Home

Citation: Wang Yu, Zhang Lipeng, Zhao Yuxia. Study on the Relationship of Structures and Spectral Properties of Aromatic Ketone Derivatives with Twisted Intramolecular Charge Transfer[J]. Chemistry, ;2019, 82(7): 612-617. shu

Study on the Relationship of Structures and Spectral Properties of Aromatic Ketone Derivatives with Twisted Intramolecular Charge Transfer

Wang Yu ^1,2 ,
Zhang Lipeng ¹ ,
Zhao Yuxia ^1,,

1.
Technical Institute of Physics and Chemistry, CAS, Beijing 100190
2.
University of Chinese Academy of Sciences, Beijing 100049

Corresponding author: Zhao Yuxia, yuxia.zhao@mail.ipc.ac.cn
Received Date: 11 March 2019
Accepted Date: 9 April 2019

Figures(8)

A series of compounds with twisted intramolecular charge transfer (TICT) based on aromatic ketone derivatives were synthesized and characterized. The effects of different conjugated groups and substituent positions on the spectral properties of these compounds were studied by characterization of their linear photophysical and two-photon absorption properties. Additionally, the intramolecular charge transfer properties of these compounds were also studied by solvent effect. Combined with theoretical calculations, the results showed that the molecular conjugated skeleton and the position of substituents can significantly affect the intramolecular charge transfer characteristics. Fluorenone based compounds exhibite strong two-photon absorption and aggregation-induced fluorescence enhancement effects, which have potential applications in biological imaging.
- Intramolecular charge transfer,
- Two photon absorption,
- Fluorescence,
- Aggregation-induced emission,
- Biological imaging
1. [1]
  S Sasaki, G P C Drummen, G I Konishi. J. Mater. Chem. C, 2016, 4(14): 2731-2743.
2. [2]
  A C Benniston, A Harriman. Chem. Soc. Rev., 2006, 35(2): 169-179.
3. [3]
  G Ramakrishna, T Goodson. J. Phys. Chem. A, 2007, 111(6): 993-1000.
4. [4]
  G S He, L S Tan, Q Zheng et al. Chem. Rev., 2008, 108(4): 1245-1330.
5. [5]
  F Helmchen, W Denk. Nat. Methods, 2005, 2(12): 932-940.
6. [6]
  K S Lee, R H Kim, D Y Yang et al. Prog. Polym. Sci., 2008, 33(6): 631-681.
7. [7]
  Z Sun, L P Zhang, F Wu et al. Adv. Funct. Mater., 2017, 27(48): 1704079.
8. [8]
  K Rurack: Fluorescence Quantum Yields: Methods of Determination and Standards, Standardization and Quality Assurance in Fluorescence Measurements I, 2008: 101-145.
9. [9]
  A L Capodilupo, V Vergaro, E Fabiano et al. J. Mater. Chem. B, 2015, 3(16): 3315-3323.
10. [10]
  N S Makarov, M Drobizhev, A Rebane. Opt. Express, 2008, 16(6): 4029-4047.
11. [11]
  D Cvejn, E Michail, K Seintis et al. RSC Adv., 2016, 6(16): 12819-12828.
12. [12]
  J R Lakowicz. Principles of Fluorescence Spectroscopy. Springer Science & Business Media, 2013.
13. [13]
  M J Frisch, G W Trucks, H B Schlegel et al. Gaussian 09. Wallingford, CT, 2009.
1. [1]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
2. [2]
  Feng Lu , Tao Wang , Qi Wang . Preparation and Characterization of Water-Soluble Silver Nanoclusters: A New Design and Teaching Practice in Materials Chemistry Experiment. University Chemistry, 2025, 40(4): 375-381. doi: 10.12461/PKU.DXHX202406005
3. [3]
  Yanyang Li , Zongpei Zhang , Kai Li , Shuangquan Zang . Ideological and Political Design for the Comprehensive Experiment of the Synthesis and Aggregation-Induced Emission (AIE) Performance Study of Salicylaldehyde Schiff-Base. University Chemistry, 2024, 39(2): 105-109. doi: 10.3866/PKU.DXHX202307020
4. [4]
  Hongxia Yan , Rui Wu , Weixu Feng , Yan Zhao , Yi Yan . Innovation Inspired by Classical Chemistry: Luminescent Hyperbranched Polysiloxanes. University Chemistry, 2025, 40(4): 154-159. doi: 10.12461/PKU.DXHX202409010
5. [5]
  Ruoqian Zhang , Chaoqun Mu , Yali Hou , Mingming Zhang . 四苯乙烯基多组分金属有机笼的构筑及其固态发光性能研究. University Chemistry, 2025, 40(8): 277-283. doi: 10.12461/PKU.DXHX202410027
6. [6]
  Qin Li , Kexin Yang , Qinglin Yang , Xiangjin Zhu , Xiaole Han , Tao Huang . Illuminating Chlorophyll: Innovative Chemistry Popularization Experiment. University Chemistry, 2024, 39(9): 359-368. doi: 10.3866/PKU.DXHX202309059
7. [7]
  YanYuan Jia , Rong Rong , Jie Liu , Jing Guo , GuoYu Jiang , Shuo Guo . Unity is Strength, and Independence Shines: A Science Popularization Experiment on AIE and ACQ Effects. University Chemistry, 2024, 39(9): 349-358. doi: 10.12461/PKU.DXHX202402035
8. [8]
  Rui Gao , Ying Zhou , Yifan Hu , Siyuan Chen , Shouhong Xu , Qianfu Luo , Wenqing Zhang . Design, Synthesis and Performance Experiment of Novel Photoswitchable Hybrid Tetraarylethenes. University Chemistry, 2024, 39(5): 125-133. doi: 10.3866/PKU.DXHX202310050
9. [9]
  Zehua Zhang , Haitao Yu , Yanyu Qi . Design Strategy for Thermally Activated Delayed Fluorescence Materials with Multiple Resonance Effect. Acta Physico-Chimica Sinica, 2025, 41(1): 100006-0. doi: 10.3866/PKU.WHXB202309042
10. [10]
  Chen LU , Qinlong HONG , Haixia ZHANG , Jian ZHANG . Syntheses, structures, and properties of copper-iodine cluster-based boron imidazolate framework materials. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 149-154. doi: 10.11862/CJIC.20240407
11. [11]
  Hongxia Yan , Weixu Feng , Junyan Yao , Wei Tian , Rui Wang . Illuminating the Teaching of Science and Engineering Graduate Courses with “Curriculum Ideology and Politics”. University Chemistry, 2024, 39(6): 122-127. doi: 10.3866/PKU.DXHX202310059
12. [12]
  Jinlong YAN , Weina WU , Yuan WANG . A simple Schiff base probe for the fluorescent turn-on detection of hypochlorite and its biological imaging application. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1653-1660. doi: 10.11862/CJIC.20240154
13. [13]
  Siyi ZHONG , Xiaowen LIN , Jiaxin LIU , Ruyi WANG , Tao LIANG , Zhengfeng DENG , Ao ZHONG , Cuiping HAN . Targeting imaging and detection of ovarian cancer cells based on fluorescent magnetic carbon dots. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1483-1490. doi: 10.11862/CJIC.20240093
14. [14]
  Zishuo Yi , Peng Liu , Yan Xu . Fluorescent “Chameleon”: A Popular Science Experiment Based on Dynamic Luminescence. University Chemistry, 2024, 39(9): 304-310. doi: 10.12461/PKU.DXHX202311079
15. [15]
  Yanxi LIU , Mengjia XU , Haonan CHEN , Quan LIU , Yuming ZHANG . A fluorescent-colorimetric probe for peroxynitrite-anion-imaging in living cells. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1112-1122. doi: 10.11862/CJIC.20240423
16. [16]
  Xinyi Hong , Tailing Xue , Zhou Xu , Enrong Xie , Mingkai Wu , Qingqing Wang , Lina Wu . Non-Site-Specific Fluorescent Labeling of Proteins as a Chemical Biology Experiment. University Chemistry, 2024, 39(4): 351-360. doi: 10.3866/PKU.DXHX202310010
17. [17]
  Lin Song , Dourong Wang , Biao Zhang . Innovative Experimental Design and Research on Preparing Flexible Perovskite Fluorescent Gels Using 3D Printing. University Chemistry, 2024, 39(7): 337-344. doi: 10.3866/PKU.DXHX202310107
18. [18]
  Han ZHANG , Jianfeng SUN , Jinsheng LIANG . Hydrothermal synthesis and luminescent properties of broadband near-infrared Na₃CrF₆ phosphor. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 349-356. doi: 10.11862/CJIC.20240098
19. [19]
  Yan ZHAO , Xiaokang JIANG , Zhonghui LI , Jiaxu WANG , Hengwei ZHOU , Hai GUO . Preparation and fluorescence properties of Eu³⁺-doped CaLaGaO₄ red-emitting phosphors. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1861-1868. doi: 10.11862/CJIC.20240242
20. [20]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357

Get Citation

PDF

XML

Metrics

PDF Downloads(17)
Abstract views(1263)
HTML views(563)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return