Citation:
Wang Cairong, Wang Jinglin. Study on Coordination Mode of Tb(Ⅲ) with N, N-bis(carboxylphenyl)-2, 6-pyridinedicarboxamide[J]. Chemistry,
;2019, 82(2): 179-182.
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The studies on fluorescence titration of Tb(Ⅲ) to N, N-bis(carboxylphenyl)-2, 6-pyridinedicarboxamide (BCPD) showed that there are two coordination modes of Tb(Ⅲ) with BCPD:(BCPD)2Tb and (BCPD)Tb. The further study on emission fluorescence of BCPD and time scan intrinsic fluorescence of Tb(Ⅲ) proved that the two coordination modes were existed during the titration of Tb(Ⅲ) to BCPD. The results enriches the coordination theory and contributes to the preparation of fluorescent materials.
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