Citation: SUN Meng-chao, YUAN Xin-hua, LUO Ze-jun, ZHU Xi-feng. Influence of heating temperatures on the component distribution of distillates derived from walnut shell bio-oil[J]. Journal of Fuel Chemistry and Technology, ;2020, 48(10): 1179-1185. shu

Influence of heating temperatures on the component distribution of distillates derived from walnut shell bio-oil

School of Engineering Science, University of Science and Technology of China, Hefei 230026, China

Corresponding author: ZHU Xi-feng, xfzhu@ustc.edu.cn
Received Date: 13 August 2020
Revised Date: 16 September 2020

Fund Project: the National Key Research and Development Program of China 2018YFB1501404The project was supported by the National Key Research and Development Program of China (2018YFB1501404)

Figures(6)

Influence of heating temperatures on the component distribution of distillates distilled from walnut shell bio-oils was studied. Meanwhile, distillates were further separated into water-soluble and water-insoluble fraction to characterize product distribution. The results showed that distillate fraction yield increased with strengthening heating temperature from 120 to 300 ℃. Aromatic hydrocarbons (e.g. naphthalene) and carboxylic acids (e.g. acetic acid) significantly concentrated in water-insoluble fraction as heating temperatures were below 240 ℃. Notably, the relative concentration of aromatic and carboxylic compounds in the water-insoluble fraction derived from 300 ℃ was 13.86 and 3.15 times higher than that of crude bio-oil, respectively. Large amounts of phenols such as phenol and guaiacol was distilled as heating temperatures exceeded 240 ℃, which induced enhanced yield of water-insoluble fraction. Moreover, the moisture of all the water-soluble fractions was higher than 60%, which demonstrated the water-soluble fraction remarkably concentrated moisture. In addition, undetected components (e.g. butyl 2-ethylacetate and cyclopentanone) in crude bio-oil surprisingly existed in distillates and the total moisture of distillates was higher than that of crude bio-oils, which proved esterification and polycondensation reactions occurred in bio-oil distillation process. Furthermore, the component distribution of distillates also indicated modifying heating temperatures effectively enriched commodity chemicals. Note that water-insoluble fraction distilled from 300 ℃ exhibited relative concentration of phenol, guaiacol, 4-methyl-2-methoxyphenol, 4-ethyl-2-methoxyphenol and 4-propyl-2-methoxyphenol was 109%, 160%, 84%, 53% and 444% higher than that in crude bio-oil, respectively.
- bio-oil,
- atmospheric distillation,
- separation,
- phenols enrichment
1. [1]
  KAN T, STREZOV V, EVANS T J. Lignocellulosic biomass pyrolysis:A review of product properties and effects of pyrolysis parameters[J]. Renewable Sustainable Energy Rev, 2016,57:1126-1140. doi: 10.1016/j.rser.2015.12.185
2. [2]
  CHEN D, ZHOU J, ZHANG Q, ZHU X. Evaluation methods and research progresses in bio-oil storage stability[J]. Renewable Sustainable Energy Rev, 2014,40:69-79. doi: 10.1016/j.rser.2014.07.159
3. [3]
  BULUSHEV D A, ROSS J R H. Catalysis for conversion of biomass to fuels via pyrolysis and gasification:A review[J]. Catal Today, 2011,171(1):1-13.
4. [4]
  ZHANG Wei, ZHAO Zeng-li, ZHENG An-qing, CHANG Sheng, LI Hai-bin. Characterization and storage stability analysis of bio-oil[J]. J Fuel Chem Technol, 2012,40(2):184-189.
5. [5]
  DUAN H, DONG J, GU X, PENG Y, CHEN W, TITIPONG I, WILLIAM K M, LI M, YI N, ALEXANDER F, WANG Y, ZHENG X, JI S, WANG Q, FENG J, CHEN D, LI Y, JEAN C, LIU H, SHIK C, DERMOT O. Hydrodeoxygenation of water-insoluble bio-oil to alkanes using a highly dispersed Pd-Mo catalyst[J]. Nat Commun, 2017,8(1)591.
6. [6]
  DE S, SAHA B, LUQUE R. Hydrodeoxygenation processes:Advances on catalytic transformations of biomass-derived platform chemicals into hydrocarbon fuels[J]. Bioresource Technol, 2015,178:108-118. doi: 10.1016/j.biortech.2014.09.065
7. [7]
  NARNO S, ROCHMADI R, MULYONO P, AZIZ M, BUDIMAN A. Kinetic study of catalytic cracking of bio-oil over silica-alumina catalyst[J]. Bioresources, 2018,13(1):1917-1929.
8. [8]
  GAMLIEL , DAVID P, JULIA A V, GEORGE M B. The effect of ZSM-5 catalyst support in catalytic pyrolysis of biomass and compounds abundant in pyrolysis bio-oils[J]. J Anal Appl Pyrolysis, 2016,122:7-12. doi: 10.1016/j.jaap.2016.11.002
9. [9]
  FEI Wen-ting, LIU Rong-hou, ZHOU Wei-qi, YI Ren-zhan. Bio-oil catalytic esterification and its stability with storage[J]. Acta Energi Sin, 2014,35(11):2177-2184.
10. [10]
  BAKER E G, ELLIOTT D C. Catalytic hydrotreating of biomass-derived oils[J]. Acs Symp Ser, 1987,322.
11. [11]
  REZAEI P S, SHAFAGHAT H, DAUD W M A W. Production of green aromatics and olefins by catalytic cracking of oxygenate compounds derived from biomass pyrolysis:A review[J]. Appl Catal A:Gen, 2014,469:490-511. doi: 10.1016/j.apcata.2013.09.036
12. [12]
  LV Dong-can, LIU Yun-quan, WANG Duo, YUAN Liang. Research progress in separation of bio-oils by extraction methods[J]. Chem Ind Eng Prog, 2012,31(7):1425-1431.
13. [13]
  BENNETT N M, HELLE S S, DUFF S J B. Extraction and hydrolysis of levoglucosan from pyrolysis oil[J]. Bioresource Technol, 2009,100(23):6059-6063. doi: 10.1016/j.biortech.2009.06.067
14. [14]
  SHASHKOV M V, SIDELNIKOV V N. Separation of phenol-containing pyrolysis products using comprehensive two-dimensional chromatography with columns based on pyridinium ionic liquids[J]. J Sep Sci, 2016,39(19):3754-3760. doi: 10.1002/jssc.201600431
15. [15]
  LI S, ZHU X, LI S, ZHU X. Improved bio-oil distilling effect by adding additives to enhance downstream bio-oil processing and separation[J]. Sep Purif Technol, 2020116982.
16. [16]
  WANG Yu-Rong, WANG Shu-rong, WANG Xiang-yu, GUO Zuo-gang. Molecular distillation separation characteristic of bio-oil under different pressures[J]. J Fuel Chem Technol, 2013,41(2):177-182.
17. [17]
  CHENG B, HUANG B, ZHANG R, CHEN Y, JIANG S, LU Y, ZHANG X, JIANG H, YU H. Bio-coal:A renewable and massively producible fuel from lignocellulosic biomass[J]. Sci Adv, 2020,6(1)eaay0748. doi: 10.1126/sciadv.aay0748
18. [18]
  ZHU X, WANG C, LI S, ZHU X. Upgrading biochar from bio-oil distillation residue by adding bituminous coal:Effects of induction conditions on physicochemical properties[J]. Energy Convers Manage, 2018,174:288-294. doi: 10.1016/j.enconman.2018.08.055
19. [19]
  LI Shan-shan, PAN Yang, ZHANG Li-qiang, HUANG Ling-rui, ZHU Xi-feng. Catalytic effect of zinc acetate on products distribution and reaction process of biomass pyrolysis[J]. Chin Sci Bull, 2019(31).
20. [20]
  H E, G , RUAN X, SONG Y, LIU Z, HE G. Molecular dynamics simulation of the hydration structure and hydrogen bonding behavior of phenol in aqueous solution[J]. J Mol Liq, 2016,221:942-948. doi: 10.1016/j.molliq.2016.06.048
21. [21]
  ALSBOU E, HELLEUR B. Accelerated Aging of Bio-oil from Fast Pyrolysis of Hardwood[J]. Energy Fuels, 2014,28(5):3224-3235. doi: 10.1021/ef500399n
22. [22]
  LUO Z, XIE F, CHU W, WANG Y, ZHU X. Comparative study on the evolution of physicochemical properties of tar obtained from heavy fraction of bio-oil at different heating rates[J]. J Anal Appl Pyrolysis, 2020,150104854. doi: 10.1016/j.jaap.2020.104854
23. [23]
  ZHANG X S, YANG G X, JIANG H, LIU W, DING H. Mass production of chemicals from biomass-derived oil by directly atmospheric distillation coupled with co-pyrolysis[J]. Sentific Reports, 2013,31120. doi: 10.1038/srep01120
1. [1]
  Zhongyan Cao , Shengnan Jin , Yuxia Wang , Yiyi Chen , Xianqiang Kong , Yuanqing Xu . Advances in Highly Selective Reactions Involving Phenol Derivatives as Aryl Radical Precursors. University Chemistry, 2025, 40(4): 245-252. doi: 10.12461/PKU.DXHX202405186
2. [2]
  Chongjing Liu , Yujian Xia , Pengjun Zhang , Shiqiang Wei , Dengfeng Cao , Beibei Sheng , Yongheng Chu , Shuangming Chen , Li Song , Xiaosong Liu . Understanding Solid-Gas and Solid-Liquid Interfaces through Near Ambient Pressure X-Ray Photoelectron Spectroscopy. Acta Physico-Chimica Sinica, 2025, 41(2): 100013-. doi: 10.3866/PKU.WHXB202309036
3. [3]
  Zhibei Qu , Changxin Wang , Lei Li , Jiaze Li , Jun Zhang . Organoid-on-a-Chip for Drug Screening and the Inherent Biochemistry Principles. University Chemistry, 2024, 39(7): 278-286. doi: 10.3866/PKU.DXHX202311039
4. [4]
  Qiuting Zhang , Fan Wu , Jin Liu , Zian Lin . Chromatographic Stationary Phase and Chiral Separation Using Frame Materials. University Chemistry, 2025, 40(4): 291-298. doi: 10.12461/PKU.DXHX202405174
5. [5]
  Peipei Sun , Jinyuan Zhang , Yanhua Song , Zhao Mo , Zhigang Chen , Hui Xu . 引入内建电场增强光载流子分离以促进H₂的生产. Acta Physico-Chimica Sinica, 2024, 40(11): 2311001-. doi: 10.3866/PKU.WHXB202311001
6. [6]
  Lan Ma , Cailu He , Ziqi Liu , Yaohan Yang , Qingxia Ming , Xue Luo , Tianfeng He , Liyun Zhang . Magical Surface Chemistry: Fabrication and Application of Oil-Water Separation Membranes. University Chemistry, 2024, 39(5): 218-227. doi: 10.3866/PKU.DXHX202311046
7. [7]
  Zijuan LI , Xuan LÜ , Jiaojiao CHEN , Haiyang ZHAO , Shuo SUN , Zhiwu ZHANG , Jianlong ZHANG , Yanling MA , Jie LI , Zixian FENG , Jiahui LIU . Synthesis of visual fluorescence emission CdSe nanocrystals based on ligand regulation. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 308-320. doi: 10.11862/CJIC.20240138
8. [8]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
9. [9]
  Xinhao Yan , Guoliang Hu , Ruixi Chen , Hongyu Liu , Qizhi Yao , Jiao Li , Lingling Li . Polyethylene Glycol-Ammonium Sulfate-Nitroso R Salt System for the Separation of Cobalt (II). University Chemistry, 2024, 39(6): 287-294. doi: 10.3866/PKU.DXHX202310073
10. [10]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
11. [11]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
12. [12]
  Shui Hu , Houjin Li , Zhenming Zang , Lianyun Li , Rong Lai . Integration of Science and Education Promotes the Construction of Undergraduate-to-Master’s Integration Experimental Courses: A Case Study on the Extraction, Separation and Identification of Artemisinin from Artemisia annua. University Chemistry, 2024, 39(4): 314-321. doi: 10.3866/PKU.DXHX202310063
13. [13]
  Junjie Zhang , Yue Wang , Qiuhan Wu , Ruquan Shen , Han Liu , Xinhua Duan . Preparation and Selective Separation of Lightweight Magnetic Molecularly Imprinted Polymers for Trace Tetracycline Detection in Milk. University Chemistry, 2024, 39(5): 251-257. doi: 10.3866/PKU.DXHX202311084
14. [14]
  Yang Chen , Peng Chen , Yuyang Song , Yuxue Jin , Song Wu . Application of Chemical Transformation Driven Impurity Separation in Experiments Teaching: A Novel Method for Purification of α-Fluorinated Mandelic Acid. University Chemistry, 2024, 39(6): 253-263. doi: 10.3866/PKU.DXHX202310077
15. [15]
  Qiang Wu , Wenhua Hou . Teaching Classical Contents Newly: Taking Temperature–Entropy Diagram as an Example. University Chemistry, 2025, 40(4): 399-407. doi: 10.12461/PKU.DXHX202407102
16. [16]
  Changjun You , Chunchun Wang , Mingjie Cai , Yanping Liu , Baikang Zhu , Shijie Li . 引入内建电场强化BiOBr/C₃N₅ S型异质结中光载流子分离以实现高效催化降解微污染物. Acta Physico-Chimica Sinica, 2024, 40(11): 2407014-. doi: 10.3866/PKU.WHXB202407014
17. [17]
  Jie ZHAO , Huili ZHANG , Xiaoqing LU , Zhaojie WANG . Theoretical calculations of CO₂ capture and separation by functional groups modified 2D covalent organic framework. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 275-283. doi: 10.11862/CJIC.20240213
18. [18]
  Houjin Li , Shuanglian Cai , Yuan Zheng , Zhanxiang Liu , Chengshan Yuan , Lin Wu , Guangao Yu , Jie Han , Qingwen Liu , Xin Du , Ying Xiong , Qihan Zhang , Xingwen Sun , Jianrong Zhang , Shuyong Zhang . Basic Operations and Standardization Suggestions for Organic Chemistry Distillation Experiments. University Chemistry, 2025, 40(5): 40-54. doi: 10.12461/PKU.DXHX202411053
19. [19]
  . . Chinese Journal of Inorganic Chemistry, 2024, 40(12): 0-0.
20. [20]
  Tiantian Dai , Xi Yang . Teaching Design and Reflection on the “Osmotic Pressure of Solutions” in Medical Chemistry. University Chemistry, 2025, 40(5): 268-275. doi: 10.12461/PKU.DXHX202411032

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(1249)
HTML views(297)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142