Citation: ZHAO Ke-ke, HUANG Xin, JIA Li-tao, HOU Bo, LI De-bao. Effect of W addition on the catalytic properties of Mo/HZSM-5 catalyst in methane non-oxidative dehydroaromatization[J]. Journal of Fuel Chemistry and Technology, ;2017, 45(11): 1384-1391. shu

Effect of W addition on the catalytic properties of Mo/HZSM-5 catalyst in methane non-oxidative dehydroaromatization

ZHAO Ke-ke ^1,2 ,
HUANG Xin ^1,, ,
JIA Li-tao ^1,, ,
HOU Bo ¹ ,
LI De-bao ¹

1.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: HUANG Xin, huangxin@sxicc.ac.cn JIA Li-tao, jialitao@sxicc.ac.cn
Received Date: 31 May 2017
Revised Date: 13 August 2017

Fund Project: The project was supported by the National Natural Science Foundation of China (21273265) and the Coal Base Key Technologies R & D Program of ShanXi Province (MH2014-13)the Coal Base Key Technologies R & D Program of ShanXi Province MH2014-13the National Natural Science Foundation of China 21273265

Figures(8)

Mo/HZSM-5, Mo-W/HZSM-5 and W/HZSM-5 catalysts were prepared via a conventional impregnation method. The catalysts were characterized by means of XRD, BET, Py-FTIR, H₂-TPR, XPS, TEM, NH₃-TPD, TPO, TG and Raman, and were evaluated in methane non-oxidative dehydroaromatization(MDA). Compared with Mo/HZSM-5, the CH₄ conversion, aromatics yield and catalytic stability were improved by W addition for Mo-W/HZSM-5 in MDA reaction. H₂-TPR and XPS results indicated that the octahedral (WO₆)^n- groups existed in Mo-W/HZSM-5 were more easily reduced to W⁴⁺-containing species in MDA reaction in comparison with W/HZSM-5, and W⁴⁺-containing species was correlated with the high MDA activity. At the same time, it is found that graphitic-like coking is the main reason of catalyst deactivation for Mo/HZSM-5, and this coking over Mo-W/HZSM-5 catalyst can be inhibited by W addition during MDA.
- non-oxidative dehydroaromatization,
- molybdenum,
- coking,
- tungsten
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沈阳化工大学材料科学与工程学院沈阳 110142

Effect of W addition on the catalytic properties of Mo/HZSM-5 catalyst in methane non-oxidative dehydroaromatization

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com