Citation: JING Jie-ying, ZHANG Zi-yi, WANG Shi-dong, LI Wen-ying. Influence of calcination temperature on the structure and catalytic reforming performance of Ni/CaO-Al₂O₃ catalyst[J]. Journal of Fuel Chemistry and Technology, ;2018, 46(6): 673-679. shu

Influence of calcination temperature on the structure and catalytic reforming performance of Ni/CaO-Al₂O₃ catalyst

Training Base of State Key Laboratory of Coal Science and Technology, Taiyuan University of Technology, Taiyuan 030024, China

Corresponding author: JING Jie-ying, jingjieying@tyut.edu.cn LI Wen-ying, ying@tyut.edu.cn
Received Date: 30 March 2018
Revised Date: 3 May 2018

Fund Project: The project was supported by National Natural Science Foundation of China (21406155), Natural Science Foundation of Shanxi Province (201701D221237) and Program for the Top Young Academic Leaders of Higher Learning Institutions of Shanxi (164010121-S)Program for the Top Young Academic Leaders of Higher Learning Institutions of Shanxi 164010121-SNatural Science Foundation of Shanxi Province 201701D221237National Natural Science Foundation of China 21406155

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Considering the tunable structure of hydrotalcite-like compounds, co-precipitation method was employed to synthesize Ni/CaO-Al₂O₃ composite catalysts. The influence of calcination temperature on the structure and catalytic reforming performance of Ni/CaO-Al₂O₃ catalyst investigated. The results showed that the specific surface area and Ni particle size of the as-synthesized composite catalysts were greatly affected by calcination temperature of the precursor derived from the variable interaction between the Ni and the support. When the calcination temperature was 700 ℃, the composite catalyst obtained a specific surface area of 21.42 m²/g and Ni particle size of 19.51 nm. The catalytic evaluation showed that the composite catalyst possessed a H₂ concentration of 98.31% and a CH₄ conversion of 94.87%, and H₂ concentration exceeded 97.35% even after 10 cyclic runs. The high catalytic activity was ascribed to the higher specific surface area, which provided more active sites and enhanced CO₂ sorption. The smaller Ni particle size improved the anti-sintering capacity of the composite catalyst, endowing the composite catalyst superior stability.
- hydrogen production,
- enhanced CO₂ sorption,
- composite catalyst,
- calcination temperature,
- hydrotalcite-like compounds
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Influence of calcination temperature on the structure and catalytic reforming performance of Ni/CaO-Al2O3 catalyst

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Influence of calcination temperature on the structure and catalytic reforming performance of Ni/CaO-Al₂O₃ catalyst