Citation: Gao Qi, Zhu Xiaoqin, Zhai Liangjun. Alkylamine-Mediated Synthesis and Growth Mechanism of Copper Nanorods[J]. Chemistry, ;2019, 82(12): 1093-1097. shu

Alkylamine-Mediated Synthesis and Growth Mechanism of Copper Nanorods

School of Mathematics and Physics, Jiangsu University of Technology, Changzhou 213001

Corresponding author: Zhai Liangjun, zhailiangjun@jsut.edu.cn
Received Date: 9 June 2019
Accepted Date: 23 September 2019

Figures(6)

Uniform Cu nanoparticles were synthesized via complexation reaction and solvothermal reaction by using copper chloride as reaction precursor, glucose as reducing agent and alkylamine (mixture of hexadecylamine and octadecylamine) as complexing agents and surface capping agents. Subsequently, the Cu nanoparticles which were 100 nm in diameter spontaneously grew into Cu nanorods (including nanoparticles). The morphological characteristics of the reduction products after solvothermal reaction for 1h, 3h and 5h were characterized respectively. It is deduced that the reduced Cu atoms first nucleated uniformly to form primary Cu nanoparticles, and then grew into five-fold twin secondary Cu nanoparticles through Ostwald aging process. Eventually, due to the high growth activity of the twin structure, anisotropy Cu nanorods were simply prepared under the surface coating of alkylamine. This strategy could provide an effective method for preparing copper nanorods and reduce the cost of synthesis of one-dimensional Cu nanomaterials.
- Copper nanorod,
- Hydrothermal synthesis method,
- Five-fold twinned,
- Growth mechanism
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沈阳化工大学材料科学与工程学院沈阳 110142