Citation: Miao Xiangyang, Yu Huizhen, Wang Yang, Gu Zhun, Wang Zhaoyin, Dai Zhihui. Detection of Dopamine based on Catalytic Activity of Cu-MOF towards H₂O₂[J]. Chemistry, ;2017, 80(1): 47-52. shu

Detection of Dopamine based on Catalytic Activity of Cu-MOF towards H₂O₂

Miao Xiangyang ¹ ,
Yu Huizhen ¹ ,
Wang Yang ¹ ,
Gu Zhun ¹ ,
Wang Zhaoyin ² ,
Dai Zhihui ^2,*,,

1.
Department of Biological and Chemical Engineering, Suzhou Chien-shiung Institute of Technology, Taicang 215411
2.
Jiangsu Key Laboratory of Biofunctional Materials, College of Chemistry and Materials Science, Nanjing Normal University, Nanjing 210023

Corresponding author: Dai Zhihui, daizhihuii@njnu.edu.cn
Received Date: 4 July 2016
Accepted Date: 30 September 2016

Figures(8)

In this work, a colorimetric biosensing platform for H₂O₂ and dopamine (DA) was constructed based on the catalytic activity of one type of Cu-MOF[Cu₃(BTC)₂(H₂O)₃, HKUST-1]. The color of o-phenylenediamine (OPD) can be changed significantly because of the oxidation of H₂O₂ catalyzed by HKUST-1. As a result, H₂O₂ and DA were detected rapidly and sensitively by our system. Under the optimum conditions, two linear relationships between the intensity of absorption peak at 415nm and the concentration of H₂O₂ (from 10 to 50 mmol/L and from 50 to 100 mmol/L, R=0.9947 and 0.9995) were obtained with the detection limit of 1.29 mmol/L. Besides, DA can resist the oxidation of OPD from H₂O₂, this platform was further used for rapid detection of DA with two linear ranges (from 0.25 to 5μmol/L and from 2.5 to 25μmol/L, R=0.9783 and 0.9705), and the detection limit was 0.262 μmol/L. Therefore, this work may broaden the applications of Cu-MOFs in biological molecular catalysis and biosensing fields.
- Cu-BTC,
- Colorimetric analysis,
- H₂O₂,
- Dopamine,
- Heterogeneous catalyst
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Detection of Dopamine based on Catalytic Activity of Cu-MOF towards H₂O₂