Home

Citation: Huang Xing, Zhang Diqin, Zhang Lipeng, Zhao Yuxia. Study on the Structure and Properties of Arylene Cyclopentanone Visible Light Initiators[J]. Chemistry, ;2020, 83(8): 724-729. shu

Study on the Structure and Properties of Arylene Cyclopentanone Visible Light Initiators

Huang Xing ^1,2 ,
Zhang Diqin ^1,2 ,
Zhang Lipeng ¹ ,
Zhao Yuxia ^1,2,,

1.
Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, 100190
2.
University of Chinese Academy of Sciences, Beijing, 100049

Corresponding author: Zhao Yuxia, yuxia.zhao@mail.ipc.ac.cn
Received Date: 11 March 2020
Accepted Date: 2 April 2020

Figures(7)

Three arylene cyclopentanone visible light initiators containing benzene ring (BDMA), thiophene ring (BDTA) and furan ring (BDFA) were synthesized respectively. Their photophysical and photochemical properties were studied by UV-Vis absorption spectra, fluorescence emission spectra, laser flash photolysis and electron paramagnetic resonance. In contrast with BDMA, the absorption spectra of BDTA and BDFA exhibited a redshift due to the introduction of heterocycles, which can match the emitting spectrum of commercial 532 nm diode lasers. The photopolymerization kinetics showed that all of as-synthesized inititators could induce polymerization of acrylate monomer PEGDA400 directly under visible light irradiation. Among them, BDTA has the best initiation efficiency, suggesting it has potential application prospect in visible light polymerization.
- Visible Light Initiator,
- Arylene Cyclopentanone,
- Heterocycle,
- Photopolymerization
1. [1]
  Yagci Y, Jockusch S, Turro N J. Macromolecules, 2010, 43(15):6245-6260.
2. [2]
  Tehfe M A, Louradour F, Lalevée J, et al. Appl. Sci., 2013, 3(2):490-514.
3. [3]
  Decker C, Zahouily K. J. Polym. Sci. A, 1998, 36(14):2571-2580.
4. [4]
  Holman R, Oldring P. SITA-Technology, London, 1998, 12, 24. ISBN 0-947798-02-1.
5. [5]
  Bender M, Otto M, Hadam B, et al. Microelectron. Eng., 2000, 53(1):233-236.
6. [6]
  Nguyen K T, West J L. Biomaterials, 2002, 23(22):4307-4316.
7. [7]
  Anseth K S, Newman S M, Bowman C N. Adv. Polym. Sci., 2006, 122:177-217.
8. [8]
  Monroe B M, Weed G C. Chem. Rev., 1993, 93(1):435-448.
9. [9]
  Decker C. Prog. Polym. Sci., 1996, 21(4):593-650.
10. [10]
  Lalevée J, Savary F M, Dietlin C, et al. Molecules, 2014, 19(9):15026-15041.
11. [11]
  Zhou D, Ito Y. Sci. Chin. Chem., 2014, 57(4):510-521.
12. [12]
  Xiao P, Zhang J, Dumur F, et al. Prog. Polym. Sci., 2014, 41:32-66.
13. [13]
  Dietlin C, Schhweizer S, Xiao P, et al. Polym. Chem., 2015, 6(21):3895-3912.
14. [14]
  Lalevée J, Fouassier J P. Photochemistry, 2015, 42:215-232.
15. [15]
  Xue J, Zhao Y, Wu J, et al. J. Photochem. Photobiol. A, 2008, 195(2):261-266.
16. [16]
  Zou Q, Zhao Y, Makarov N S, et al. Phys. Chem. Chem. Phys., 2012, 14(33):11743-11752.
17. [17]
  Huang X, Zhang Y, Shi M, et al. Polym. Chem., 2019, 10(18):2273-2281.
1. [1]
  Siran Wang , Yinuo Wang , Yilong Zhao , Dazhen Xu . Advances in the Application and Preparation of Rhodanine and Its Derivatives. University Chemistry, 2025, 40(5): 318-327. doi: 10.12461/PKU.DXHX202407033
2. [2]
  Dan Liu . 可见光-有机小分子协同催化的不对称自由基反应研究进展. University Chemistry, 2025, 40(6): 118-128. doi: 10.12461/PKU.DXHX202408101
3. [3]
  Xinzhe HUANG , Lihui XU , Yue YANG , Liming WANG , Zhangyong LIU , Zhongjian WANG . Preparation and visible light responsive photocatalytic properties of BiSbO₄/BiOBr. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 284-292. doi: 10.11862/CJIC.20240212
4. [4]
  Jiajia Li , Xiangyu Zhang , Zhihan Yuan , Zhengyang Qian , Jian Zhu . 3D Printing Based on Photo-Induced Reversible Addition-Fragmentation Chain Transfer Polymerization. University Chemistry, 2024, 39(5): 11-19. doi: 10.3866/PKU.DXHX202309073
5. [5]
  Chi Li , Jichao Wan , Qiyu Long , Hui Lv , Ying Xiong . N-Heterocyclic Carbene (NHC)-Catalyzed Amidation of Aldehydes with Nitroso Compounds. University Chemistry, 2024, 39(5): 388-395. doi: 10.3866/PKU.DXHX202312016
6. [6]
  Zhen Yao , Bing Lin , Youping Tian , Tao Li , Wenhui Zhang , Xiongwei Liu , Wude Yang . Visible-Light-Mediated One-Pot Synthesis of Secondary Amines and Mechanistic Exploration. University Chemistry, 2024, 39(5): 201-208. doi: 10.3866/PKU.DXHX202311033
7. [7]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
8. [8]
  Tongyan Yu , Pan Xu . Visible-Light Photocatalyzed Radical Rearrangement Reaction. University Chemistry, 2025, 40(7): 169-176. doi: 10.12461/PKU.DXHX202409070
9. [9]
  Zhuoyan Lv , Yangming Ding , Leilei Kang , Lin Li , Xiao Yan Liu , Aiqin Wang , Tao Zhang . Light-Enhanced Direct Epoxidation of Propylene by Molecular Oxygen over CuO_x/TiO₂ Catalyst. Acta Physico-Chimica Sinica, 2025, 41(4): 2408015-0. doi: 10.3866/PKU.WHXB202408015
10. [10]
  Hong RAO , Yang HU , Yicong MA , Chunxin LÜ , Wei ZHONG , Lihua DU . Synthesis and in vitro anticancer activity of phenanthroline-functionalized nitrogen heterocyclic carbene homo- and heterobimetallic silver/gold complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2429-2437. doi: 10.11862/CJIC.20240275
11. [11]
  Jianjun LI , Mingjie REN , Lili ZHANG , Lingling ZENG , Huiling WANG , Xiangwu MENG . UV-assisted degradation of tetracycline hydrochloride by MnFe₂O₄@activated carbon activated persulfate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1869-1880. doi: 10.11862/CJIC.20240187
12. [12]
  Jie Li , Huida Qian , Deyang Pan , Wenjing Wang , Daliang Zhu , Zhongxue Fang . Efficient Synthesis of Anethaldehyde Induced by Visible Light. University Chemistry, 2024, 39(4): 343-350. doi: 10.3866/PKU.DXHX202310076
13. [13]
  Junjie Zhang , Yue Wang , Qiuhan Wu , Ruquan Shen , Han Liu , Xinhua Duan . Preparation and Selective Separation of Lightweight Magnetic Molecularly Imprinted Polymers for Trace Tetracycline Detection in Milk. University Chemistry, 2024, 39(5): 251-257. doi: 10.3866/PKU.DXHX202311084
14. [14]
  Rui Gao , Ying Zhou , Yifan Hu , Siyuan Chen , Shouhong Xu , Qianfu Luo , Wenqing Zhang . Design, Synthesis and Performance Experiment of Novel Photoswitchable Hybrid Tetraarylethenes. University Chemistry, 2024, 39(5): 125-133. doi: 10.3866/PKU.DXHX202310050
15. [15]
  Wanmin Cheng , Juan Du , Peiwen Liu , Yiyun Jiang , Hong Jiang . Photoinitiated Grignard Reagent Synthesis and Experimental Improvement in Triphenylmethanol Preparation. University Chemistry, 2024, 39(5): 238-242. doi: 10.3866/PKU.DXHX202311066
16. [16]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
17. [17]
  Yurong Tang , Yunren Shi , Yi Xu , Bo Qin , Yanqin Xu , Yunfei Cai . Innovative Experiment and Course Transformation Practice of Visible-Light-Mediated Photocatalytic Synthesis of Isoquinolinone. University Chemistry, 2024, 39(5): 296-306. doi: 10.3866/PKU.DXHX202311087
18. [18]
  Zhiwen HUANG , Qi LIU , Jianping LANG . W/Cu/S cluster-based supramolecular macrocycles and their third-order nonlinear optical responses. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 79-87. doi: 10.11862/CJIC.20240184
19. [19]
  Chengqian Mao , Yanghan Chen , Haotong Bai , Junru Huang , Junpeng Zhuang . Photodimerization of Styrylpyridinium Salt and Its Application in Silk Screen Printing. University Chemistry, 2024, 39(5): 354-362. doi: 10.3866/PKU.DXHX202312014
20. [20]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349

Get Citation

PDF

XML

Metrics

PDF Downloads(6)
Abstract views(1133)
HTML views(345)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return