Citation: ZHAO Li-ye, WANG Liang, LI Chun-hu. Synthesis and characterization of a novel BiOBr/HPW/Au for the enhanced photocatalytic activity[J]. Journal of Fuel Chemistry and Technology, ;2020, 48(10): 1263-1269. shu

Synthesis and characterization of a novel BiOBr/HPW/Au for the enhanced photocatalytic activity

College of Chemistry and Chemical Engineering, Ocean University of China, Qindao 266100, China

Corresponding author: WANG Liang, wangliang_good@163.com
Received Date: 11 August 2020
Revised Date: 4 October 2020

Fund Project: State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering 2018-K21The project was supported by State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering (2018-K21)

Figures(8)

In this study, a novel BiOBr/HPW/Au photocatalyst was prepared via hydrothermal method followed by photo-reduction method. The characterization results indicated the successful introduction of HPW and Au in BiOBr. BiOBr/HPW/Au exhibited excellent photocatalytic activity in RhB degradation. The degradation rate constant of BiOBr/HPW/Au was 3.55 times higher than that of BiOBr. Radical scavenger experiments showed that ·O₂^- was the dominant reactive radical species. A possible mechanism of the enhanced photocatalytic activity was attributed to the synergistic effect of BiOBr, HPW and Au, which resulted in enhanced quantum efficiency and high light harvesting efficiency.
- BiOBr,
- HPW,
- Au,
- photocatalyst
1. [1]
  MENG X, LI Z, CHEN J, XIE H, ZHANG Z. Enhanced visible light-induced photocatalytic activity of surface-modified BiOBr with Pd nanoparticles[J]. Appl Surf Sci, 2018,433:76-87. doi: 10.1016/j.apsusc.2017.09.103
2. [2]
  AO Y, WANG K, WANG P, WANG C, HOU J. Synthesis of novel 2D-2D p-n heterojunction BiOBr/La₂Ti₂O₇ composite photocatalyst with enhanced photocatalytic performance under both UV and visible light irradiation[J]. Appl Catal B:Environ, 2016,194:157-168. doi: 10.1016/j.apcatb.2016.04.050
3. [3]
  GUO Q, FU L, YAN T, TIAN W, MA D, LI J, JIANG Y, WANG X. Improved photocatalytic activity of porous ZnO nanosheets by thermal deposition graphene-like g-C₃N₄ for CO₂ reduction with H₂O vapor[J]. Appl Surf Sci, 2020,509144773. doi: 10.1016/j.apsusc.2019.144773
4. [4]
  NGUYEN C H, TRAN M L, TRAN T T V, JUANG R. Enhanced removal of various dyes from aqueous solutions by UV and simulated solar photocatalysis over TiO₂/ZnO/rGO composites[J]. Sep Purif Technol, 2020,232115962. doi: 10.1016/j.seppur.2019.115962
5. [5]
  YE L, JIN X, LIU C, DING C, XIE H, CHU K, WONG P. Thickness-ultrathin and bismuth-rich strategies for BiOBr to enhance photoreduction of CO₂ into solar fuels[J]. Appl Catal B:Environ, 2016,187:281-290. doi: 10.1016/j.apcatb.2016.01.044
6. [6]
  XU Z, ZHENG R, CHEN Y, ZHU J, BIAN Z. Ordered mesoporous Fe/TiO₂ with light enhanced photo-Fenton activity[J]. Chin J Catal, 2019,40:631-637.
7. [7]
  WANG Y, LI J, WANG Q. The performance of daylight photocatalytic activity towards degradation of MB by the flower-like and approximate flower-like complexes of graphene with ZnO and Cerium doped ZnO[J]. Optik, 2020,204164131. doi: 10.1016/j.ijleo.2019.164131
8. [8]
  QIU B, LI C, SHEN X, WANG W, REN H, LI Y, TANG J. Revealing the size effect of metallic CoS₂ on CdS nanorods for photocatalytic hydrogen evolution based on Schottky junction[J]. Appl Catal A:Gen, 2020,592117377. doi: 10.1016/j.apcata.2019.117377
9. [9]
  XU C, ZHANG W. Facile synthesis of nitrogen deficient g-C₃N₄ by copolymerization of urea and formamide for efficient photocatalytic hydrogen evolution[J]. Mol Catal, 2018,453:85-92. doi: 10.1016/j.mcat.2018.04.029
10. [10]
  GUAN Y, WU J, LIU Q, GU M, LIN Y, QI Y, JIA T, PAN W, HE P, LI Q. Fabrication of BiOI/MoS₂ heterojunction photocatalyst with different treatment methods for enhancing photocatalytic performance under visible-light[J]. Mater Res Bull, 2019,120:110579-110589. doi: 10.1016/j.materresbull.2019.110579
11. [11]
  ALLAGUI L, CHOUCHENE B, GRIES T, MEDJAHDI G, GIROT E, FRAMBOISIER X, AMARA A, BALAN L, SCHNEIDER R. Core/shell rGO/BiOBr particles with visible photocatalytic activity towards water pollutants[J]. Appl Surf Sci, 2019,490:580-591. doi: 10.1016/j.apsusc.2019.06.091
12. [12]
  SHI Z, ZHANG Y, SHEN X, DUOERKUN G, ZHU B, ZHANG L, LI M, CHEN Z. Fabrication of g-C₃N₄/BiOBr heterojunctions on carbon fibers as weaveable photocatalyst for degrading tetracycline hydrochloride under visible light[J]. Chem Eng J, 2020,386124010. doi: 10.1016/j.cej.2020.124010
13. [13]
  MENG P, HENG H, SUN Y, HUANG J, YANG J, LIU X. Positive effects of phosphotungstic acid on the in-situ solid-state polymerization and visible light photocatalytic activity of polyimide-based photocatalyst[J]. Appl Catal B:Environ, 2018,226:487-498. doi: 10.1016/j.apcatb.2018.01.004
14. [14]
  XU L, ZANG H, ZHANG Q, CHEN Y, WEI Y, YAN J, ZHAO Y. Photocatalytic degradation of atrazine by H₃PW₁₂O₄₀/Ag-TiO₂:Kinetics, mechanism and degradation pathways[J]. Chem Eng J, 2013,232:174-182. doi: 10.1016/j.cej.2013.07.095
15. [15]
  GUO J, YAN D, LAM F, DEKA B, LV X, NG Y, AN A. Self-cleaning BiOBr/Ag photocatalytic membrane for membrane regeneration under visible light in membrane distillation[J]. Chem Eng J, 2019,378122173. doi: 10.1016/j.cej.2019.122173
16. [16]
  BAI Y, CHEN T, WANG P, WANG L, YE L, SHI X, BAI W. Size-dependent role of gold in g-C₃N₄/BiOBr/Au system for photocatalytic CO₂ reduction and dye degradation[J]. Sol Energy Mater Sol Cells, 2016,157:406-414. doi: 10.1016/j.solmat.2016.07.001
17. [17]
  GUAN Z, LI Q, SHEN B, BAO S, ZHANG J, TIAN B. Fabrication of Co₃O₄ and Au co-modified BiOBr flower-like microspheres with high photocatalytic efficiency for sulfadiazine degradation[J]. Sep Purif Technol, 2020,234116100. doi: 10.1016/j.seppur.2019.116100
18. [18]
  XIONG X, DING L, WANG Q, LI Y, JIANG Q, HU J. Synthesis and photocatalytic activity of BiOBr nanosheets with tunable exposed {010} facets[J]. Appl Catal B:Environ, 2016,188:283-291. doi: 10.1016/j.apcatb.2016.02.018
19. [19]
  DI J, XIA J, JI M, WANG B, YIN S, ZHANG Q, CHEN Z, LI H. Advanced photocatalytic performance of graphene-like BN modified BiOBr flower-like materials for the removal of pollutants and mechanism insight[J]. Appl Catal B:Environ, 2016,183:254-262. doi: 10.1016/j.apcatb.2015.10.036
20. [20]
  LI H, HU T, LIU J, SONG S, DU N, ZHANG R, HOU W. Thickness-dependent photocatalytic activity of bismuth oxybromide nanosheets with highly exposed (010) facets[J]. Appl Catal B:Environ, 2016,182:431-438. doi: 10.1016/j.apcatb.2015.09.050
21. [21]
  LI Q, LU M, WANG W, ZHAO W, CHEN G, SHI H. Fabrication of 2D/2D g-C₃N₄/Au/Bi₂WO₆ Z-scheme photocatalyst with enhanced visible-light-driven photocatalytic activity[J]. Appl Surf Sci, 2020,508144182. doi: 10.1016/j.apsusc.2019.144182
22. [22]
  GAO Z, YAO B, XUE T, MA M. Effect and study of reducing agent NaBH₄ on Bi/BiOBr/CdS photocatalyst[J]. Mater Lett, 2020,259126874. doi: 10.1016/j.matlet.2019.126874
23. [23]
  SUN Y, MENG P, LIU X. Self-assembly of tungstophosphoric acid/acidified carbon nitride hybrids with enhanced visible-light-driven photocatalytic activity for the degradation of imidacloprid and acetamiprid[J]. Appl Surf Sci, 2018,456:259-269. doi: 10.1016/j.apsusc.2018.06.104
24. [24]
  AYATI A, TANHAEI B, BAMOHARRM F, AHMADPOUR A, MAYDANNIK P, SILLANPAA M. Photocatalytic degradation of nitrobenzene by gold nanoparticles decorated polyoxometalate immobilized TiO₂ nanotubes[J]. Sep Purif Technol, 2016,171:62-68. doi: 10.1016/j.seppur.2016.07.015
25. [25]
  WANG L, ZHANG H G, GUO C, FENG L J, LI C H, WANG W T. Facile constructing plasmonic Z-scheme Au NPs/g-C₃N₄/BiOBr for enhanced visible light photocatalytic activity[J]. J Fuel Chem Technol, 2019,47(7):834-842. doi: 10.1016/S1872-5813(19)30036-2
1. [1]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
2. [2]
  Yujia LI , Tianyu WANG , Fuxue WANG , Chongchen WANG . Direct Z-scheme MIL-100(Fe)/BiOBr heterojunctions: Construction and photo-Fenton degradation for sulfamethoxazole. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 481-495. doi: 10.11862/CJIC.20230314
3. [3]
  Yuan CONG , Yunhao WANG , Wanping LI , Zhicheng ZHANG , Shuo LIU , Huiyuan GUO , Hongyu YUAN , Zhiping ZHOU . Construction and photocatalytic properties toward rhodamine B of CdS/Fe₃O₄ heterojunction. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2241-2249. doi: 10.11862/CJIC.20240219
4. [4]
  Zhinan GUO , Junli WANG , Qiang ZHAO , Zhifang JIA , Zuopeng LI , Kewei WANG , Yong GUO . Cu₂O/Bi₂CrO₆ Z-scheme heterojunction: Construction and photocatalytic degradation properties for tetracycline. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 741-752. doi: 10.11862/CJIC.20240403
5. [5]
  Linping Li , Junhui Su , Yanping Qiu , Yangqin Gao , Ning Li , Lei Ge . Design and fabrication of ternary Au/Co3O4/ZnCdS spherical composite photocatalyst for facilitating efficient photocatalytic hydrogen production. Chinese Journal of Structural Chemistry, 2024, 43(12): 100472-100472. doi: 10.1016/j.cjsc.2024.100472
6. [6]
  Qiang ZHAO , Zhinan GUO , Shuying LI , Junli WANG , Zuopeng LI , Zhifang JIA , Kewei WANG , Yong GUO . Cu₂O/Bi₂MoO₆ Z-type heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 885-894. doi: 10.11862/CJIC.20230435
7. [7]
  Yaping ZHANG , Tongchen WU , Yun ZHENG , Bizhou LIN . Z-scheme heterojunction β-Bi₂O₃ pillared CoAl layered double hydroxide nanohybrid: Fabrication and photocatalytic degradation property. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 531-539. doi: 10.11862/CJIC.20240256
8. [8]
  Kun Tang , Yu-Wu Zhong . Water reduction by an organic single-chromophore photocatalyst. Chinese Journal of Structural Chemistry, 2024, 43(8): 100376-100376. doi: 10.1016/j.cjsc.2024.100376
9. [9]
  Haojie Song , Laiyu Luo , Siyu Wang , Guo Zhang , Baojiang Jiang . Advances in poly(heptazine imide)/poly(triazine imide) photocatalyst. Chinese Chemical Letters, 2024, 35(10): 109347-. doi: 10.1016/j.cclet.2023.109347
10. [10]
  Kun Wang , Jiaxuan Qiu , Zefei Wu , Yang Liu , Yongqi Liu , Xiangpeng Chen , Bao Zang , Jianmei Chen , Yunchao Lei , Longlu Wang , Qiang Zhao . Wafer-level GaN-based nanowires photocatalyst for water splitting. Chinese Chemical Letters, 2025, 36(3): 109993-. doi: 10.1016/j.cclet.2024.109993
11. [11]
  Xingmin Chen , Yunyun Wu , Yao Tang , Peishen Li , Shuai Gao , Qiang Wang , Wen Liu , Sihui Zhan . Construction of Z-scheme Cu-CeO₂/BiOBr heterojunction for enhanced photocatalytic degradation of sulfathiazole. Chinese Chemical Letters, 2024, 35(7): 109245-. doi: 10.1016/j.cclet.2023.109245
12. [12]
  Xianghai Song , Xiaoying Liu , Zhixiang Ren , Xiang Liu , Mei Wang , Yuanfeng Wu , Weiqiang Zhou , Zhi Zhu , Pengwei Huo . Insights into the greatly improved catalytic performance of N-doped BiOBr for CO₂ photoreduction. Acta Physico-Chimica Sinica, 2025, 41(6): 100055-. doi: 10.1016/j.actphy.2025.100055
13. [13]
  Xue Xin , Qiming Qu , Islam E. Khalil , Yuting Huang , Mo Wei , Jie Chen , Weina Zhang , Fengwei Huo , Wenjing Liu . Hetero-phase zirconia encapsulated with Au nanoparticles for boosting electrocatalytic nitrogen reduction. Chinese Chemical Letters, 2024, 35(5): 108654-. doi: 10.1016/j.cclet.2023.108654
14. [14]
  Guorong Li , Yijing Wu , Chao Zhong , Yixin Yang , Zian Lin . Predesigned covalent organic framework with sulfur coordination: Anchoring Au nanoparticles for sensitive colorimetric detection of Hg(Ⅱ). Chinese Chemical Letters, 2024, 35(5): 108904-. doi: 10.1016/j.cclet.2023.108904
15. [15]
  Bicheng Zhu , Jingsan Xu . S-scheme heterojunction photocatalyst for H2 evolution coupled with organic oxidation. Chinese Journal of Structural Chemistry, 2024, 43(8): 100327-100327. doi: 10.1016/j.cjsc.2024.100327
16. [16]
  Huihui LIU , Baichuan ZHAO , Chuanhui WANG , Zhi WANG , Congyun ZHANG . Green synthesis of MIL-101/Au composite particles and their sensitivity to Raman detection of thiram. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2021-2030. doi: 10.11862/CJIC.20240059
17. [17]
  Fei ZHOU , Xiaolin JIA . Co₃O₄/TiO₂ composite photocatalyst: Preparation and synergistic degradation performance of toluene. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2232-2240. doi: 10.11862/CJIC.20240236
18. [18]
  Chang LIU , Chao ZHANG , Tongbu LU . Small-size Au nanoparticles anchored on pyrenyl-graphdiyne for N₂ electroreduction. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 174-182. doi: 10.11862/CJIC.20240305
19. [19]
  Linlu Bai , Wensen Li , Xiaoyu Chu , Haochun Yin , Yang Qu , Ekaterina Kozlova , Zhao-Di Yang , Liqiang Jing . Effects of nanosized Au on the interface of zinc phthalocyanine/TiO₂ for CO₂ photoreduction. Chinese Chemical Letters, 2025, 36(2): 109931-. doi: 10.1016/j.cclet.2024.109931
20. [20]
  Yaxuan Jin , Chao Zhang , Guigang Zhang . Atomically dispersed low-valent Au on poly(heptazine imide) boosts photocatalytic hydroxyl radical production. Chinese Journal of Structural Chemistry, 2024, 43(12): 100414-100414. doi: 10.1016/j.cjsc.2024.100414

Get Citation

PDF

XML

Metrics

PDF Downloads(5)
Abstract views(793)
HTML views(157)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142