Citation:
Wang Jiaguo, Jing Xiping. Solubilities of Metal Halides in Water[J]. Chemistry,
;2018, 81(3): 278-287.
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The first-year undergraduates are always racked by the solubility rule of metal halides in water. In this paper, firstly, the chemical bonds were deduced from atomic structures and molecular structures. Then, the dissolve modes in water were derived from the chemical bonds. Thirdly, the correlation between the energy changes and the solubilities was analyzed based on thermodynamic data, and finally, the solubility rule of halides in water was revealed.
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Keywords:
- Metal halide,
- Solubility in water,
- Chemical bond,
- Structure
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- [1]
- [2]
-
[3]
Findit Database, 2009.
-
[4]
CRC Handbook of Chemistry and Physics, 84th Ed. 2003~2004.
- [5]
- [6]
-
[7]
M D Collings, D M Sherman, K V Ragnarsdottir. Chem. Geol., 2000, 167(1/2):65~73.
-
[8]
L Eisen, N Marano, S Glazier. J. Chem. Edu., 2014, 91:484~491.
-
[9]
Langes Chemistry Handbook, 15th Ed. 2003.
-
-
-
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