Citation: Dao Li DENG, Xiao Fan ZHANG, Chang Tao QIAN, Jie SUN, Pei Ju ZHENG, Jian CHEN. A New Approach for Stabilizing Organouranium Dichloride： Synthesis and X-ray Structure of (MeOCH₂CH₂C₅H₄)₂UCl₂[J]. Chinese Chemical Letters, ;1996, 7(12): 1143-1144. shu

A New Approach for Stabilizing Organouranium Dichloride： Synthesis and X-ray Structure of (MeOCH₂CH₂C₅H₄)₂UCl₂

a Laboratory of Organometallic Chemistry Shanghai Institute of OrganicChemistry Chinese Academy of Sciences 354 Fenglin Lu Shanghai 200032;
b Center of Analysis and Measument Fudan University Shanghai 200433

Received Date: 12 March 1996

Cp'₂UCI₂(Cp'=MeOCH₂CH₂C₅H₄) complex 1 has been synthesized by the reaction of UCI₄ with Cp'Na in tetrahydrofuran.A single-crystal X-ray study shows that the uranium compound is a mononuclear complex with uranium in a pseudo-hexahedral co-ordination geometry if the cyclopentadienyl ring is regarded as occupying a single polyhedral vertex.
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