bouizi, V Fornés et al. J. Am. Chem. Soc., 2009, 131:13833-13839.
33. [33]
  Y F Zhao, B Li, Q Wang et al. Chem. Sci., 2014, 5:951-958.
34. [34]
  S Iguchi, S Kikkawa, T Kentaro et al. Phys. Chem. Chem. Phys., 2016, 18:13811-13819.
35. [35]
  S Xia, L Zhang, X Zhou et al. Appl. Clay Sci., 2015, 114:577-585.
36. [36]
  P R Chowdhury, K G Bhattacharyya. RSC Adv., 2015, 5:92189-92206.
37. [37]
  S J Kim, Y Lee, D K Lee et al. J. Mater. Chem. A, 2014, 2:4136-4139.
38. [38]
  J Fahel, S Kim, P Durand et al. Dalton Transac., 2016, 45:8224-8235.
39. [39]
  J Liu, G Zhang. Phys. Chem. Chem. Phys., 2014, 16:8178-8192.
40. [40]
  G Mendoza-Damián, F Tzompantzi, A Mantill et al. J. Hazard. Mater., 2013, 263:67-72.
41. [41]
  F Tzompantzi, A Mantilla, F Bañuelos et al. Top. Catal., 2011, 54:257-263.
42. [42]
  J Prince, F Tzompantzi, G Mendoza-Damián et al. Appl. Catal. B Environ., 2015, 163:352-360.
43. [43]
  S He, S T Zhang, J Lu et al. Chem. Commun., 2011, 47:10797-10799.
44. [44]
  J Y Zhu, Z L Zhu, H Zhang et al. J. Colloid Interf. Sci., 2016, 481:144-157.
45. [45]
  G L Fan, F Li, D G Evans et al. Chem. Soc. Rev., 2014, 43:7040-7066.
46. [46]
  C Nan, G Fan, J Fan et al. Mater. Lett., 2013, 106:5-7.
47. [47]
  F E Osterloh. Chem. Soc. Rev., 2013, 42:2294-2320.
48. [48]
  J Hong, Z L Zhu, H T Lu et al. Chem. Eng. J., 2014, 252:267-274.
49. [49]
  X R Gao, M Hu, L X Lei et al. Chem. Commun., 2011, 47:2104-2106.
50. [50]
  S K Parayil, J Baltrusaitis, C M Wu et al. Int. J. Hydrogen Energy, 2013, 38:2656-2669.
51. [51]
  Q Wang, Y Feng, J Feng et al. J. Soli. Stat. Chem., 2011, 184:1551-1555.
52. [52]
  G Bottari, I T G De, D M Guldi et al. Chem. Rev., 2010, 110:6768-6781.
53. [53]
  Z Xiong, Y Xu. Chem. Mater., 2007, 19:1452-1458.
54. [54]
  S Omwoma, W Chen, R Tsunashima et al. Coord. Chem. Rev., 2014, 258-259:58-71.
55. [55]
  J Zhu, H Fan, J Sun et al. Sep. Purif. Technol., 2013, 120:134-140.
56. [56]
  L Mohapatra, K Parida, M Satpathy. J. Phys. Chem. C, 2012, 116:13063-13070.
57. [57]
  K Katsumata, K Sakai, K Ikeda et al. Mater. Lett., 2013, 107:138-140.
58. [58]
  S Kawamura, M C Puscasu, Y Yoshida et al. Appl. Catal. A, Gen., 2015, 504:238-247.
59. [59]
  Y Wei, F C Li, L Liu. RSC Adv., 2014, 4:18044-18051.
60. [60]
  M Adachi-Pagano, C Forano, J P Besse. Chem. Commnn., 2000, 1:91-92.
61. [61]
  J L Gunjakar, T W Kim, H N Kim et al. J. Am. Chem. Soc., 2011, 133:14998-5007.
62. [62]
63. [63]
64. [64]
  Z J Huang, P X Wu, B N Gong et al. J. Mater. Chem. A, 2014, 2:5534-5540.
65. [65]
  G H Zhang, B Z Lin, W W Yan et al. RSC Adv., 2015, 5:5823-5829.
66. [66]
  G Carja, A Nakajima, S Dranca et al. J. Phys. Chem. C, 2010, 114:14722-14728.
67. [67]
  Y Guo, H Zhang, Y Wang et al. J. Phys. Chem. B, 2005, 109:21602-21607.
68. [68]
  Y H Ao, D D Wang, P F Wang et al. Mater. Res. Bull., 2016, 80:23-29.
69. [69]
  W He, Y Yang, L Wang et al. ChemSusChem, 2015, 8:1568-1576.
70. [70]
  Y B Dou, S T Zhang, T Pan et al. Adv. Funct. Mater., 2015, 25:2243-2249.
71. [71]
  J Yu, L Lu, J Li et al. RSC Adv., 2016, 6:12797-12808.
72. [72]
  L Li, Y Feng, Y Li et al. Angew. Chem. Int. Ed., 2009, 48:5888-5892.
73. [73]
  H Wang, X Xiang, F Li. AIChE J. 2010, 56(3):768-778.
74. [74]
  B Li, Y Zhao, S Zhang et al. ACS Appl. Mater. Interf., 2013, 5:10233-10239.
75. [75]
  S Nayak, L Mohapatra, K Parida. J. Mater. Chem. A, 2015, 3:18622-18635.
76. [76]
  Z W Zhao, Y J Sun, F Dong. Nanoscale, 2015, 7:15-37.
77. [77]
  J Yang, H H Chen, J H Gao et al. Mater. Lett., 2016, 164:183-189.
78. [78]
  N N Wang, Y Zhou, C H Chen et al. Catal. Commun., 2016, 73:74-79.
79. [79]
  Y Hou, Z H Wen, S M Cui et al. Nano Lett., 2016, 16:2268-2277.
80. [80]
  F Tzompantzi, G Mendoza, J L Rico et al. Catal. Today, 2014, 220:56-60.
81. [81]
1. [1]
  Liu Lin , Zemin Sun , Huatian Chen , Lian Zhao , Mingyue Sun , Yitao Yang , Zhensheng Liao , Xinyu Wu , Xinxin Li , Cheng Tang . Recent Advances in Electrocatalytic Two-Electron Water Oxidation for Green H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(4): 2305019-0. doi: 10.3866/PKU.WHXB202305019
2. [2]
  Meiran Li , Yingjie Song , Xin Wan , Yang Li , Yiqi Luo , Yeheng He , Bowen Xia , Hua Zhou , Mingfei Shao . Nickel-Vanadium Layered Double Hydroxides for Efficient and Scalable Electrooxidation of 5-Hydroxymethylfurfural Coupled with Hydrogen Generation. Acta Physico-Chimica Sinica, 2024, 40(9): 2306007-0. doi: 10.3866/PKU.WHXB202306007
3. [3]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
4. [4]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
5. [5]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
6. [6]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-0. doi: 10.3866/PKU.WHXB202312014
7. [7]
  Xia ZHANG , Yushi BAI , Xi CHANG , Han ZHANG , Haoyu ZHANG , Liman PENG , Shushu HUANG . Preparation and photocatalytic degradation performance of rhodamine B of BiOCl/polyaniline. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 913-922. doi: 10.11862/CJIC.20240255
8. [8]
  Yifan ZHAO , Qiyun MAO , Meijing GUO , Guoying ZHANG , Tongliang HU . Z-scheme bismuth-based multi-site heterojunction: Synthesis and hydrogen production from photocatalytic hydrogen production. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1318-1330. doi: 10.11862/CJIC.20250001
9. [9]
  Jingyu Cai , Xiaoyu Miao , Yulai Zhao , Longqiang Xiao . Exploratory Teaching Experiment Design of FeOOH-RGO Aerogel for Photocatalytic Benzene to Phenol. University Chemistry, 2024, 39(4): 169-177. doi: 10.3866/PKU.DXHX202311028
10. [10]
  Ronghui LI . Photocatalysis performance of nitrogen-doped CeO₂ thin films via ion beam-assisted deposition. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1123-1130. doi: 10.11862/CJIC.20240440
11. [11]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-Based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-0. doi: 10.3866/PKU.WHXB202406029
12. [12]
  Jingping Li , Suding Yan , Jiaxi Wu , Qiang Cheng , Kai Wang . Improving hydrogen peroxide photosynthesis over inorganic/organic S-scheme photocatalyst with LiFePO₄. Acta Physico-Chimica Sinica, 2025, 41(9): 100104-0. doi: 10.1016/j.actphy.2025.100104
13. [13]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . Architecting Inorganic/Organic S-Scheme Heterojunction of Bi₄Ti₃O₁₂ Coupling with g-C₃N₄ for Photocatalytic H₂O₂ Production from Pure Water. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-0. doi: 10.3866/PKU.WHXB202403009
14. [14]
  Yuchen Zhou , Huanmin Liu , Hongxing Li , Xinyu Song , Yonghua Tang , Peng Zhou . Designing thermodynamically stable noble metal single-atom photocatalysts for highly efficient non-oxidative conversion of ethanol into high-purity hydrogen and value-added acetaldehyde. Acta Physico-Chimica Sinica, 2025, 41(6): 100067-0. doi: 10.1016/j.actphy.2025.100067
15. [15]
  Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . Remarkable Photocatalytic H₂O₂ Production Efficiency over Ultrathin g-C₃N₄ Nanosheet with Large Surface Area and Enhanced Crystallinity by Two-Step Calcination. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-0. doi: 10.3866/PKU.WHXB202406019
16. [16]
  Yuting Bai , Cenqi Yan , Zhen Li , Jiaqiang Qin , Pei Cheng . Preparation of High-Strength Polyimide Porous Films with Thermally Closed Pore Property by In Situ Pore Formation Method. Acta Physico-Chimica Sinica, 2024, 40(9): 2306010-0. doi: 10.3866/PKU.WHXB202306010
17. [17]
  Ruolin CHENG , Yue WANG , Xiyao NIU , Huagen LIANG , Ling LIU , Shijian LU . Efficient photothermal catalytic CO₂ cycloaddition over W₁₈O₄₉/rGO composites. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1276-1284. doi: 10.11862/CJIC.20240424
18. [18]
  Yuanqing Wang , Yusong Pan , Hongwu Zhu , Yanlei Xiang , Rong Han , Run Huang , Chao Du , Chengling Pan . Enhanced Catalytic Activity of Bi₂WO₆ for Organic Pollutants Degradation under the Synergism between Advanced Oxidative Processes and Visible Light Irradiation. Acta Physico-Chimica Sinica, 2024, 40(4): 2304050-0. doi: 10.3866/PKU.WHXB202304050
19. [19]
  Changjun You , Chunchun Wang , Mingjie Cai , Yanping Liu , Baikang Zhu , Shijie Li . Improved Photo-Carrier Transfer by an Internal Electric Field in BiOBr/N-rich C₃N₅ 3D/2D S-Scheme Heterojunction for Efficiently Photocatalytic Micropollutant Removal. Acta Physico-Chimica Sinica, 2024, 40(11): 2407014-0. doi: 10.3866/PKU.WHXB202407014
20. [20]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037

Get Citation

PDF

XML

Metrics

PDF Downloads(34)
Abstract views(4692)
HTML views(1786)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142