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Citation: Liu Chengmei, Guo Junshi, Xie Hongquan. Preparation and Characterization of Soluble Precursor Polymer of Poly(2,5-Dimethoxy Phenylene Vinylene)[J]. Chinese Journal of Applied Chemistry, ;1995, 12(5): 5-9. shu

Preparation and Characterization of Soluble Precursor Polymer of Poly(2,5-Dimethoxy Phenylene Vinylene)

Department of Chemistry, Huazhong University of Science and Technology, Wuhan 430074

Received Date: 27 November 1994
Revised Date: 3 April 1995

The reaction conditions for preparing the organic soluble precursor polymer of poly(2,5-dimethoxy phenylene vinylene) have been examined. The results indicated that NaOH was an effective initiator for this polymerization. The optimum reaction conditions were as follows: molar ratio of monomer to NaOH 1:1;concentration of monomer 0.05 to 0.2mol/L;polymerization time 2 hours and temperature below 5℃. Hexane and petroleum ether can effectively increase the monome,conversion and precursor polymer yield. The structure of the polymer precursor were characterized by IR, UV-Vis,¹H NMR,TGA and DSC.
- conductive pnfymer,
- poly(dimethoxy phenylene vinylene),
- precursor polymer,
- synthesis
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  南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积
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Preparation and Characterization of Soluble Precursor Polymer of Poly(2,5-Dimethoxy Phenylene Vinylene)

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com