Citation: Ling Guang QIU, An Jian XIE, Yu Hua SHEN. Synthesis and Surface Activity of Novel Triazole-based Cationic Gemini Surfactants[J]. Chinese Chemical Letters, ;2003, 14(6): 653-656. shu

Synthesis and Surface Activity of Novel Triazole-based Cationic Gemini Surfactants

1.
School of Chemistry and Chemical Engineering, Anhui University, Hefei 230039;
2.
Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031

Received Date: 23 August 2002

Fund Project: We are grateful for the financial support from the National Natural Science Foundation of China (29971001,20031010), the Natural Science Foundation of Anhui Province (0045115), and the Science Foundation for Excellent Young Teachers of Universities of Anhui Province (01080309).

The synthesis and surfactant activities of two new cationic gemini surfactants containingtriazole compound as spacer were described. Their critical micelle concentrations (CMC), whichare 1.8×l0^-4 mol/L and 3.9×10^-4 mol/L respectively, are much lower than that of conventionalsurfactant cetyltrimethyl ammonium chloride (CTAC). In addition, compared with some geminisurfactants containing phenylene, xylylene and stilbenyl as spacer, this new kind of surfactants hasgood solubility in water at room temperature because of containing more hydrophilic groups oratoms in molecules.
- Gemini surfactant,
- cationic surfactant,
- critical micelle concentration,
- triazole,
- synthesis
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