Citation: LI Ting-ting, HUANG Yan-qin, LIU Hua-cai, YUAN Hong-you, YIN Xiu-li, WU Chuang-zhi. Effects of paper mill residual additives on sintering and melting characteristic of wheat straw[J]. Journal of Fuel Chemistry and Technology, ;2017, 45(11): 1323-1331. shu

Effects of paper mill residual additives on sintering and melting characteristic of wheat straw

1.
Key Laboratory of Renewable Energy, CAS, Guangdong Key Laboratory of New and Renewable Energy Research and Development, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: HUANG Yan-qin, huangyq@ms.giec.ac.cn
Received Date: 16 May 2017
Revised Date: 16 August 2017

Fund Project: the Science and Technology Support Program of Guangdong Province, China 2016A010104011the National Key Research and Devetopment Program of China 2016YFE0203300the National Natural Science Foundation of China 51661145022The project was supported by the National Natural Science Foundation of China (51661145022), the National Key Research and Devetopment Program of China(2016YFE0203300) and the Science and Technology Support Program of Guangdong Province, China(2016A010104011)

Figures(4)

The effects of paper mill residues (delinking sludge, paper mill sludge, municipal sewage sludge) addition on slagging tendency of wheat straw were investigated using ash melting point test system, X-ray fluorescence (XRF) and powder X-ray diffraction (XRD). The differences between other 4 common additives were also discussed. The results show that addition of delinking sludge and paper mill sludge behaves better than municipal sewage sludge in blending range of 3% to 10%, while softening temperature of wheat ash tends to get the highest value when adding 5% paper mill sludge. Along with the blends increasing, Al₂O₃ plays an important framework structure modification role while adding paper mill sludge. While generation of feldspar such as orthoclase and anorthite takes place, the softening temperature decreases. In addition, silicon aluminum garnet is more likely to form to enhance the fusion characteristic temperate while adding delinking sludge. On the contrary, formation of high melting point material(CaSiO₃)inhibits low melting silicate by adding paper mill sludge. Components analyses indicate that crystal structure of SiO₂ is changed along with municipal sludge added. Sludge used as anti-slagging additives is promising.
- wheat ash,
- additives,
- delinking sludge,
- papermaking wastewater sludge,
- municipal wastewater sludge,
- sintering and melting characteristics
1. [1]
  WANG L, SKREIBERG O, BECIDAN M, LI H L. Investigation of rye straw ash sintering characteristics and the effect of additives[J]. Appl Energy, 2016,162:1195-1204. doi: 10.1016/j.apenergy.2015.05.027
2. [2]
  WANG L, BECIDAN M, SKREIBERG O. Sintering behavior of agricultural residues ashes and effects of additives[J]. Energy Fuels, 2012,26(9):5917-5929. doi: 10.1021/ef3004366
3. [3]
  STEENARI B M, LINDQVIST O. High-temperature reactions of straw ash and the anti-sintering additives kaolin and dolomite[J]. Biomass Bioenergy, 1998,14(1):67-76. doi: 10.1016/S0961-9534(97)00035-4
4. [4]
  OHMAN M, NORDIN A, LUNDHOLM K, BOSTROM D, HEDMAN H, LUNDBERG M. Ash transformations during combustion of meat-, bonemeal, and RDF in a (bench-scale) fluidized bed combustor[J]. Energy Fuels, 2003,17(5):1153-1159. doi: 10.1021/ef020273a
5. [5]
  QI J H, LI H, HAN K H, ZUO Q, GAO J, WANG Q, LU C M. Influence of ammonium dihydrogen phosphate on potassium retention and ash melting characteristics during combustion of biomass[J]. Energy, 2016,102:244-251. doi: 10.1016/j.energy.2016.02.090
6. [6]
  GRIMM A, SKOGLUND N, BOSTROM D, BOMAN C, OHMAN M. Influence of phosphorus on alkali distribution during combustion of logging residues and wheat straw in a bench-scale fluidized bed[J]. Energy Fuels, 2012,26(5):3012-3023. doi: 10.1021/ef300275e
7. [7]
  LI H, HAN K H, WANG Q, LU C M. Influence of ammonium phosphates on gaseous potassium release and ash-forming characteristics during combustion of biomass[J]. Energy Fuels, 2015,29(4):2555-63. doi: 10.1021/acs.energyfuels.5b00285
8. [8]
  XIA Han-yuan, YUAN Hong-you, WANG Gui-jin, ZHOU Zhao-qiu, SU De-ren, YANG Qing, YIN Xiu-li. Experimental study on pyrolysis and gasification characteristics of deinking sludge[J]. Paper Sci Technol, 2012,3:88-92.
9. [9]
  FERREIRA C I A, CALISTO V, CUERDA-CORREA E M, OTERO M, NADAIS H, ESTEVES V I. Comparative valorisation of agricultural and industrial biowastes by combustion and pyrolysis[J]. Bioresour Technol, 2016,218:918-925. doi: 10.1016/j.biortech.2016.07.047
10. [10]
  SKOGLUND N, GRIMM A, OHMAN M, BOSTROM D. Effects on ash chemistry when co-firing municipal sewage sludge and wheat straw in a fluidized bed:Influence on the ash chemistry by fuel mixing[J]. Energy Fuels, 2013,27(10):5725-5732. doi: 10.1021/ef401197q
11. [11]
  WANG L, SKJEVRAK G, HUSTAD J E, GRONLI M G. Effects of sewage sludge and marble sludge addition on slag characteristics during wood waste pellets combustion[J]. Energy Fuels, 2011,25(12):5775-5785. doi: 10.1021/ef2007722
12. [12]
  DAVIDSSON K O, AMAND L E, ELLED A L, LECKNER B. Effect of cofiring coal and biofuel with sewage sludge on alkali problems in a circulating fluidized bed boiler[J]. Energy Fuels, 2007,21(6):3180-3188. doi: 10.1021/ef700384c
13. [13]
  HUPA M. Ash-related issues in fluidized-bed combustion of biomasses:recent research highlights[J]. Energy Fuels, 2012,26(1):4-14. doi: 10.1021/ef201169k
14. [14]
  BROSTROM M, KASSMAN H, HELGESSON A, BERG M, ANDERSSON C, BACKMAN R, NORDIN A. Sulfation of corrosive alkali chlorides by ammonium sulfate in a biomass fired CFB boiler[J]. Fuel Process Technol, 2007,88(11/12):1171-1177.
15. [15]
  LI L N, REN Q Q, LI S Y, LU Q G. Effect of phosphorus on the behavior of potassium during the co-combustion of wheat straw with municipal sewage sludge[J]. Energ Fuels, 2013,27(10):5923-5930. doi: 10.1021/ef401196y
16. [16]
  ARING , MAND L E, LECKNER B, ESKILSSON D, TULLIN C. Deposits on heat transfer tubes during co-combustion of biofuels and sewage sludge[J]. Fuel, 2006,85(10/11):1313-1322.
17. [17]
  NIU Y Q, TAN H. Z, HUI S E. Ash-related issues during biomass combustion:Alkali-induced slagging, silicate melt-induced slagging (ash fusion), agglomeration, corrosion, ash utilization, and related countermeasures[J]. Prog Energy Combust Sci, 2016,52:1-61. doi: 10.1016/j.pecs.2015.09.003
18. [18]
  GILBE C, LINDSTROM E, BACKMAN R, SAMUELSSON R, BURVALL J, OHMAN M. Predicting slagging tendencies for biomass pellets fired in residential appliances:A comparison of different prediction methods[J]. Energy Fuels, 2008,22(6):3680-3686. doi: 10.1021/ef800321h
19. [19]
  WANG S, JIANG X M, HAN X X, WANG H. Fusion characteristic study on seaweed biomass ash[J]. Energy Fuels, 2008,22(4):2229-2235. doi: 10.1021/ef800128k
20. [20]
  NIU Yan-qing, TAN Hou-zhang, WANG Xue-bin, XU Tong-mo, LIU Zheng-ning, LIU Yang. Fusion characteristic of capsicum stalks ash[J]. Proc CSEE, 2011,11:68-72.
21. [21]
  PRIYANTO D E, UENO S, SATO N, KASAI H, TANOUE T, FUKUSHIMA H. Ash transformation by co-firing of coal with high ratios of woody biomass and effect on slagging propensity[J]. Fuel, 2016,174:172-179. doi: 10.1016/j.fuel.2016.01.072
22. [22]
  MA T, FAN C G, HAO L F, LI S G, SONG W L, LI W G. Biomass-ash-induced agglomeration in a fluidized bed. Part 1:Experimental study on the effects of a gas atmosphere[J]. Energy Fuels, 2016,30(8):6395-6404. doi: 10.1021/acs.energyfuels.6b00164
23. [23]
  LI Ting-ting, HUANG Yan-qin, YUAN Hong-you, LIU Hua-cai, YIN Xiu-li, WU Chuang-zhi. Characterization of sintering behavior of wheat straw ash based on capacitance test[J]. Acta Energi Sina, 2018, 34.
24. [24]
  LI Wen, BAI Jin. Chemistry of Ash from Coal[M]. Beijing:Science Press, 2013, 84.
25. [25]
  WANG L, SKJEVRAK G, HUSTAD J E, GRONLI M G. Sintering characteristics of sewage sludge ashes at elevated temperatures[J]. Fuel Process Technol, 2012,96:88-97. doi: 10.1016/j.fuproc.2011.12.022
26. [26]
  BLÄSING M, ZINI M, MVLLER M. Influence of feedstock on the release of potassium, sodium, chlorine, sulfur, and phosphorus species during gasification of wood and biomass shells[J]. Energy Fuels, 2013,27(3):1439-1445. doi: 10.1021/ef302093r
27. [27]
  WU H, CASTRO M, JENSEN P A, FRANDSEN F J, GLARBORG PETER DAM-JOHANSEN K, RØKKE M, LUNDTORP K. Release and transformation of inorganic elements in combustion of a high-phosphorus fuel[J]. Energy Fuels, 2011,25(7):2874-2886. doi: 10.1021/ef200454y
28. [28]
  YUAN Yan-wen, ZHAO Li-xin, MENG Hai-bo, LIN Chong, TIAN Yi-shui. Effects comparison on anti-slagging additives of corn straw biomass pellet fuel[J]. Trans CSAE, 2010,11:251-255. doi: 10.3969/j.issn.1002-6819.2010.09.041
29. [29]
  LI L N, REN Q Q, LI S Y, LU Q G. Effect of phosphorus on the behavior of potassium during the Co-combustion of wheat straw with municipal sewage sludge[J]. Energy Fuels, 2013,27(10):5923-5930. doi: 10.1021/ef401196y
30. [30]
  LI H, HAN K H, WANG Q, LU C M. Pyrolysis of rice straw with ammonium dihydrogen phosphate:Properties and gaseous potassium release characteristics during combustion of the products[J]. Bioresour Technol, 2015,197:193-200. doi: 10.1016/j.biortech.2015.08.070
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沈阳化工大学材料科学与工程学院沈阳 110142