Citation: JING Jie-ying, ZHANG Zi-yi, WANG Shi-dong, LI Wen-ying. Influence of calcination temperature on the structure and catalytic reforming performance of Ni/CaO-Al₂O₃ catalyst[J]. Journal of Fuel Chemistry and Technology, ;2018, 46(6): 673-679. shu

Influence of calcination temperature on the structure and catalytic reforming performance of Ni/CaO-Al₂O₃ catalyst

Training Base of State Key Laboratory of Coal Science and Technology, Taiyuan University of Technology, Taiyuan 030024, China

Corresponding author: JING Jie-ying, jingjieying@tyut.edu.cn LI Wen-ying, ying@tyut.edu.cn
Received Date: 30 March 2018
Revised Date: 3 May 2018

Fund Project: The project was supported by National Natural Science Foundation of China (21406155), Natural Science Foundation of Shanxi Province (201701D221237) and Program for the Top Young Academic Leaders of Higher Learning Institutions of Shanxi (164010121-S)Program for the Top Young Academic Leaders of Higher Learning Institutions of Shanxi 164010121-SNatural Science Foundation of Shanxi Province 201701D221237National Natural Science Foundation of China 21406155

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Considering the tunable structure of hydrotalcite-like compounds, co-precipitation method was employed to synthesize Ni/CaO-Al₂O₃ composite catalysts. The influence of calcination temperature on the structure and catalytic reforming performance of Ni/CaO-Al₂O₃ catalyst investigated. The results showed that the specific surface area and Ni particle size of the as-synthesized composite catalysts were greatly affected by calcination temperature of the precursor derived from the variable interaction between the Ni and the support. When the calcination temperature was 700 ℃, the composite catalyst obtained a specific surface area of 21.42 m²/g and Ni particle size of 19.51 nm. The catalytic evaluation showed that the composite catalyst possessed a H₂ concentration of 98.31% and a CH₄ conversion of 94.87%, and H₂ concentration exceeded 97.35% even after 10 cyclic runs. The high catalytic activity was ascribed to the higher specific surface area, which provided more active sites and enhanced CO₂ sorption. The smaller Ni particle size improved the anti-sintering capacity of the composite catalyst, endowing the composite catalyst superior stability.
- hydrogen production,
- enhanced CO₂ sorption,
- composite catalyst,
- calcination temperature,
- hydrotalcite-like compounds
1. [1]
  BALASUBRAMANIAN B, ORTIZ A L, KAYTAKOGLU S, HARRISON D P. Hydrogen from methane in a single-step process[J]. Chem Eng Sci, 1999,54(15):3543-3552.
2. [2]
  SILVA J M, SORIA M A, MADEIRA L M. Thermodynamic analysis of glycerol steam reforming for hydrogen production with in situ hydrogen and carbon dioxide separation[J]. J Power Sources, 2015,273:423-430. doi: 10.1016/j.jpowsour.2014.09.093
3. [3]
  ROMANO M C, CASSOTTI E N, CHIESA P, MEYER J, MASTIN J. Application of the sorption enhanced-steam reforming process in combined cycle-based power plants[J]. Energy Procedia, 2011,4(4):1125-1132.
4. [4]
  LYSIKOV A, DEREVSCHIKOV V, OKUNEV A. Sorption-enhanced reforming of bioethanol in dual fixed bed reactor for continuous hydrogen production[J]. Int J Hydrogen Energy, 2015,40(42):14436-14444. doi: 10.1016/j.ijhydene.2015.06.029
5. [5]
  XUE X, WU S. The microstructure and stability of a Ni-nano-CaO/Al₂O₃ reforming catalyst under carbonation-calcination cycling conditions[J]. Int J Hydrogen Energy, 2015,40(16):5617-5623. doi: 10.1016/j.ijhydene.2015.02.032
6. [6]
  LI M. Thermodynamic analysis of adsorption enhanced reforming of ethanol[J]. Int J Hydrogen Energy, 2009,34(23):9362-9372. doi: 10.1016/j.ijhydene.2009.09.054
7. [7]
  JING J Y, LI T Y, ZHANG X W, WANG S D, FENG J, TURMEL W A, LI W Y. Enhanced CO₂ sorption performance of CaO/Ca₃Al₂O₆ sorbents and its sintering-resistance mechanism[J]. Appl Energy, 2017,199:225-233. doi: 10.1016/j.apenergy.2017.03.131
8. [8]
  JING J Y, ZHANG X W, WANG S D, LI T Y, LI W Y. Improving CO₂ sorption performance of CaO/Ca₃Al₂O₆ sorbents by thermally pretreated in CO₂ atmosphere[J]. Energy Procedia, 2017,142:3258-3263. doi: 10.1016/j.egypro.2017.12.500
9. [9]
  GARCIA-LARIO A L, AZNAR M, GRASA G S, MURILLO R. Evaluation of process variables on the performance of sorption enhanced methane reforming[J]. J Power Sources, 2015,285:90-99. doi: 10.1016/j.jpowsour.2015.03.075
10. [10]
  CHEN Y, MAHECHABOTERO A, LIM C J, GRACE J R, ZHANG J, ZHAO Y, ZHENG C. Hydrogen production in a sorption-enhanced fluidized-bed membrane reactor:Operating parameter investigation[J]. Ind Eng Chem Res, 2014,53(14):6230-6242. doi: 10.1021/ie500294k
11. [11]
  RADFARNIA H R, ILIUTA M C. Hydrogen production by sorption-enhanced steam methane reforming process using CaO-Zr/Ni bifunctional sorbent-catalyst[J]. Chem Eng Process, 2014,86:96-103. doi: 10.1016/j.cep.2014.10.014
12. [12]
  CHANBURANASIRI N, RIBEIRO A M, RODRIGUES A E, ARPORNWICHANOP A, LAOSIRIPOJANA N, PRASERTHDAM P, ASSABUMRUNGRAT S. Hydrogen production via sorption enhanced steam methane reforming process using Ni/CaO multifunctional catalyst[J]. Ind Eng Chem Res, 2011,50(24):69-86.
13. [13]
  RADFRNIA H R, ILIUTA M C. Development of Al-stabilized CaO-nickel hybrid sorbent-catalyst for sorption-enhanced steam methane reforming[J]. Chem Eng Sci, 2014,109(16):212-219.
14. [14]
  CESARIO M R, BARROS B S, COURSON C, MELO D M A, KIENNEMANN A. Catalytic performances of Ni-CaO-mayenite in CO₂ sorption enhanced steam methane reforming[J]. Fuel Process Technol, 2015,131:247-253. doi: 10.1016/j.fuproc.2014.11.028
15. [15]
  XU P, ZHOU Z, ZHAO C, CHENG Z. Ni/CaO-Al₂O₃ bifunctional catalysts for sorption-enhanced steam methane reforming[J]. AIChE J, 2015,60(10):3547-3556.
16. [16]
  PHROMPRASIT J, POWELL J, WONGSAKULPHASATCH S, KIATKITTIPONG W, BUMROONGSAKULSAWAT P, ASSABUMRUNGRAT S. Activity and stability performance of multifunctional catalyst (Ni/CaO and Ni/Ca₁₂Al₁₄O₃₃-CaO) for bio-hydrogen production from sorption enhanced biogas steam reforming[J]. Int J Hydrogen Energy, 2016,41(18):7318-7331. doi: 10.1016/j.ijhydene.2016.03.125
17. [17]
  WU K, JING J Y, LI W Y. Calcination temperature influence on the catalytic performance of Ni/CeO₂-ZrO₂ for low temperature steam reforming of methane[C]//31st Annual International Pittsburgh Coal Conference, 2014. Pittsburgh, PA, USA.
18. [18]
  LI T Y, JING J Y, FENG J, LI W Y. Carbon dioxide capture over Al-doped CaO-based sorbents with enhanced reactive stability in cyclic operations[C]//2015 Internation Conference on Coal Science and Technology, 2015. Australia.
19. [19]
  JING Jie-ying, WANG Shi-dong, ZHANG Xue-wei, LI Qing, LI Wen-ying. Influence of Ca/Al molar ratio on the structure and catalytic reforming performance of Ni/CaO-Al₂O₃ catalyst[J]. J Fuel Chem Technol, 2017,45(8):956-962.
20. [20]
  WU C H, CHANG Y P, CHEN S Y, LIU D M, YU C T, PEN B L. Characterization and structure evolution of Ca-Al-CO₃ hydrotalcite film for high temperature CO₂ adsorption[J]. J Nanosci Nanotechnol, 2010,10(7):4716-4720. doi: 10.1166/jnn.2010.1708
21. [21]
  CHANG P H, CHANG Y P, CHEN S Y, YY C T, CHYOU Y P. Ca-rich Ca-Al-oxide, high-temperature-stable sorbents prepared from hydrotalcite precursors:Synthesis, characterization, and CO₂ capture capacity[J]. ChemSusChem, 2011,4(12):1844-1851. doi: 10.1002/cssc.v4.12
22. [22]
  ZHANG Fan, WU Rong, WU Su-fang. The preparation of a type of NiO-CaO sorption complex catalyst by hydrothermal precipitation method and its application in ReSER process[J]. J Chem Eng Chin Univ, 2014,28(5):985-991.
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沈阳化工大学材料科学与工程学院沈阳 110142

Influence of calcination temperature on the structure and catalytic reforming performance of Ni/CaO-Al2O3 catalyst

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通讯作者: 陈斌, bchen63@163.com

Influence of calcination temperature on the structure and catalytic reforming performance of Ni/CaO-Al₂O₃ catalyst