Citation: Yingying Wu, Yongsheng Wang, Xinping Zhang, Tian Qiu, Zhengkang Duan. Preparation of TS-1 Molecular Sieve and Its Research Progress in Cyclohexanone Ammoximation Process[J]. Chemistry, ;2021, 84(4): 359-364. shu

Preparation of TS-1 Molecular Sieve and Its Research Progress in Cyclohexanone Ammoximation Process

College of Chemical Engineering, Xiangtan University, Hunan Collaborative Innovation Center of New Chemical Technologies for Environmental Benignity and Efficient Resource Utilization, Xiangtan, 411105

Corresponding author: Zhengkang Duan, dzk0607@163.com
Received Date: 9 October 2020
Accepted Date: 21 December 2020

Figures(2)

Cyclohexanone oxime, an important organic intermediate, is widely applied in synthetic fiber, industrial manufacturing, medicine, and daily necessities. Many methods for the synthetic of cyclohexanone oxime are available, in which the cyclohexanone ammoximation reaction has attracted extensive attention because of the simple process, mild conditions, and no by-products. In this review, the research progress in the preparation of cyclohexanone oxime catalyst and continuous process are summarized. Although the TS-1 catalyst has made a great success at present, there are still some disadvantages such as high cost of the catalyst, difficulty in separating the reaction liquid from the catalyst, and blockage of the catalyst pores by the reaction liquid, resulting in catalyst deactivation. In addition, the research priorities for the development of efficient, green and stable TS-1 catalysts and the future research directions of the continuous cyclohexanone oxime process are prospected.
- Cyclohexanone,
- Cyclohexanone oxime,
- Catalyst,
- TS-1 molecular sieve,
- Continuous process
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