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Citation: Lin Xinxin, W E Lindsell. Selective Reduction of Oxygen-Containing Ferrocene Derivatives with NaBH₃Cn-ZnCl₂[J]. Chinese Journal of Applied Chemistry, ;1995, 12(2): 101-103. shu

Selective Reduction of Oxygen-Containing Ferrocene Derivatives with NaBH₃Cn-ZnCl₂

Lin Xinxin ¹ ,
W E Lindsell ²

1.
Guangzhou Institute of Chemistry, Chinese Academy of Sciences, Guangzhou 510650;
2.
Department of Chemistry, Heriot-Watt University, United Kingdom

Received Date: 24 July 1994
Revised Date: 2 December 1994

NaBH₃CN-ZnCl₂ was applied for the selective reduction deoxygenation of hydroxyl and carbonyl groups in ferrocene derivatives under mild condition without affecting on the carboxy groups. The molar ratio of B/Fe and Zn/Fe,as well as the solvents showed impor-tant influences on the deoxygenation. The possible intermediates were suggested.
- sodium cyanoborohydrate,
- zink chloride,
- ferrocene derivative,
- selective reduction
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Selective Reduction of Oxygen-Containing Ferrocene Derivatives with NaBH3Cn-ZnCl2

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Selective Reduction of Oxygen-Containing Ferrocene Derivatives with NaBH₃Cn-ZnCl₂